Latest Publications
Prof. Holger Braunschweig has published 700 manuscripts since 1990, the majority of which appeared in first ranking journals such as Science, Nature, Nature Chemistry, Angewandte Chemie, Chemistry - A European Journal,...
Latest Publications 2023/2024
| 727 | L. Euringer, M. Holzapfel, I. Krummenacher, M. Franz, S. Richert, H. Braunschweig, C. Lambert Tuning Electron Transfer Coupling and Exchange Interaction in Bis-triarylamine Radical Cations and Dications by Bridge Electron Density J. Am. Chem. Soc. 2024, 146, 27679–27689. |
| 726 | C. Luz, K. Oppel, R. D. Dewhurst, H. Braunschweig, U. Radius Construction of a Boron Chain on a Single Metal by Dehydrocoupling of Borane Ligands J. Am. Chem. Soc. 2024, 146, 23741–23751. |
| 725 | L. Wu, X. Zhang, M. Moos, I. Krummenacher, M. Dietz, A. Jayaraman, R. Bertermann, Q. Ye, M. Finze, M. Wenzel, R. Mitric, C. Lambert, H. Braunschweig, L. Ji Full Electron Delocalization across the Cluster in 1,12-bisBMes2-p-carborane Radical Anion J. Am. Chem. Soc. 2024, 146, 17956–17963. |
| 724 | M. Rang, M. Heinz, A. Halkić, M. Weber, R. D. Dewhurst, A. Rempel, M. Härterich, M. C. Holthausen, H. Braunschweig Trapping of a Terminal Intermediate in the Boron-Mediated Dinitrogen Reduction: Mono‑,Tri‑, and Tetrafunctionalized Hydrazines in Two Steps from N2 J. Am. Chem. Soc. 2024, 146, 11048–11053. |
| 723 | A. Das, B. J. Elvers, N. Chrysochos, S. I. Uddin, T. Gangber, I. Krummenacher, D. Borah, A. Mishra, M. Shanmugam, C. B. Yildiz, H. Braunschweig, C. Schulzke, A. Jana Dianionic and Neutral Diboron-Centered Classical Diradicaloids J. Am. Chem. Soc. 2024, 146, 9004–9011. |
| 722 | L. Walther, K. Radacki, R. D. Dewhurst, R. Bertermann, M. Finze, H. Braunschweig All-Inorganic sp-Chain Ligands: Isoelectronic B/N Analogues of E. O. Fischer's Alkynylcarbynes Angew. Chem. 2024, 136, e202404930; Angew. Chem. Int. Ed. 2024, 63, e202404930. |
| 721 | M. Weber, T. Kupfer, M. Arrowsmith, R. D. Dewhurst, M. Rang, B. Ritschel, S. Titlbach, M. Ernst, M. Oliveira Rodrigues, E. N. da Silva Júnior, H. Braunschweig Bypassing Ammonia: From N2 to Nitrogen Heterocycles without N1 Intermediates or Transition Metals Angew. Chem. 2024, 136, e202402777; Angew. Chem. Int. Ed. 2024, 63, e202402777. |
| 720 | C. Czernetzki, T. Kunz, S. Huynh, A. Lamprecht, J. Sprenger, M. Finze, M. Arrowsmith, H. Braunschweig Synthesis and Reactivity of Tricoordinate Organoberyllium Azides Angew. Chem. 2024, 136, e202401279; Angew. Chem. Int. Ed. 2024, 63, e202401279. |
| 719 | D. Dhara, L. Endres, I. Krummenacher, M. Arrowsmith, R. D. Dewhurst, B. Engels, R. Bertermann, M. Finze, S. Demeshko, F. Meyer, F. Fantuzzi, H. Braunschweig Synthesis and Reactivity of a Dialane-Bridged Diradical Angew. Chem. 2024, 136, e202401052; Angew. Chem. Int. Ed. 2024, 63, e202401052. |
| 718 | M. Arrowsmith, H. Braunschweig Peter Paetzold (1935‒2023): a Chemist of Many Talents Angew. Chem. 2024, 136, e202319179; Angew. Chem. Int. Ed. 2024, 63, e202319179. |
| 717 | S. Koushik, H. Braunschweig Characterization of a secondary carbon-centred radical Nature Synth. 2024, 3, 677–678. |
