1995-2000
Publikationen 1995 - 2000
- L. Fischer, S.A. Wagner, R. Tacke, Preparation of enantiomerically pure (R)-(1-hydroxyethyl)dimethyl(phenyl)silane using resting cells of Saccharomyces cerevisiae (DHW S-3) as biocatalyst, Appl. Microbiol. Biotechnol. 42, 671-674 (1995).
- R. Tacke, D. Reichel, M. Kropfgans, P.G. Jones, E. Mutschler, J. Gross, X. Hou, M. Waelbroeck, G. Lambrecht, Biological recognition of enantiomeric silanes: syntheses and antimuscarinic properties of optically active (2-aminoethyl)cyclohexyl(hydroxy-methyl)phenylsilanes and related quaternary ammonium derivatives, Organometallics 14, 251-262 (1995).
- R. Tacke, D. Reichel, K. Günther, S. Merget, The first liquid-chromatographic separation of the (R)- and (S)-enantiomers of a chiral silanol, silane and germane, Z. Naturforsch. 50b, 568-572 (1995).
- R. Tacke, M. Mühleisen, A. Lopez-Mras, W.S. Sheldrick, Synthesen und Kristallstrukturanalysen neuer zwitterionischer spirocyclischer (Ammonioorganyl)- bis[vic-arendiolato(2─)]silicate: Untersuchungen zur Struktur der λ5Si-Koordinationspolyeder, Z. Anorg. Allg. Chem. 621, 779-788 (1995).
- R. Tacke, D. Terunuma, A. Tafel, M. Mühleisen, B. Forth, M. Waelbroeck, J. Gross, E. Mutschler, T. Friebe, G. Lambrecht, Fluorine-containing derivatives of the muscarinic antagonists sila-pridinol and sila-difenidol: syntheses and antimuscarinic properties, J. Organomet. Chem. 501, 145-154 (1995).
- R. Tacke, B. Forth, M. Waelbroeck, J. Gross, E. Mutschler, G. Lambrecht, Unsaturated derivatives of the muscarinic antagonists hexahydro-sila-difenidol (HHSiD) and p-fluoro-hexahydro-sila-difenidol (p-F-HHSiD) with an (E)-Si─CH=CH─CH2─N moiety: syntheses and binding affinities at muscarinic receptor subtypes, J. Organomet. Chem. 505, 73-79 (1995).
- R. Tacke, D. Reichel, P.G. Jones, X. Hou, M. Waelbroeck, J. Gross, E. Mutschler, G. Lambrecht, Pharmacological discrimination between enantiomeric germanes by muscarinic receptors: a study on germanium/silicon bioisosterism, J. Organomet. Chem. 521, 305-323 (1996).
- R. Tacke, J. Becht, O. Dannappel, R. Ahlrichs, U. Schneider, W.S. Sheldrick, J. Hahn, F. Kiesgen, Zwitterionic λ5Si-organofluorosilicates of the formula types F4SiCH2NMe2R and F3MeSiCH2NMe2R (R = H, Me) and related compounds: synthesis, structure, and dynamic behavior, Organometallics 15, 2060-2077 (1996).
- R. Tacke, J. Heermann, M. Pülm, Zwitterionic bis[citrato2B)-O3,O4](morpholinio-methyl)germanate hydrate and its silicon analogue: syntheses and crystal structure analyses, Organometallics 16, 5648-5652 (1997).
- M. Pülm, R. Tacke, [(Dimethylammonio)methyl]bis[cis-1,2-diphenylethene-1,2-diolato(2B)]silicate: the first zwitterionic spirocyclic λ5Si-silicate containing cis-ethene-1,2-diolato(2B) ligands, Organometallics 16, 5664-5668 (1997).
- B. Pfrommer, R. Tacke, A zwitterionic pentacoordinate silicon compound with an SiO2N2C framework, Eur. J. Inorg. Chem. 1998, 415-418.
- R. Tacke, J. Heermann, B. Pfrommer, The first zwitterionic dinuclear germanium(IV) complex with pentacoordinate germanium atoms: synthesis and crystal structure analysis, Inorg. Chem. 37, 2070-2072 (1998).
- R. Tacke, J. Heermann, M. Pülm, I. Richter, (Ammoniomethyl)bis[salicylato(2B)-O1,O2]silicates: zwitterionic spirocyclic λ5Si-silicates with two six-membered SiO2C3 ring systems, Organometallics 17, 1663-1668 (1998).
- R. Tacke, U. Kosub, S.A. Wagner, R. Bertermann, S. Schwarz, S. Merget, K. Günther, Enzymatic transformation and liquid-chromatographic separation as methods for the preparation of the (R)- and (S)-enantiomers of the centrochiral hydridogermanes p-XC6H4(H)Ge(CH2OAc)CH2OH (X = H, F), Organometallics 17, 1687-1699 (1998).
- R. Tacke, J. Heermann, M. Pülm, Pentafluoro[(4-methyl-1,4-bisazoniacyclohex-1-yl)-methyl]germanate hydrate: synthesis and crystal structure of a zwitterionic λ6Ge-germanate with a GeF5C framework, Z. Naturforsch. 53b, 535-539 (1998).
