2015–2019
Veröffentlichungen (Peer-Review) & Patente
2019
127. | I. Simon, J. Hornung, J. Barthel, J. Thomas, M. Finze, R. A. Fischer, C. Janiak Synthesis of nickel/gallium nanoalloys using a dual-source approach in 1-alkyl-3-methylimidazole ionic liquids Beilstein J. Nanotechnol. 2019, 10, 1754–1767. DOI: 10.3762/bjnano.10.171 |
126. | T. Ribbeck, C. Kerpen, C. Schmidle, F. Keppner, J. A. P. Sprenger, M. Arrowsmith, H. Braunschweig, N. V. Ignat’ev, M. Finze Hydroxytricyanoborate Anion: Synthetic Aspects and Structural, Chemical, and Spectroscopic Properties Inorg. Chem. 2019, 58, 16689–16702. DOI: 10.1021/acs.inorgchem.9b02802 |
125. | J. He, F. Rauch, A. Friedrich, D. Sieh, T. Ribbeck, I. Krummenacher, H. Braunschweig, M. Finze, T. B. Marder N-Heterocyclic Olefins as Electron Donors in Combination with Triarylborane Acceptors: Synthesis, Optical and Electronic Properties of D–π–A Compounds Chem. Eur. J. 2019, 25, 13777–13784. DOI: 10.1002/chem.201903118 |
124. | N. V. Ignat'ev, M. Finze Cyaonoborates Eur. J. Inorg. Chem. 2019, 3539–3560. DOI: 10.1002/ejic.201900403 Cover Profile - Front Cover - |
123. | M. Hailmann, A. Himmelspach, F. Keppner, P. T. Hennig, R. Bertermann, M. Finze, B. Hupp, A. Steffen Carba-closo-dodecaboranylethynyl ligands facilitating luminescent reversed charge-transfer excited states in gold/silver complexes Chem. Commun. 2019, 55, 9351–9354. DOI: 10.1039/C9CC05060D |
122. | P. T. Hennig, J. A. P. Sprenger, L. N. Schneider, N. V. Ignat'ev, M. Finze The pentafluoroethylhydridoborate anion: From shock sensitive salts to stable room temperature ionic liquids Chem. Commun. 2019, 55, 6110–6113. DOI: 10.1039/C9CC02935D |
121. | R.-J. Li, M. Han, J. Tessarolo, J. J. Holstein, J. Lübben, B. Dittrich, C. Volkmann, M. Finze, C. Jenne, G. H. Clever Successive Photoswitching and Derivatization Effects in Photochromic Dithienylethene-Based Coordination Cages ChemPhotoChem 2019, 3, 378–383. DOI: 10.1002/cptc.201900038 |
120. | L. A. Bischoff, M. Drisch, C. Kerpen, P. T. Hennig, J. Landmann, J. A. P. Sprenger, R. Bertermann, M. Grüne, Q. Yuan, J. Warneke, X. Wang, N. Ignat'ev, M. Finze Cyanohydridoborate Anions: Synthesis, Salts, and Low-viscosity Ionic Liquids Chem. Eur. J. 2019, 25, 3560–3574. DOI: 10.1002/chem.201804698 |
119. | T. Ribbeck, C. Kerpen, D. Löw, A. E. Sedykha, K. Müller-Buschbaum, N. V. Ignat’ev, M. Finze Lanthanide trifluoromethyltricyanoborates: Synthesis, crystal structures and thermal properties J. Fluor. Chem. 2019, 219, 70–78. DOI: 10.1016/j.jfluchem.2018.12.013 |
118. | M. Lucas, S. J. Brotton, J. A. P. Sprenger, M. Finze, S. K. Sharma, R. I. Kaiser Oxidation of a Levitated 1‑Butyl-3-methylimidazolium Dicyanoborate Droplet by Nitrogen Dioxide J. Phys. Chem. A 2019, 123, 780–795. DOI: 10.1021/acs.jpca.8b11796 |
117. | J. Warneke, M. Rohdenburg, J. K. Y. Liu, E. Johnson, X. Ma, R. Kumar, P. Su, E. Aprà, X.-B. Wang, C. Jenne, M. Finze, H. I. Kenttämaa, J. Laskin Gas phase fragmentation of adducts between dioxygen and closo-borate radical anions Int. J. Mass Spectr. 2019, 436, 71–78. DOI: 10.1016/j.ijms.2018.11.005 |
116. | J. Warneke, S. Z. Konieczka, G.-L. Hou, E. Aprà, C. Kerpen, F. Keppner, T. C. Schäfer, M. Deckert, Z. Yang, E. J. Bylaska, G. E. Johnson, J. Laskin, S. S. Xantheas, X.-B. Wang, M. Finze Properties of perhalogenated {closo-B10} and {closo-B11} multiply charged anions and a critical comparison with {closo-B12} in the gas and the condensed phase Phys. Chem. Chem. Phys. 2019, 21, 5903–5915. DOI: 10.1039/C8CP05313H - Back Cover - |