| 716 | N. Wieprecht, I. Krummenacher, L. Wüst, M. Michel, S. Fuchs, S. Nees, M. Härterich, H. Braunschweig The forgotten borole: synthesis, properties and reactivity of a 1-boraindene Chem. Sci. 2024, 15, 12496-12501. |
| 715 | A. Swain, K. Radacki, H. Braunschweig, P. Ravat Helically twisted nanoribbons via stereospecific annulative π-extension reaction employing [7]helicene as a molecular wrench Chem. Sci. 2024, 15, 11737-11747. |
| 714 | J. Krebs, L. Brändler, I. Krummenacher, A. Friedrich, H. Braunschweig, M. Finze, B. F. E. Curchod, T. B. Marder Synthesis, Photophysical and Electronic Properties of a D-π-A Julolidine-Like Pyrenyl-o-Carborane Chem. Eur. J. 2024, 30, e202401704. |
| 713 | P. Mentzel, M. Holzapfel, A. Schmiedel, J. Günther, M. Michel, I. Krummenacher, A. Wodyński, M. Kaupp, H. Braunschweig, C. Lambert Structure and Photophysics of N-Tolanyl-phenochalcogenazines and their Radical Cations Chem. Eur. J. 2024, 30, e202303782. |
| 712 | Í. A. O. Bozzi, L. A. Machado, E. B. T. Diogo, F. G. Delolo, L. O. F. Barros, G. A. P. Graça, M. H. Araujo, F. T. Martins, L. F. Pedrosa, L. C. da Luz, F. S. Rodembusch, J. S. F. Guimarães, A. G. Oliveira, S. Röttger, D. B. Werz, C. P. Souza, F. Fantuzzi, T. B. Marder, H. Braunschweig, E. N. da Silva Júnior Electrochemical Diselenation of BODIPY Fluorophores for Bioimaging Applications and Sensitization of 1O2 Chem. Eur. J. 2024, 30, e202303883. |
| 711 | R. Witte, S. Kar, K. Radacki, M. Härterich, M. Rang, M. Michel, C. Mihm, C. Czernetzki, T. Brückner, E. Beck, S. Lutz, R. D. Dewhurst, H. Braunschweig Transition-metal-like coordination chemistry of dicoordinate borylenes with organic azides Chem. Commun. 2024, 60, 8629-8632. |
| 710 | T. Brückner, D. Duwe, F. Fantuzzi, M. Heß, R. D. Dewhurst, K. Radacki, H. Braunschweig Hydrosilylation of B-B Triple Bonds: Catalyst- and Reductant-Free Construction of B–Si bonds and B2Si Heterocycles Chem. Commun. 2024, 60, 3259-3262. |
| 709 | M. K. Nayak, B. J. Elvers, S. Mehta, I. Krummenacher, A. Mondal, H. Braunschweig, C. Schulzke, P. Ravat, A. Jana Bis-[cyclic(alkyl)(amino)carbene]s-derived diradicals Chem. Commun. 2024, 60, 1739-1742. |
| 708 | D. Duwe, K. Saha, L. Endres, T. Brückner, R. D. Dewhurst, M. Dietz, K. Radacki, F. Fantuzzi, H. Braunschweig Stepwise and selective synthesis of chelating, multimetallic and mixed-metal π-diborene complexes Chem. Commun. 2024, 60, 1120-1123. |
| 707 | M. Passargus, M. Arrowsmith, R. Bertermann, M. Finze, H. Braunschweig A-Frame-Templated High-Coordinate Platinum(IV) cis-Bis(boryl) Complexes Inorg. Chem. 2024, 63, 10657–10670. |
| 706 | C. Czernetzki, M. Arrowsmith, L. Endres, I. Krummenacher, H. Braunschweig Tricoordinate Beryllium Radicals and Their Reactivity Inorg. Chem. 2024, 63, 2670–2678. |
| 705 | A. Lamprecht, M. Arrowsmith, M. Dietz, S. Fuchs, A. Rempel, M. Härterich, H. Braunschweig Synthesis, reduction and C‒H activation chemistry of azaborinines with redox-active organoboryl substituents Dalton Trans. 2024, 53, 449-453. |
| 704 | M. Dietz, M. Arrowsmith, H. Braunschweig CAAC-stabilised 9,10-diboraanthracene: an electronically and structurally flexible platform for small-molecule activation and metal complexation Dalton Trans. 2024, 53, 449-453. |
