2002–2009
Veröffentlichungen (Peer-Review) & Patente
2009
33. | M. Finze, J. A. P. Sprenger Anionic Gold(I) Complexes – Twelve- and Ten-Vertex Monocarba-closo-borate Anions with Carbon-Gold σ Bonds Chem. Eur. J. 2009, 15, 9918–9927. DOI: 10.1002/chem.200901130 |
| 32. | M. Finze, G. J. Reiss Tetraethylammonium-12-phenylethinylcarba-closo-dodecaborate – [Et4N][12-PhCC-closo-CB11H11] Acta Crystallogr. 2009, E65, o1048. DOI: 10.1107/S1600536809013300 |
31. | M. Finze Regioselective Monoiodination of Carba-closo-dodecaborates: M[7-I-12-X-closo-CB11H10] (M = Cs+, [Et4N]+; X = F, Cl, Br, OH) Eur. J. Inorg. Chem. 2009, 501–507. DOI: 10.1002/ejic.200801046 |
| 30. | M. Finze Synthesis and Characterization of 2-Mono- and 1,2-Diaminocarba-closo-dodecaborates M[1-R-2-H2N-closo-CB11H10] (R=H, Ph, H2N, CyHN) Chem. Eur. J. 2009, 15, 947–962. DOI: 10.1002/chem.200801497 |
2008
| 29. | M. Finze Carba-closo-dodecaborates with One or Two Alkynyl Substituents Bonded to Boron Inorg. Chem. 2008, 47, 11857–11867. DOI: 10.1021/ic801610b |
| 28. | M. Finze, G. J. Reiss Salts with the Triborate Anion [B3O3F2(OH)2]–: A Combined Experimental and Theoretical Study Eur. J. Inorg. Chem. 2008, 2321–2325. DOI: 10.1002/ejic.200800068 |
2007
| 27. | M. Finze, E. Bernhardt, H. Willner Trifluoromethylboranes and -Borates: New Synthetic Strategies and Applications Angew. Chem. Int. Ed. 2007, 46, 9180–9196. DOI: 10.1002/anie.200700826 Trifluormethylborane und -borate – neue Synthesestrategien und Anwendungen Angew. Chem. 2007, 119, 9340-9357. DOI: 10.1002/ange.200700826 |
| 26. | M. Finze Carbon Extrusion/Cluster Contraction: Synthesis of the Fluorinated Cyano-closo-Undecaborate K2[3-NC-closo-B11F10] Angew. Chem. Int. Ed. 2007, 46, 8880–8882. DOI: 10.1002/anie.200703385 Kohlenstoff-Extrusion/Cluster-Kontraktion: Synthese des fluorierten Cyano-closo-undecaborats K2[3-NC-closo-B11F10] Angew. Chem. 2007, 119, 9036-9039. DOI: 10.1002/ange.200703385 |
| 25. | M. Finze, G. J. Reiss, M. Zähres [1-H2N-CB11F11]– – Synthesis and Reactions of a Functionalized Fluorinated Carbadodecaborate Anion Inorg. Chem. 2007, 46, 9873–9883. DOI: 10.1021/ic701398u |
| 24. | E. Bernhardt, D. J. Brauer, M. Finze, H. Willner closo-[B21H18]–: A Face-Fused Diicosahedral Borate Ion Angew. Chem. Int. Ed. 2007, 46, 2927–2930. DOI: 10.1002/anie.200604077 closo-[B21H18]− – ein flächenverknüpftes diikosaedrisches Borat-Ion Angew. Chem. 2007, 119, 2985–2988. DOI: 10.1002/ange.200604077 |
2006
| 23. | E. Bernhardt, M. Finze, H. Willner, C. W. Lehmann Salts of the Cobalt(I) Complexes [Co(CO)5]+ and [Co(CO)2(NO)2]+ and the Lewis Acid-Base Adduct [Co2(CO)7CO-B(CF3)3] Chem. Eur. J. 2006, 12, 8276–8283. DOI: 10.1002/chem.200600210 |
| 22. | E. Bernhardt, D. J. Brauer, M. Finze, H. Willner [B(CO2H)4]– and [B(CNCH3)4]3+: Homoleptic Boron Complexes Containing Carboxy and Methylisonitrile Ligands Angew. Chem. Int. Ed. 2006, 45, 6383–6386. DOI: 10.1002/anie.200601870 [B(CO2H)4]− und [B(CNCH3)4]3+ – homoleptische Borkomplexe mit Carboxy- und Methylisocyanid-Liganden Angew. Chem. 2006, 118, 6532–6534. DOI: 10.1002/ange.200601870 |
