Intern
Arbeitsgruppe Finze

2002–2009

Veröffentlichungen (Peer-Review) & Patente

2009

33.

 M. Finze, J. A. P. Sprenger
Anionic Gold(I) Complexes – Twelve- and Ten-Vertex Monocarba-closo-borate Anions with Carbon-Gold σ Bonds
Chem. Eur. J. 2009, 15, 9918–9927.
DOI: 10.1002/chem.200901130
32.   M. Finze, G. J. Reiss
Tetraethylammonium-12-phenylethinylcarba-closo-dodecaborate – [Et4N][12-PhCC-closo-CB11H11]
Acta Crystallogr. 2009, E65, o1048.
DOI: 10.1107/S1600536809013300

31.

 M. Finze
Regioselective Monoiodination of Carba-closo-dodecaborates: M[7-I-12-X-closo-CB11H10] (M = Cs+, [Et4N]+; X = F, Cl, Br, OH)
Eur. J. Inorg. Chem. 2009, 501–507.
DOI: 10.1002/ejic.200801046
30.   M. Finze
Synthesis and Characterization of 2-Mono- and 1,2-Diaminocarba-closo-dodecaborates M[1-R-2-H2N-closo-CB11H10] (R=H, Ph, H2N, CyHN)
Chem. Eur. J. 2009, 15, 947–962.
DOI: 10.1002/chem.200801497

2008

29.   M. Finze
Carba-closo-dodecaborates with One or Two Alkynyl Substituents Bonded to Boron
Inorg. Chem. 2008, 47, 11857–11867.
DOI: 10.1021/ic801610b
28.   M. Finze, G. J. Reiss
Salts with the Triborate Anion [B3O3F2(OH)2]–: A Combined Experimental and Theoretical Study
Eur. J. Inorg. Chem. 2008, 2321–2325.
DOI: 10.1002/ejic.200800068

2007

27.   M. Finze, E. Bernhardt, H. Willner
Trifluoromethylboranes and -Borates: New Synthetic Strategies and Applications
Angew. Chem. Int. Ed. 2007, 46, 9180–9196.
DOI: 10.1002/anie.200700826
Trifluormethylborane und -borate – neue Synthesestrategien und Anwendungen
Angew. Chem. 2007, 119, 9340-9357.
DOI: 10.1002/ange.200700826
26.   M. Finze
Carbon Extrusion/Cluster Contraction: Synthesis of the Fluorinated Cyano-closo-Undecaborate K2[3-NC-closo-B11F10]
Angew. Chem. Int. Ed. 2007, 46, 8880–8882.
DOI: 10.1002/anie.200703385
Kohlenstoff-Extrusion/Cluster-Kontraktion: Synthese des fluorierten Cyano-closo-undecaborats K2[3-NC-closo-B11F10]
Angew. Chem. 2007, 119, 9036-9039.
DOI: 10.1002/ange.200703385
25.   M. Finze, G. J. Reiss, M. Zähres
[1-H2N-CB11F11]– – Synthesis and Reactions of a Functionalized Fluorinated Carbadodecaborate Anion
Inorg. Chem. 2007, 46, 9873–9883.
DOI: 10.1021/ic701398u
24.   E. Bernhardt, D. J. Brauer, M. Finze, H. Willner
closo-[B21H18]–: A Face-Fused Diicosahedral Borate Ion
Angew. Chem. Int. Ed. 2007, 46, 2927–2930.
DOI: 10.1002/anie.200604077
closo-[B21H18]− – ein flächenverknüpftes diikosaedrisches Borat-Ion
Angew. Chem. 2007, 119, 2985–2988.
DOI: 10.1002/ange.200604077