| 703 | M. Härterich, A. Matler, R. D. Dewhurst, A. Sachs, K. Oppel, A. Stoy, H. Braunschweig A step-for-step main-group replica of the Fischer carbene synthesis at a borylene carbonyl Nature Communications 2023, 14, Article number: 2764. |
| 702 | P. Saha, N. Chrysochos, B. J. Elvers, S. Pätsch, S. I. Uddin, I. Krummenacher, M. Nandeshwar, G. P. Sankar, H. Braunschweig, P. Ravat, C. Schulzke, A. Jana Bis-Olefin Based Crystalline Schlenk Hydrocarbon Diradicals with a Triplet Ground State Angew. Chem. 2023, 135, e202311868; Angew. Chem. Int. Ed. 2023, 62, e202311868. |
| 701 | S. Nees, T. Wellnitz, F. Dankert, S. Dotzauer, M. Härterich, M. Feldt, H. Braunschweig, C. Hering-Junghans On the Reactivity of Phosphaalumenes towards C−C Multiple Bonds Angew. Chem. 2023, 135, e202215838; Angew. Chem. Int. Ed. 2023, 62, e202215838. |
| 700 | T. Brückner, B. Ritschel, J. O. C. Jiménez-Halla, F. Fantuzzi, D. Duwe, R. D. Dewhurst, H. Braunschweig Metal-Free Intermolecular C–H Borylation of N-Heterocycles at B–B Multiple Bonds Angew. Chem. 2023, 135, e202213284; Angew. Chem. Int. Ed. 2023, 62, e202213284. |
| 699 | L. C. Haufe, L. Endres, M. Arrowsmith, R. Bertermann, M. Dietz, F. Fantuzzi, M. Finze, H. Braunschweig Boron Insertion into the N≡N bond of a Tungsten Dinitrogen Complex J. Am. Chem. Soc. 2023, 145, 23986–23993. |
| 698 | M. Heinz, M. Arrowsmith, J. I. Schweizer, I. Krummenacher, M. C. Holthausen, H. Braunschweig Experimental and Computational Study of a Confirmed Borylene-to-Diborene Dimerization J. Am. Chem. Soc. 2023, 145, 22685–22696. |
| 697 | M. Dietz, M. Arrowsmith, L. Endres, V. Paprocki, B. Engels, H. Braunschweig Synthesis and Reactivity of Highly Electron-Rich Zerovalent Group 10 Diborabenzene Pogo-Stick and Half-Sandwich Complexes J. Am. Chem. Soc. 2023, 145, 22222–22231. |
| 696 | M. Dietz, M. Arrowsmith, K. Drepper, A. Gärtner, I. Krummenacher, R. Bertermann, M. Finze, H. Braunschweig Structure and Electronics of a Series of CAAC-Stabilized Diboron-Doped Acenes from 1,4-Diboranaphthalene to 6,13-Diborapentacenes J. Am. Chem. Soc. 2023, 145, 15001–15015. |
| 695 | A. Gärtner, U. S. Karaca, M. Rang, M. Heinz, P. D. Engel, I. Krummenacher, M. Arrowsmith, A. Hermann, A. Matler, A. Rempel, R. Witte, H. Braunschweig, M. C. Holthausen, M.-A. Légaré Achieving Control over the Reduction/Coupling Dichotomy of N2 by Boron Metallomimetics J. Am. Chem. Soc. 2023, 145, 8231–8241. |
| 694 | J. L. Bohlen, L. Endres, R. Drescher, K. Radacki, M. Dietz, I. Krummenacher, H. Braunschweig Boroles from alumoles: accessing boroles with alkyl-substituted backbones via transtrielation Chem. Sci. 2023, 14, 9010-9015. |
| 693 | Y. K. J. Bejaoui, F. Philippi, H.-G. Stammler, K. Radacki, L. Zapf, N. Schopper, K. Goloviznina, K. A. M. Maibom, R. Graf, J. A. P. Sprenger, R. Bertermann, H. Braunschweig, T. Welton, N. V. Ignat´ev, M. Finze Insights to structure-property relationships in ionic liquids using cyclic perfluoroalkylsulfonylimides Chem. Sci. 2023, 14, 2200-2214. |
| 692 | S. Jana, B. J. Elvers, S. Pätsch, P. Sarkar, I. Krummenacher, M. K. Nayak, A. Maiti, N. Chrysochos, S. K. Pati, C. Schulzke, H. Braunschweig, C. B. Yildiz, A. Jana Air and Moisture Stable para- and ortho-Quinodimethane Derivatives Derived from bis-N-Heterocyclic Olefins Org. Lett. 2023, 25, 1799–1804. |
