2010–2014

Veröffentlichungen (Peer-Review) & Patente

2014

66.	M. Hailmann, S. Z. Konieczka, A. Himmelspach, J. Löblein, G. J. Reiss, M. Finze *Carba-closo-dodecaborate Anions with Two Functional Groups: [1-R-12-HC≡C-closo-1-CB₁₁H₁₀]^– (R = CN, NC, CO₂H, C(O)NH₂, NHC(O)H)* Inorg. Chem. 2014, 53, 9385–9399. DOI: 10.1021/ic501526g

65.	K. Junold, J. A. Baus, C. Burschka, M. Finze, R. Tacke *Selective C–H Bond Activation of 1,2-Dicarba-closo-dodecaborane by the Donor-Stabilized Silylene Bis[N,N'-diisopropylbenzamidinato(–)]silicon(II)* Eur. J. Inorg. Chem. 2014, 5099–5102. DOI: 10.1002/ejic.201402685

64.	N. Ignatyev, J. A. P. Sprenger, J. Landmann, M. Finze Merck Patent GmbH, 64293 Darmstadt (Germany) Method for Producing Salts having Hydridocyanoborate Anions WO2014/198401A1, 18.12.2014 (14.06.2013).

63.	N. Ignatyev, J. A. P. Sprenger, J. Landmann, M. Finze Merck Patent GmbH, 64293 Darmstadt (Germany) Method for Producing Salts having Monofluoro-Tricyanoborate Anions WO2014/198402A1, 18.12.2014 (14.06.2013).

Nach oben

2013

62.	M. Hailmann, L. Herkert, A. Himmelspach, M. Finze *Difunctionalized {closo-1-CB₁₁} Clusters: 1- and 2-Amino-12-ethynylcarba-closo-dodecaborates* Chem. Eur. J. 2013, 51, 15745–15758. DOI: 10.1002/chem.201302931

61.	M. Drisch, J. A. P. Sprenger, M. Finze *Carba-closo-dodecaborate Anions with Cluster Carbon‒Phosphorous Bonds* Z. Anorg. Allg. Chem. 2013, 639, 1134–1139. DOI: 10.1002/zaac.201300130

60.	S. Schlecht, M. Finze, R. Bertermann, W. Frank, A. Domann, M. Braun Cocrystallising Rotamers of a Pentacoordinate Silicon Complex with a Chiral Aminodiol Ligand Eur. J. Inorg. Chem. 2013, 1488–1492. DOI: 10.1002/ejic.201201173

59.	R. T. Boeré, C. Bolli, M. Finze, A. Himmelspach, C. Knapp, T. L. Roemmele Quantum-Chemical and Electrochemical Investigation of the Electrochemical Windows of Halogenated Carborate Anions Chem. Eur. J. 2013, 51, 1784–1795. DOI: 10.1002/chem.201202475

58.	S. Z. Konieczka, A. Himmelspach, M. Hailmann, M. Finze *Synthesis, Characterization, and Selected Properties of 7- and 12-Ammoniocarba-closo-dodecaboranes* Eur. J. Inorg. Chem. 2013, 134–146. DOI: 10.1002/ejic.201200969

57.	N. Ignatyev, M. Schulte, K. Kawata, T. Goto, J. Sprenger, M. Finze, W. Frank Merck Patent GmbH, 64293 Darmstadt (Germany) Compounds containing alkyl-cyano-borate or alkyl-cyano-fluoroborate anions WO2013/010641A1, 24.01.2013 (15.07.2011).

56.	N. Ignatyev, M. Schulte, K. Kawata, T. Goto, J. Sprenger, M. Finze, W. Frank Merck Patent GmbH, 64293 Darmstadt (Germany) Compounds containing alkyl-alkoxy-cyano-borate anions WO2013/010640A1, 24.01.2013 (15.07.2011).

Nach oben

2012

55.	A. Himmelspach, M. Finze, A. Vöge, D. Gabel *Cesium and Tetrabutylammonium Salt of the Ethynyl-closo-dodecaborate Dianion* Z. Anorg. Allg. Chem. 2012, 638, 512–519. DOI: 10.1002/zaac.201100458 Cover Picture

54.	A. Himmelspach, G. J. Reiss, M. Finze *Microwave-assisted Kumada-type Cross-coupling Reactions of Iodinated Carba-closo-dodecaborate Anions* Inorg. Chem. 2012, 51, 2679–2688. DOI: 10.1021/ic202638k

53.

A. Himmelspach, J. A. P. Sprenger, J. Warneke, M. Zähres, M. Finze
Mercury(II) Complexes of the Carba-closo-dodecaboranyl Ligands [closo-1-CB₁₁X₁₁]^2– (X = H, F, Cl, Br, I)
Special Issue: Fluorine in Organometallic Chemistry
Organometallics 2012, 31, 1566–1577.
DOI: 10.1021/om201023h

52.	M. Finze, G. J. Reiß Ammonium 4,4-difluoro-1,3,2-dithiazetin-2-ide 1,1,3,3-tetraoxide Acta Crystallogr. 2012, E68, o1992–o1993. DOI: 10.1107/S1600536812024221

51.	M. Finze, G. J. Reiß, H.-J. Frohn 2,3,5,6-Tetrafluoro-1,4-bis(trimethylsilyl)benzene Acta Crystallogr. 2012, E68, o1082. DOI: 10.1107/S1600536812010677

50.	M. Finze, G. J. Reiß *Trimethylsulfonium 1-amino-6-fluoro-2,3,4,5,7,8,9,10,11,12-decaiodo-1-carba-closo-dodecaborate* Acta Crystallogr. 2012, E68, o640. DOI: 10.1107/S1600536812004424

49.	N. Ignatyev, M. Schulte, K. Kawata, J. Sprenger, M. Finze, W. Frank Merck Patent GmbH, 64293 Darmstadt (Germany) Electrolyte formulations containing cyano-alkoxy-borate anions WO2012/041434A1, 05.04.2012 (28.09.2010).