2006

23.   E. Bernhardt, M. Finze, H. Willner, C. W. Lehmann
Salts of the Cobalt(I) Complexes [Co(CO)5]+ and [Co(CO)2(NO)2]+ and the Lewis Acid-Base Adduct [Co2(CO)7CO-B(CF3)3]
Chem. Eur. J. 2006, 12, 8276–8283.
DOI: 10.1002/chem.200600210
22.   E. Bernhardt, D. J. Brauer, M. Finze, H. Willner
[B(CO2H)4]– and [B(CNCH3)4]3+: Homoleptic Boron Complexes Containing Carboxy and Methylisonitrile Ligands
Angew. Chem. Int. Ed. 2006, 45, 6383–6386.
DOI: 10.1002/anie.200601870
[B(CO2H)4]− und [B(CNCH3)4]3+ – homoleptische Borkomplexe mit Carboxy- und Methylisocyanid-Liganden
Angew. Chem. 2006, 118, 6532–6534.
DOI: 10.1002/ange.200601870
21.   M. Finze, E. Bernhardt, H. Willner, C. W. Lehmann
(PPh3)3RhCNB(CF3)3 and (PPh3)3RhNCB(CF3)3 – Isocyano- and Cyanoborate Complexes of Tris(triphenylphosphin)rhodium(I)
Organometallics 2006, 25, 3070–3075.
DOI: 10.1021/om060135z
20.   M. Finze, E. Bernhardt, H. Willner, C. W. Lehmann
Reactions of (CF3)3BCO with Amines and Phosphines
Inorg. Chem. 2006, 45, 669–678.
DOI: 10.1021/ic0515305
19.   E. Bernhardt, M. Finze, H. Willner
Eine neue Synthese für Nitrosyl-Salze mit schwach koordinierenden Anionen am Beispiel von NO[B(CF3)4]
A New Synthesis for Nitrosyl Salts with Weakly Coordinating Anions Exemplified by NO[B(CF3)4]
Z. Anorg. Allg. Chem. 2006, 632, 248–250.
DOI: 10.1002/zaac.200500392
18.   M. Finze, E. Bernhardt, H. Willner, U. Welz-Biermann, N. Ignatyev
Merck Patent GmbH, 64293 Darmstadt (Germany)
Process for Preparation of Hydrogen Fluoroalkylborate Strong Acids and Their Binary and Complex Salts
WO2006045405, 04.05.2006 (04.10.2005).
17.   N. Ignatyev, U. Welz-Biermann, M. Finze, E. Bernhardt, H. Willner
Merck Patent GmbH, 64293 Darmstadt (Germany)
Preparation of Salts Containing Alkoxytris(fluoroalkyl)borate Anions as Ionic Liquids
WO2006010455, 02.02.2006 (09.07.2005).

2005

16.

 M. Finze, E. Bernhardt, M. Berkei, H. Willner, J. Hung, R. M. Waymouth
[H(OEt2)2]+ and [Ph3C]+ Salts of the Borate Anions [B(CF3)4]–, [(CF3)3BCN]–, and [B(CN)4]–
Organometallics 2005, 24, 5103–5109.
DOI: 10.1021/om050463j
15.   M. Finze, E. Bernhardt, H. Willner, C. W. Lehmann
Cyano- and Isocyanotris(trifluoromethyl)borates: Synthesis, Spectroscopic Properties and Solid State Structures of K[(CF3)3BCN] and K[(CF3)3BNC]
J. Am. Chem. Soc. 2005, 127, 10712–10722.
DOI: 10.1021/ja0516357

14.

 M. Finze, E. Bernhardt, H. Willner, C. W. Lehmann
Haloacylcomplexes of Boron, [(CF3)3BC(O)Hal]– (Hal = F, Cl, Br, I)
Chem. Eur. J. 2005, 11, 6653–6665.
DOI: 10.1002/chem.200500038

13.

 M. Finze, E. Bernhardt, H. Willner, C. W. Lehmann, F. Aubke
Homoleptic, σ-Bonded Octahedral Superelectrophilic Metal Carbonyl Cations of Iron(II), Ruthenium(II), and Osmium(II). Part 2:  Syntheses and Characterizations of [M(CO)6][BF4]2 (M = Fe, Ru, Os)
Inorg. Chem. 2005, 44, 4206–4214.
DOI: 10.1021/ic0482483
12.   N. Ignatyev, U. Welz-Biermann, H. Willner, M. Finze, E. Bernhardt
Merck Patent GmbH, 64293 Darmstadt (Germany)
New stable, organic solvent-soluble cationic dyes with cyanoborate, fluoroalkyl phosphate, fluoroalkyl borate or imidate anion, useful e.g. for dyeing plastics, synthetic fibers or flexographic printing inks    
DE2003157359, 07.07.2005 (12.09.2003).
11.   N. Ignatyev, U. Welz-Biermann, H. Willner, M. Finze, E. Bernhardt
Merck Patent GmbH, 64293 Darmstadt (Germany)
Fluoralkylborat-Farbstoffe
DE200310338834, 24.03.2005 (21.08.2003);
N. Ignatyev, U. Welz-Biermann, H. Willner, M. Finze, E. Bernhardt, A. Kucheryna
Merck Patent GmbH, 64293 Darmstadt (Germany)
Cyanoborate, Fluoroalkyl Phosphate, Fluoroalkyl Borate or Imide Dyes
WO2005021661, 10.03.2005 (22.07.2004)