| 691 | Z. Wu, N. Hippchen, J. Han, L. Ji, A. Friedrich, I. Krummenacher, H. Braunschweig, J. Krebs, M. Moos, P. Biegger, O. Tverskoy, S. Maier, C. Lambert, A. Dreuw, T. B. Marder, J. Freudenberg, U. H. F. Bunz The Radical Anion and Dianion of Benzo[3,4]cyclobuta[1,2-b]phenazine J. Org. Chem. 2023, 88, 2742–2749. |
| 690 | A. Maiti, B. J. Elvers, S. Bera, F. Lindl, I. Krummenacher, P. Ghosh, H. Braunschweig, C. B. Yildiz, C. Schulzke, H.-G. Korth, A. Jana Comment on “Disclosing Cyclic(Alkyl)(Amino)Carbenes as a One-Electron Reductant: Synthesis of Acyclic(Amino)(Aryl)Carbene-Based Kekulé Diradicaloids” Chem. Eur. J. 2023, 29, e202302848. |
| 689 | W. Lu, N. Hensiek, K. Saha, R. D. Dewhurst, M. Härterich, C. Pranckevicius, S. Hagspiel, M. Dietz, I. Krummenacher H. Braunschweig Electron-Precise Dicationic Tetraboranes: Syntheses, Structures and Rearrangement to an Alkylidene Borate-Borenium Zwitterion and a 1,3-Azaborinine Chem. Eur. J. 2023, 29, e202300644. |
| 688 | C. Czernetzki, T. Tröster, L. Endres, F. Endres, M. Arrowsmith, A. Gärtner, F. Fantuzzi, H. Braunschweig Synthesis, Structural Characterization, and Bonding of Molecular Heavier Beryllium Chalcogenides Chem. Eur. J. 2023, 29, e202301418. |
| 687 | F. Schorr, T. Keim, M. Arrowsmith, A. Vargas, R. D. Dewhurst, I. Krummenacher, H. Braunschweig Thienyl-Substituted Diboranes(4): Electronic Stabilization of Radicals Versus Increased Reactivity towards Bond Activatio Chem. Eur. J. 2023, 29, e202301286. |
| 686 | L. Xiang, J. Wang, I. Krummenacher, K. Radacki, H. Braunschweig, Z. Lin, Q. Ye Persistent and Predominantly Localized Boron Radical from the Reduction of a Three-dimensional Analogue of NHC-Stabilized Borafluorenium Chem. Eur. J. 2023, 29, e202301270. |
| 685 | D. Dhara, A. Jayaraman, M. Härterich, M. Arrowsmith, M. Jürgensen, M. Michel, H. Braunschweig Trapping of a Transient Base-Stabilised Alumylene and Alumylene-Type Reactivity of a Self-Stabilising Dialumene towards Organic Azides Chem. Eur. J. 2023, 29, e202300483. |
| 684 | T. Bischof, L. Beßler, I. Krummenacher, L. Erhard, H. Braunschweig, M. Finze Construction of a Diverse Range of Boron Heterocycles via Ring Expansion of a Carboranyl-Substituted 9-Borafluorene Chem. Eur. J. 2023, 29, e202300210. |
| 683 | R. Witte, M. Arrowsmith, A. Lamprecht, I. Krummenacher, H. Braunschweig C‒C and C‒N Bond Activation, Lewis-Base Coordination and One- and Two-Electron Oxidation at a Linear Aminoborylene Chem. Eur. J. 2023, 29, e202203663. |
| 682 | F. Lindl, A. Lamprecht, M. Arrowsmith, E. Khitro, A. Rempel, M. Dietz, T. Wellnitz, G. Bélanger-Chabot, A. Stoy, V. Paprocki, D. Prieschl, C. Lenczyk, J. Ramler, C. Lichtenberg H. Braunschweig Aromatic 1,2-Azaborinin-1-yls as Electron-Withdrawing Anionic Nitrogen Ligands for Main Group Elements Chem. Eur. J. 2023, 29, e202203345. |
| 681 | R. Dolai, B. J. Elvers, T. Singh, N. Chrysochos, R. Kumar, B. Joseph, M. K. Nayak, A. Maiti, A. Jayaraman, I. Krummenacher, J. Mondal, H. Braunschweig, C. B. Yildiz, C. Schulzke, A. Jana Carbodicarbenes and Striking Redox Transitions of their Conjugate Acids: Influence of NHC vs. CAAC as Donor Substituents Chem. Eur. J. 2023, 29, e202202888. |
