Nachrichten, Meldungen

NHC·Alane Adducts as Hydride Sources in the Hydrodefluorination of Fluoroaromatics and Fluoroolefins

Bromination Improves the Electron Mobility of Tetraazapentacene

Nitrogen fixation and reduction at boron

Preparation, Properties, and Structures of the Radical Anions and Dianions of Azapentacenes

Catalyst-free room-temperature iClick reaction of molybdenum(II) and tungsten(II) azide complexes with electron-poor alkynes: structural preferences and kinetic studies

Ligand versus Complex: C-F and C-H Bond Activation of Polyfluoroaromatics at a Cyclic (Alkyl)(Amino) Carbene

Main-Group Metallomimetics: Transition Metal-like Photolytic CO Substitution at Boron

Protonation versus Oxonium Salt Formation: Basicity and Stability Tuning of Cyanoborate Anions

Deprotonation of a Hydridoborate Anion

A Cyclic Alkyl(amino)carbene as Two-Atom π-Chromophore Leading to the First Phosphorescent Linear CuI Complexes

Highly Efficient Synthesis of Alkylboronate Esters via Cu(II)-Catalyzed Borylation of Unactivated Alkyl Bromides and Chlorides in Air

Cationic Bismuth Amides: Accessibility, Structure, and Reactivity

Unexpected Dimeric Spiro-Borate Complexes from Lewis-Acid Induced Transformation of Oxalatoborates

A Silacyclopropene with a Six-Coordinate Silicon Atom and an SiN4C2 Skeleton: Synthesis and Structural Characterization

Cyclisation of biscarbenoids – a novel mode of cyclobutadiene stabilisation