2004

10.   M. Finze, E. Bernhardt, H. Willner, C. W. Lehmann
[(CF3)3BCP]– and [(CF3)3BCAs]–: Thermally Stable Phosphaethynyl and Arsaethynyl Complexes
Angew. Chem. Int. Ed. 2004, 43, 4159–4163.
DOI: 10.1002/anie.200454034
[(CF3)3BCP]− und [(CF3)3BCAs]− –thermisch stabile Phosphaethinyl- und Arsaethinyl-Komplexe
Angew. Chem. 2004, 116, 4254–4257.
DOI: 10.1002/ange.200454034
9.   E. Bernhardt, M. Finze, H. Willner
Synthesis and NMR spectroscopic investigation of salts containing the novel [Au(CF3)nX4–n]– (n = 4–1, X = F, CN, Cl) anions
J. Fluorine Chem. 2004, 125, 967–973.
DOI: 10.1016/j.jfluchem.2004.01.029
8.   M. Finze, E. Bernhardt, M. Zähres, H. Willner
Rearrangement Reactions of the Transient Lewis Acids (CF3)3B and (CF3)3BCF2: An Experimental and Theoretical Study
Inorg. Chem. 2004, 43, 490–505.
DOI: 10.1021/ic0350640
7.   U. Welz-Biermann, N. Ignatyev, E. Bernhardt, M. Finze, H. Willner
Merck Patent GmbH, 64293 Darmstadt (Germany)
Process for Preparation of Hydrogen Fluoroalkylborate Strong Acids and Salze mit Cyanoborat-Anionen
DE20031006617, 26.08.2004 (14.02.2003);
Salts Comprising Cyanoborate Anions
WO2004072089, 26.08.2004 (15.01.2004).

2003

6.   M. Finze, S. E. Reybuck, R. M. Waymouth
Propylene Polymerization with 1,2’-Bridged Bis(indenyl)zirconium Dichlorides
Macromolecules 2003, 36, 9325–9334.
DOI: 10.1021/ma0303972
5.   E. Bernhardt, M. Finze, H. Willner
Eine effiziente Synthese von Tetracyanoboraten durch Sinterprozesse
An Efficient Synthesis for Tetracyanoborates by Sinter Processes
Z. Anorg. Allg. Chem. 2003, 629, 1229–1234.
DOI: 10.1002/zaac.200300047
4.   E. Bernhardt, M. Finze, H. Willner, C. W. Lehmann, F. Aubke
[Co(CO)5][(CF3)3BF]: A Stable Salt of a Homoleptic Trigonal-Bipyramidal Metal–Carbonyl Cation
Angew. Chem. Int. Ed. 2003, 42, 2077–2079.
DOI: 10.1002/anie.200250780
[Co(CO)5][(CF3)3BF]: ein stabiles Salz eines homoleptischen trigonal-bipyramidalen Metallcarbonyl-Kations
Angew. Chem. 2003, 115, 2123–2125.
DOI: 10.1002/ange.200250780
3.   M. Finze, E. Bernhardt, H. Willner, C. W. Lehmann
The Fluoracyltris(trifluoromethyl)borate Ion, [(CF3)3BC(O)F]–, a Fluoroacylboron Complex
Angew. Chem. Int. Ed. 2003, 42, 1052–1055.
DOI: 10.1002/anie.200390272
Das Fluoracyltris(trifluormethyl)borat-Ion, [(CF3)3BC(O)F]–, ein Fluoracylkomplex des Bors
Angew. Chem. 2003, 115, 1082–1085.
DOI: 10.1002/ange.200390247

2002

2.   R. M. Waymouth, G. M. Wilmes, M. Finze, S. E. Reybuck, S. Lin
Conformationally-Dynamic Metallocenes: Hypersensitive Systems for Modulating Stereochemistry
Polym. Mat. Sci. and Eng. 2002, 87, 48–49.
1.   M. Finze, E. Bernhardt, A. Terheiden, M. Berkei, H. Willner, D. Christen, H. Oberhammer, F. Aubke
Tris(trifluoromethyl)borane Carbonyl, (CF3)3BCO – Synthesis, Physical, Chemical and Spectroscopic Properties, Gas Phase and Solid State Structure
J. Am. Chem. Soc. 2002, 124, 15385–15398.
DOI: 10.1021/ja0209924