| 680 | V. Zeh, J. S. Schneider, J. Bachmann, I. Krummenacher, H. Braunschweig, H. Helten Poly(ferrocenyleneiminoborane): an inorganic–organic hybrid polymer comprising a backbone of moderately interacting ferrocenes Chem. Commun. 2023, 59, 13723-13726. |
| 679 | N. Chrysochos, S. Pätsch, B. J. Elvers, I. Krummenacher, N. M. Giridhar, G. Prabusankar, H. Braunschweig, C. Schulzke, P. Ravat, A. Jana Introducing an orthogonally polarized electron-rich alkene synthesis of a zwitterionic boron-Containing π-conjugated system Chem. Commun. 2023, 59, 12350-12353. |
| 678 | A. Lamprecht, F. Lindl, L. Endres, I. Krummenacher, H. Braunschweig Coinage metal complexes of BN analogues of m-terphenyl ligands Chem. Commun. 2023, 59, 10149-10152. |
| 677 | T. Tröster, F. Endres, M. Arrowsmith, L. Endres, F. Fantuzzi, H. Braunschweig Dibenzoberylloles: antiaromatic s-block fluorene analogues Chem. Commun. 2023, 59, 9199-9202. |
| 676 | J. S. Schneider, I. Krummenacher, H. Braunschweig, H. Helten Linear and macrocyclic oligo(p-phenylene iminoboranes) with ferrocenyl side groups – observation of selective, non-templated macrocyclization Chem. Commun. 2023, 59, 8408-8411. |
| 675 | D. Čavlović, O. Blacque, I. Krummenacher, H. Braunschweig, P. Ravat, M. Juríček Dimethylnonacethrene – en route to a magnetic switch Chem. Commun. 2023, 59, 7743-7746. |
| 674 | T. Bischof, N. Wieprecht, S. Fuchs, L. Endres, I. Krummenacher, M. Michel, C. Mihm, H. Braunschweig, M. Finze Unlocking Heteroaromatic Ring Systems through Chalcogen Insertion into Boroles Inorg. Chem. 2023, 62, 21329–21335. |
| 673 | B. Chakraborty, F. E. Basumatary, H. Braunschweig, A. K. Phukan Cooperative Activation of Small Molecules by Base-Stabilized Borylenes Inorg. Chem. 2023, 62, 9063–9076. |
| 672 | D. Čavlović, O. Blacque, I. Krummenacher, H. Braunschweig, P. Ravat, M. Juríček Dimethylnonacethrene – En Route to a Magnetic Switch ChemRxiv 2023,doi: 10.26434/chemrxiv-2023-3fbgs. |
| 671 | S. Huynh, M. Arrowsmith, L. Meier, M. Dietz, M. Härterich, M. Michel, A. Gärtner, H. Braunschweig Cyclic alkyl(amino)iminates (CAAIs) as strong 2σ,4π-electron donor ligands for the stabilisation of boranes and diboranes(4): a synthetic and computational study Dalton Trans. 2023, 52, 3869-3876. |
| 670 | J. Weiser, J. Cui, R. D. Dewhurst, H. Braunschweig, B. Engels, F. Fantuzzi Structure and bonding of proximity-enforced main-group dimers stabilized by a rigid naphthyridine diimine ligand J. Comput. Chem. 2023, 44, 456-467. |
| 669 | S. Nees, H. Beer, P. Just, L. M. Teichmeier, L. E. Christoffer, A. Guljam, Kushik, H. Braunschweig, C. Hering-Junghans On the reactivity of Mes*P(PMe3) towards Al(I) compounds - Evidence for the Intermediate Formation of Phosphaalumenes ChemPlusChem 2023 2023, 88, e202300078. |
| 668 | D. E. Trujillo-González, G. G. García, T. A. Hamlin, F. M. Bickelhaupt, H. Braunschweig, J. O. C. Jiménez-Halla, M. Solà The Search for Enhanced σ-Donor Ligands to Stabilize Boron-Boron Multiple Bonds Eur. J. Inorg. Chem. 2023, 26, e202200767. |
For a full list of publications visit our Group homepage www.braunschweiggroup.de.
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