2018
115. | S. H. Zottnick, W. G. Daul, C. Kerpen, M. Finze, K. Müller-Buschbaum Lanthanide Coordination Polymers and MOFs based on the Dicyanodihydridoborate Anion Chem. Eur. J. 2018, 24, 15287–15294. DOI: 10.1002/chem.201802627 |
114. | S. H. Zottnick, J. A. P. Sprenger, M. Finze, K. Müller-Buschbaum Transformation of [EMIm][BPB] into a Cationic Luminescent Ln‐Coordination Polymer with the Bis(phthalato)borate Anion Z. Anorg. Allg. Chem. 2018, 644, 1445–1450. DOI: 10.1002/zaac.201800254 |
113. | L. A. Bischoff, J. A. P. Sprenger, P. T. Hennig, N. V. Ignat'ev, M. Finze Chlorocyanoborates: Synthesis, Spectroscopic and Structural Characterization, and Properties of Ionic Liquids Z. Anorg. Allg. Chem. 2018, 644, 1285–1292. DOI: 10.1002/zaac.201800268 |
112. | S. Z. Konieczka, F. Schlüter, C. Sindorf, C. Kerpen, E. Bernhardt, M. Finze Stepwise Introduction of Cyano Groups into nido- and closo-Undecaborate Clusters Chem. Eur. J. 2018, 24, 3528–3538. DOI: 10.1002/chem.201704860 |
111. | S. Santner, J. A. P. Sprenger, M. Finze, S. Dehnen The Role of [BF4]– and [B(CN)4]– Anions in the Ionothermal Synthesis of Chalcogenidometalates Chem. Eur. J. 2018, 24, 3474–3480. DOI: 10.1002/chem.201705297 |
110. | J. A. P. Sprenger, C. Kerpen, N. Ignat'ev, M. Finze Convenient Synthesis of Perfluoroalkyltrifluoroborates J. Fluor. Chem. 2018, 206, 54–60. DOI: 10.1016/j.jfluchem.2017.12.004 |
109. | J. Landmann, J. A. P. Sprenger, P. T. Hennig, R. Bertermann, M. Grüne, F. Würthner, N. V. Ignat'ev, M. Finze Perfluoroalkyltricyanoborate and Perfluoroalkylcyanofluoroborate Anions: Building Blocks for Low-viscoity Ionic Liquids Chem. Eur. J. 2018, 24, 608–623. DOI: 10.1002/chem.201703685 - Front Cover - |
108. | M. Drisch, N. Ignatiev, M. Finze Merck Patent GmbH, 64293 Darmstadt (Germany) Verbindungen mit ein-, bis- und mehrfach geladenen schwach koordinierenden Anionen DE102016010488A1, 01.03.18 (30.08.2016). |
107. | J. A. P. Sprenger, P. T. Hennig, L. N. Schneider, N. Ignatiev, M. Finze Merck Patent GmbH, 64293 Darmstadt (Germany) Fluoralkylhydrido- und Fluoralkylcyanohydridoborate DE102016009846A1, 22.02.2018 (16.08.2016). |
2017
106. | M. Hailmann, N. Wolf, R. Renner, B. Hupp, A. Steffen, M. Finze Silver(I) Clusters with Carba-closo-dodecaboranylethynyl Ligands: Synthesis, Structure, and Phosphorescence Chem. Eur. J. 2017, 23, 11684–11693. DOI: 10.1002/chem.201702515 |
105. | S. H. Zottnick, M. T. Seuffert, C. Kerpen, M. Finze Homoleptic Luminescent Lanthanide Frameworks with the Tricyanohydridoborate Anion Eur. J. Inorg. Chem. 2017, 4668–4672. DOI: 10.1002/ejic.201700547 |
104. | J. Landmann, P. T. Hennig, N. V. Ignat'ev, M. Finze Borylation of Fluorinated Arenes with the Boron-centered Nucleophile B(CN)32-– a Unique Entry to Aryltricyanoborates Chem. Sci. 2017, 8, 5962–5968. DOI: 10.1039/C7SC02249B |
103. | Y. T. A. Wong, J. Landmann, M. Finze, D. L. Bryce Dynamic Disorder and Electronic Structures of Electron-Precise Dianionic Diboranes: Insights from Solid-State Multinuclear Magnetic Resonance Spectroscopy J. Am. Chem. Soc. 2017, 139, 8200–8211. DOI: 10.1021/jacs.7b01783 |