| 21. | M. Finze, E. Bernhardt, H. Willner, C. W. Lehmann (PPh3)3RhCNB(CF3)3 and (PPh3)3RhNCB(CF3)3 – Isocyano- and Cyanoborate Complexes of Tris(triphenylphosphin)rhodium(I) Organometallics 2006, 25, 3070–3075. DOI: 10.1021/om060135z |
| 20. | M. Finze, E. Bernhardt, H. Willner, C. W. Lehmann Reactions of (CF3)3BCO with Amines and Phosphines Inorg. Chem. 2006, 45, 669–678. DOI: 10.1021/ic0515305 |
| 19. | E. Bernhardt, M. Finze, H. Willner Eine neue Synthese für Nitrosyl-Salze mit schwach koordinierenden Anionen am Beispiel von NO[B(CF3)4] A New Synthesis for Nitrosyl Salts with Weakly Coordinating Anions Exemplified by NO[B(CF3)4] Z. Anorg. Allg. Chem. 2006, 632, 248–250. DOI: 10.1002/zaac.200500392 |
| 18. | M. Finze, E. Bernhardt, H. Willner, U. Welz-Biermann, N. Ignatyev Merck Patent GmbH, 64293 Darmstadt (Germany) Process for Preparation of Hydrogen Fluoroalkylborate Strong Acids and Their Binary and Complex Salts WO2006045405, 04.05.2006 (04.10.2005). |
| 17. | N. Ignatyev, U. Welz-Biermann, M. Finze, E. Bernhardt, H. Willner Merck Patent GmbH, 64293 Darmstadt (Germany) Preparation of Salts Containing Alkoxytris(fluoroalkyl)borate Anions as Ionic Liquids WO2006010455, 02.02.2006 (09.07.2005). |
2005
16. | M. Finze, E. Bernhardt, M. Berkei, H. Willner, J. Hung, R. M. Waymouth [H(OEt2)2]+ and [Ph3C]+ Salts of the Borate Anions [B(CF3)4]–, [(CF3)3BCN]–, and [B(CN)4]– Organometallics 2005, 24, 5103–5109. DOI: 10.1021/om050463j |
| 15. | M. Finze, E. Bernhardt, H. Willner, C. W. Lehmann Cyano- and Isocyanotris(trifluoromethyl)borates: Synthesis, Spectroscopic Properties and Solid State Structures of K[(CF3)3BCN] and K[(CF3)3BNC] J. Am. Chem. Soc. 2005, 127, 10712–10722. DOI: 10.1021/ja0516357 |
14. | M. Finze, E. Bernhardt, H. Willner, C. W. Lehmann Haloacylcomplexes of Boron, [(CF3)3BC(O)Hal]– (Hal = F, Cl, Br, I) Chem. Eur. J. 2005, 11, 6653–6665. DOI: 10.1002/chem.200500038 |
13. | M. Finze, E. Bernhardt, H. Willner, C. W. Lehmann, F. Aubke Homoleptic, σ-Bonded Octahedral Superelectrophilic Metal Carbonyl Cations of Iron(II), Ruthenium(II), and Osmium(II). Part 2: Syntheses and Characterizations of [M(CO)6][BF4]2 (M = Fe, Ru, Os) Inorg. Chem. 2005, 44, 4206–4214. DOI: 10.1021/ic0482483 |
| 12. | N. Ignatyev, U. Welz-Biermann, H. Willner, M. Finze, E. Bernhardt Merck Patent GmbH, 64293 Darmstadt (Germany) New stable, organic solvent-soluble cationic dyes with cyanoborate, fluoroalkyl phosphate, fluoroalkyl borate or imidate anion, useful e.g. for dyeing plastics, synthetic fibers or flexographic printing inks DE2003157359, 07.07.2005 (12.09.2003). |
| 11. | N. Ignatyev, U. Welz-Biermann, H. Willner, M. Finze, E. Bernhardt Merck Patent GmbH, 64293 Darmstadt (Germany) Fluoralkylborat-Farbstoffe DE200310338834, 24.03.2005 (21.08.2003); N. Ignatyev, U. Welz-Biermann, H. Willner, M. Finze, E. Bernhardt, A. Kucheryna Merck Patent GmbH, 64293 Darmstadt (Germany) Cyanoborate, Fluoroalkyl Phosphate, Fluoroalkyl Borate or Imide Dyes WO2005021661, 10.03.2005 (22.07.2004) |