- R. Tacke, B. Pfrommer, K. Lunkenheimer, R. Hirte, Zwitterionic (ammoniomethyl)-tetrafluorosilicates of the formula type F4SiCH2NH2(CH2)nMe (n = 5B11) and F4SiCH2NMe2(CH2)5Me: a new class of highly efficient surface-active compounds, Organometallics 17, 3670-3676 (1998).
- R. Tacke, J. Heermann, M. Pülm, E. Gottfried, A zwitterionic λ5Si-silicate with an almost ideal square-pyramidal Si-coordination polyhedron: synthesis and crystal structure analysis, Monatsh. Chem. 130, 99-107 (1999).
- R. Tacke, R. Bertermann, A. Biller, O. Dannappel, M. Pülm, R. Willeke, Syntheses, stereochemistry, and dynamic behavior of chiral zwitterionic (ammoniomethyl)-bis[glycolato(2B)-O1,O2]silicates, Eur. J. Inorg. Chem. 1999, 795-805.
- R. Tacke, B. Pfrommer, M. Pülm, R. Bertermann, New chiral zwitterionic λ5Si-silicates with an SiO5 or SiO4C framework: syntheses, crystal structures, and properties, Eur. J. Inorg. Chem. 1999, 807-816.
- R. Tacke, M. Pülm, I. Richter, B. Wagner, R. Willeke, New zwitterionic spirocyclic λ5Si-silicates with two ethane-1,2-diolato(2B), oxalato(2B), or benzene-1,2-diolato(2B) ligands - synthesis, structure, and dynamic behavior, Z. Anorg. Allg. Chem. 625, 2169-2177 (1999).
- M. Pülm, J. Becht, R. Tacke, Singly charged λ6Si-silicate anions with an SiF5C skeleton: syntheses and crystal structure analyses of the ionic hexacoordinate silicon compounds [Me3NH][F5SiCH2NMe2H] · H2O and [Me3NH][F5SiCH2NMe3] · H2O, Z. Naturforsch. 55b, 60-64 (2000).
- V.I. Handmann, M. Merget, R. Tacke, Sila-substitution of the α-amino acid proline: synthesis of rac- and (R)-4,4-dimethyl-4-sila-proline ethyl ester, Z. Naturforsch. 55b, 133-138 (2000).
- R. Tacke, R. Bertermann, A. Biller, O. Dannappel, M. Penka, M. Pülm, R. Willeke, Zwitterionic spirocyclic λ5Si-silicates with two bidentate acetohydroximato(2B) or benzohydroximato(2B) ligands: synthesis, structure, and dynamic stereochemistry, Z. Anorg. Allg. Chem. 626, 1159-1173 (2000).
- D. Kost, I. Kalikhman, S. Krivonos, R. Bertermann, C. Burschka, R.E. Neugebauer, M. Pülm, R. Willeke, R. Tacke, New zwitterionic pentacoordinate silicates with SiONFC2,
SiONF2C, and SiO2N2C frameworks: synthesis, structure, and dynamic stereochemistry,
Organometallics 19, 1083-1095 (2000). - R. Tacke, A. Stewart, J. Becht, C. Burschka, I. Richter, Di[(hydroxyalkyl)-
dimethylammonium] tris[benzene-1,2-diolato(2B)]silicates and their germanium analogs:
syntheses, crystal structure analyses, and NMR studies, Can. J. Chem. 78, 1380-1387
(2000). - R. Tacke, M. Merget, R. Bertermann, M. Bernd, T. Beckers, T. Reissmann, Syntheses and
properties of silicon- and germanium-containing α-amino acids and peptides: a study on C/Si/Ge Bioisosterism, Organometallics 19, 3486-3497 (2000). - R. Bertermann, R. Tacke, Solid-state 29Si VACP/MAS NMR studies of silicon-accumulating plants: structural characterization of biosilica deposits, Z. Naturforsch. 55b, 459-461 (2000).
- V.I. Handmann, R. Bertermann, C. Burschka, R. Tacke, New bicyclic sila-heterocycles: syntheses and crystal structure analyses of rac-7-ethoxy-2,2-diorganyl-2,3,5,7a-tetrahydro-1H-3a,6-diaza-2-sila-inden-4-ones, J. Organomet. Chem. 613, 19-25 (2000).
- R. Tacke, C. Burschka, I. Richter, B. Wagner, R. Willeke, Pentacoordinate silicon compounds with SiO5 skeletons containing SiOH or SiOSi groups: derivatives of the pentahydroxosilicate(1&) Anion [Si(OH)5]S and its anhydride [(OH)4Si-O-Si(OH)4]2S, J. Am. Chem. Soc. 122, 8480-8485 (2000).
- R. Tacke, B. Ulmer, B. Wagner, M. Arlt, A novel silicon-based linkage and cleavage
strategy for solid-phase synthesis: formation of resin-linked zwitterionic pentacoordinate silicates as the key step and release of the target molecules in a traceless fashion, Organometallics 19, 5297-5309 (2000).