102. | N. Wolf, M. Hailmann, M. Finze Silver(I) Complexes of 12-Phenylalkynyl- and 12-Triisopropylalkynylcarba-closo-dodecaborate Anions Eur. J. Inorg. Chem. 2017, 4459–4466. DOI: 10.1002/ejic.201700379 |
101. | S. H. Zottnick, M. Finze, K. Müller-Buschbaum Transformation of the Ionic Liquid [EMIM][B(CN)4] into Anionic and Neutral Lanthanum Tetracyanoborate Coordination Polymers by Ionothermal Reactions Chem. Commun. 2017, 53, 5193–5195. DOI: 10.1039/C7CC01378G |
100. | F. Falk, L. Herkert, L. Hackbarth, K. Müller-Buschbaum, M. Finze, M. Köckerling Syntheses and Structures of New Rare Earth Metal Tetracyanidoborates Z. Anorg. Allg. Chem. 2017, 643, 625–630. DOI: 10.1002/zaac.201700040 |
99. | S. Zottnick, J. A. P. Sprenger, M. Finze, K. Müller-Buschbaum Bis-Salicylatoborate as Versatile Sensitizer for Highly Luminescent Ln-oxoborates from UV to NIR with 4f- and 5d-Participation of the Lanthanides Eur. J. Inorg. Chem. 2017, 10, 1355–1363. DOI: 10.1002/ejic.201601512 |
98. | T. Ribbeck, S. H. Zottnick, C. Kerpen, J. Landmann, N. V. Ignat'ev, K. Müller-Buschbaum, M. Finze Anhydrous, Homoleptic Lanthanide Frameworks with the Pentafluoroethyltricyanoborate Anion Inorg. Chem. 2017, 56, 2278–2286. DOI: 10.1021/acs.inorgchem.6b02984 |
97. | C. Kerpen, J. A. P. Sprenger, L. Herkert, M. Schäfer, L. A. Bischoff, P. Zeides, M. Grüne, R. Bertermann, F. A. Brede, K. Müller-Buschbaum, N. V. Ignat'ev, M. Finze Protonation versus Oxonium Salt Formation: Basicity and Stability Tuning of Cyanoborate Anions Angew. Chem. Int. Ed. 2017, 56, 2800–2804. DOI: 10.1002/anie.201611901 Protonierung kontra Oxoniumsalz-Bildung: Abstimmung der Basizität und Stabilität von Cyanoborat-Anionen Angew. Chem. 2017, 129, 2844–2848. DOI: 10.1002/ange.201611901 - Front Cover - |
96. | J. Landmann, F. Keppner, D. B. Hoffmann, J. A. P. Sprenger, M. Häring, S. H. Zottnick, K. Müller-Buschbaum, N. V. Ignat'ev, M. Finze Deprotonation of Hydridoborate Anion Angew. Chem. Int. Ed. 2017, 56, 2795–2799. DOI: 10.1002/anie.201611899 Deprotonierung eines Hydridoborat-Anions Angew. Chem. 2017, 129, 2389–2843. DOI: 10.1002/ange.201611899 - Front Cover - |
95. | S. H. Zottnick, J. R. Sorg, J. A. P. Sprenger, M. Finze, K. Müller-Buschbaum Unexpected Dimeric Spiro-Borate Complexes from Lewis-Acid Induced Transformation of Oxalatoborates Z. Anorg. Allg. Chem. 2017, 643, 53–59. DOI: 10.1002/zaac.201600319 |
94. | N. Arnold, R. Bertermann, F. M. Bickelhaupt, H. Braunschweig, M. Drisch, M. Finze, F. Hupp, J. Poater, J. A. P. Sprenger Formation of a Trifluorophosphane Platinum (II) Complex via P-F Bond Activation of Phosphorus Pentafluoride with a Pt(0) Complex Chem. Eur. J. 2017, 23, 5948–5952. DOI: 10.1002/chem.201604997 |
93. | J. A. P. Sprenger, M. Finze, N. Ignatiev Merck Patent GmbH, 64293 Darmstadt (Germany) Verfahren zur Herstellung von Salzen mit Monofluorotricyanoboratanionen DE102015016401A1, 22.06.2017 (18.12.2015). |
92. | J. A. P. Sprenger, M. Finze, N. Ignatiev Merck Patent GmbH, 64293 Darmstadt (Germany) Verfahren zur Herstellung von Salzen mit Perfluoralkyltricyanoboratanionen oder Tetracyanoboratanionen DE102015016400A1, 22.06.2017 (18.12.2015). |
91. | L. A. Bischoff, J. A. P. Sprenger, M. Finze, N. Ignatyev, M. Schulte Merck Patent GmbH, 64293 Darmstadt (Germany) Verfahren zur Herstellung von Kaliummonofluorotricyanoborat DE102016001344A1, 16.03.2017 (08.02.2016). |