2004
| 10. | M. Finze, E. Bernhardt, H. Willner, C. W. Lehmann [(CF3)3BCP]– and [(CF3)3BCAs]–: Thermally Stable Phosphaethynyl and Arsaethynyl Complexes Angew. Chem. Int. Ed. 2004, 43, 4159–4163. DOI: 10.1002/anie.200454034 [(CF3)3BCP]− und [(CF3)3BCAs]− –thermisch stabile Phosphaethinyl- und Arsaethinyl-Komplexe Angew. Chem. 2004, 116, 4254–4257. DOI: 10.1002/ange.200454034 |
| 9. | E. Bernhardt, M. Finze, H. Willner Synthesis and NMR spectroscopic investigation of salts containing the novel [Au(CF3)nX4–n]– (n = 4–1, X = F, CN, Cl) anions J. Fluorine Chem. 2004, 125, 967–973. DOI: 10.1016/j.jfluchem.2004.01.029 |
| 8. | M. Finze, E. Bernhardt, M. Zähres, H. Willner Rearrangement Reactions of the Transient Lewis Acids (CF3)3B and (CF3)3BCF2: An Experimental and Theoretical Study Inorg. Chem. 2004, 43, 490–505. DOI: 10.1021/ic0350640 |
| 7. | U. Welz-Biermann, N. Ignatyev, E. Bernhardt, M. Finze, H. Willner Merck Patent GmbH, 64293 Darmstadt (Germany) Process for Preparation of Hydrogen Fluoroalkylborate Strong Acids and Salze mit Cyanoborat-Anionen DE20031006617, 26.08.2004 (14.02.2003); Salts Comprising Cyanoborate Anions WO2004072089, 26.08.2004 (15.01.2004). |
2003
| 6. | M. Finze, S. E. Reybuck, R. M. Waymouth Propylene Polymerization with 1,2’-Bridged Bis(indenyl)zirconium Dichlorides Macromolecules 2003, 36, 9325–9334. DOI: 10.1021/ma0303972 |
| 5. | E. Bernhardt, M. Finze, H. Willner Eine effiziente Synthese von Tetracyanoboraten durch Sinterprozesse An Efficient Synthesis for Tetracyanoborates by Sinter Processes Z. Anorg. Allg. Chem. 2003, 629, 1229–1234. DOI: 10.1002/zaac.200300047 |
| 4. | E. Bernhardt, M. Finze, H. Willner, C. W. Lehmann, F. Aubke [Co(CO)5][(CF3)3BF]: A Stable Salt of a Homoleptic Trigonal-Bipyramidal Metal–Carbonyl Cation Angew. Chem. Int. Ed. 2003, 42, 2077–2079. DOI: 10.1002/anie.200250780 [Co(CO)5][(CF3)3BF]: ein stabiles Salz eines homoleptischen trigonal-bipyramidalen Metallcarbonyl-Kations Angew. Chem. 2003, 115, 2123–2125. DOI: 10.1002/ange.200250780 |
| 3. | M. Finze, E. Bernhardt, H. Willner, C. W. Lehmann The Fluoracyltris(trifluoromethyl)borate Ion, [(CF3)3BC(O)F]–, a Fluoroacylboron Complex Angew. Chem. Int. Ed. 2003, 42, 1052–1055. DOI: 10.1002/anie.200390272 Das Fluoracyltris(trifluormethyl)borat-Ion, [(CF3)3BC(O)F]–, ein Fluoracylkomplex des Bors Angew. Chem. 2003, 115, 1082–1085. DOI: 10.1002/ange.200390247 |
2002
| 2. | R. M. Waymouth, G. M. Wilmes, M. Finze, S. E. Reybuck, S. Lin Conformationally-Dynamic Metallocenes: Hypersensitive Systems for Modulating Stereochemistry Polym. Mat. Sci. and Eng. 2002, 87, 48–49. |
| 1. | M. Finze, E. Bernhardt, A. Terheiden, M. Berkei, H. Willner, D. Christen, H. Oberhammer, F. Aubke Tris(trifluoromethyl)borane Carbonyl, (CF3)3BCO – Synthesis, Physical, Chemical and Spectroscopic Properties, Gas Phase and Solid State Structure J. Am. Chem. Soc. 2002, 124, 15385–15398. DOI: 10.1021/ja0209924 |