Nach oben

2011

48.	E. Bernhardt, M. Finze, H. Willner Mechanistic Study on the Fluorination of K[B(CN)₄] with ClF Enabling the High Yield and Large Scale Synthesis of K[B(CF₃)₄] and K[(CF₃)₃BCN] Inorg. Chem. 2011, 50, 10268–10273. DOI: 10.1021/ic201319h

47.

A. Himmelspach, M. Finze, S. Raub
Tetrahedral Gold(I) Clusters with Carba-closo-dodecaboranylethynido Ligands: [{12-(R3PAu)₂C≡C-closo-1-CB₁₁H₁₁}₂]
Angew. Chem. Int. Ed. 2011, 50, 2628–2631.
DOI: 10.1002/anie.201007239
Tetraedrische Gold(I)-Cluster mit Carba-closo-dodecaboranylethinido-Liganden: [{12-(R₃PAu)₂C≡C-closo-1-CB₁₁H₁₁}₂]
Angew. Chem. 2011, 115, 2123–2125.
DOI: 10.1002/ange.201007239

46.	A. Himmelspach, M. Zähres, M. Finze *Salts of the Lewis-Acidic Dianion [Hg(closo-1-CB₁₁F₁₁)₂]^2–: Coordination of Acetonitrile and Water* Inorg. Chem. 2011, 50, 3186–3188. DOI: 10.1021/ic200330d

45.	G. J. Reiß, M. Finze *(η⁴-s-cis-1,3-Butadiene)tetracarbonylchromium(0)* Acta Crystallogr. 2011, E67, m333. DOI: 10.1107/S1600536811004636

44.	A. Himmelspach, G. J. Reiß, M. Finze *2-Azaniumylcarba-closo-dodecaborate ethanol monosolvate* Acta Crystallogr. 2011, E67, o704. DOI: 10.1107/S1600536811006222

43.	G. J. Reiß, M. Finze *μ-η^2:2-s-trans-Butadieneoctacarbonyldiiron(0) – Structural and Spectroscopic Properties* J. Organomet. Chem. 2011, 696, 512–516. DOI: 10.1016/j.jorganchem.2010.09.009

42.

H. Shinohara, K. Kawata, H. Yoshizaki, P. Kirsch, N. Ignatyev, W.-R. Pitner, M. Schulte, J. A. Sprenger, M. Finze, W. Frank
Merck Patent GmbH, 64293 Darmstadt (Germany)
Compounds containing perfluoroalkyl-cyano-alkoxy-borate anions or perfluoroalkyl-cyano-alkoxy-fluoro-borate anions
WO2011/085967A1, 21.07.2011 (18.01.2010).

41.	N. Ignatyev, M. Schulte, J. A. Sprenger, M. Finze, W. Frank Merck Patent GmbH, 64293 Darmstadt (Germany) Method for producing perfluoroalkyl cyanoborates or perfluoroalkyl cyanofluoroborates WO2011/085966A1, 21.07.2011 (18.01.2010).

40.	K. Kawata, Yoshizaki, H. Shinohara, H. P. Kirsch, N. Ignatyev, M. Schulte, J. A. Sprenger, M. Finze, W. Frank Merck Patent GmbH, 64293 Darmstadt (Germany) Electrolyte Formulations WO2011/085965A1, 21.07.2011 (18.01.2010).

Nach oben

2010

39.	S. Konietzny, M. Finze, G. J. Reiß Tricarbonyl-6,6’-dimethylfulvene chromium(0) – Structural Properties J. Organomet. Chem. 2010, 695, 512–516. DOI: 10.1016/j.jorganchem.2010.05.017

38.	M. Finze, J. A. P. Sprenger *1-Amino-2-fluoromonocarba-closo-dodecaborates: K[1-H₂N-2-F-closo-1-CB₁₁H₁₀] and [Et₄N][1-H₂N-2-F-closo-1-CB₁₁I₁₀]* Z. Anorg. Allg. Chem. 2010, 636, 1538–1542. DOI: 10.1002/zaac.201000096

37.	M. Finze, G. J. Reiss *9-Ethynyl-1,2-dimethyl-1,2-dicarba-closo-dodecaborane (1,2-Me₂-9-HC≡C-closo-1,2-C₂B₁₀H₉)* Acta Crystallogr. 2010, E66, o1709–o1710. DOI: 10.1107/S1600536810022440

36.	A. Himmelspach, M. Finze *Dicarba-closo-dodecaboranes with One and Two Ethynyl Groups Bonded to Boron* Eur. J. Inorg. Chem. 2010, 2012–2024. DOI: 10.1002/ejic.201000064

35.	A. Himmelspach, M. Finze *Ethynylmonocarba-closo-dodecaborates: M[12-HCC-closo-1-CB₁₁H₁₁] and M[7,12-(HCC)₂-closo-1-CB₁₁H₁₀] (M= Cs⁺, [Et₄N]⁺)* J. Organomet. Chem. 2010, 695, 1337–1345. DOI: 10.1016/j.jorganchem.2010.02.011

34.	J. A. P. Sprenger, M. Finze, B. B. Schaack *Salts of the 1-cyanocarba-closo-dodecaborate anions* *[1-NC-closo-1-CB₁₁X₁₁]^–(X = H, F, Cl, Br, I)* Dalton Trans. 2010, 39, 2708-2716. DOI: 10.1039/B922720B