Just Published in Angewandte Chemie, International Edition
11/25/2024Regioregular Poly(p-phenylene iminoborane): A Strictly Alternating BN-Isostere of Poly(p-phenylene vinylene) with Stimuli-Responsive Behavior
![[Translate to Englisch:]](/fileadmin/08010000/2024/Screenshot_2024-12-12_at_13.57.04.png "[Translate to Englisch:]")
Authors: Johannes Chorbacher, Jonas Klopf, Alexandra Friedrich, Maximilian Fest, Johannes S. Schneider, Bernd Engels, Holger Helten
Abstract: An inorganic poly(p-phenylene vinylene) (PPV) analogue with a strictly alternating arrangement of BN units along the chain was prepared by an AB-polymerization process. The polymer and monodisperse oligomers show emission from locally excited (LE) or twisted intramolecular charge transfer (TICT) states, respectively, which can be addressed by various stimuli, giving rise to solvatochromic, thermochromic, and reversible mechanochromic behavior.
Link: https://onlinelibrary.wiley.com/doi/10.1002/anie.202416088