2016
90. | K. Duda, A. Himmelsbach, J. Landmann, F. Kraus, M. Finze Synthesis of the Fluorohydridoborate Anions [BHF3]– and [1-HF2B-9,12-X2-closo-1,2-C2B10H9]– (X = H, I): Deboronation of 1,2- and 1,7-dicarba-closo-dodecaboranes with anhydrous [Me4N]F Chem. Commun. 2016, 52, 13241–13244. DOI: 10.1039/C6CC07711K |
89. | M. Arrowsmith, D. Auerhammer, R. Bertermann, H. Braunschweig, G. Bringmann, M. A. Celik, R. D. Dewhurst, M. Finze, M. Grüne, M. Hailmann, T. Hertle, I. Krummenacher Generation of Dicoordinate Boron(I) Units by Fragmentation of a Tetra-Boron(I) Molecular Square Angew. Chem. Int. Ed. 2016, 55, 14464–14468. DOI: 10.1002/anie.201608429 Erzeugung zweifach koordinierter Bor(I)-Einheiten durch Fragmentierung eines molekularen Tetra-Bor(I)-Quadrats Angew. Chem. 2003, 128, 14680–14684. DOI: 10.1002/ange.201608429 |
88. | M. Hailmann, N. Wolf, R. Renner, T. C. Schäfer, B. Hupp, A. Steffen, M. Finze Unprecedented Efficient Structure Controlled Phosphorescence of Silver(I) Clusters Stabilized by Carba-closo-dodecaboranylethynyl Ligands Angew. Chem. Int. Ed. 2016, 55, 10507–10511. DOI: 10.1002/anie.201604198 Ungewöhnlich effiziente strukturdirigierte Phosphoreszenz in Silber(I)-Clustern, realisiert mit Carba-closo-dodecaboranylethinyl-Liganden Angew. Chem. 2016, 128, 10663–10667. DOI: 10.1002/ange.201604198 |
87. | J. Warneke, T. Dülcks, D. Kemken, M. Finze Identification of a neutral loss from precursor ions with nearly Gaussian-shaped isotopic patterns via inverted isotopic patterns of product ions Rapid Commun. Mass. Spectrom. 2016, 30, 985–991. DOI: 10.1002/rcm.7522 |
86. | J. A. P. Sprenger, M. Finze, J. Landmann, A. Lennert, U. Schmid-Großmann, J. Eichhorn Merck Patent GmbH, 64293 Darmstadt (Germany) Polymere enthaltend polymerisierte ionische Flüssigkeiten und deren Anwendung in Membranen DE102015006493A1, 24.11.2016 (22.05.2015). |
85. | J. Landmann, F. Keppner, J. A. P. Sprenger, M. Finze, N. Ignatyev Merck Patent GmbH, 64293 Darmstadt (Germany) Verfahren zur Herstellung von Verbindungen mit Tricyanoborat-Dianionen DE20141018103 20141209, 09.06.2016 (09.12.2014). |
84. | M. Drisch, L. A. Bischoff, L. Herkert, J. A. P. Sprenger, M. Finze, N. Ignatyev, R. Van Hal Merck Patent GmbH, 64293 Darmstadt (Germany) Method for producing salts having hydridocyanoborate anions WO2016074760A1, 19.05.2016 (19.10.2015). |
83. | J. A. P. Sprenger, M. Finze, N. Ignatyev Merck Patent GmbH, 64293 Darmstadt (Germany) Method for producing perfluoralkylfluoroborate salts WO2016074756A1, 19.05.2016 (15.10.2015). |
82. | J. A. P. Sprenger, L. A. Bischoff, M. Drisch, L. Herkert, M. Finze, H. Willner, E. Bernhardt, N. Ignatyev, M. Schulte Merck Patent GmbH, 64293 Darmstadt (Germany) Method for producing compounds with monofluorotricyanoborate anions WO2016058665A1, 21.04.2016 (18.09.2015). |
81. | J. A. P. Sprenger, L. A. Bischoff, M. Finze, N. Ignatyev, M. Schulte Merck Patent GmbH, 64293 Darmstadt (Germany) Method for producing salts having hydridocyanoborate anions WO2016015811A1, 04.02.2016 (03.07.2014). |
2015
80. | J. A. P. Sprenger, S. Z. Konieczka, F. A. Brede, C. Kerpen, M. Hailmann, K.-D. Franz, N. Ignat'ev, G. J. Reiss, W. Frank, M. Finze N,N'-Bis(trifluoromethylsulfonyl)oxamidates – Syntheses, Thermal, Electrochemical, Spectroscopic, and Structural Properties Eur. J. Inorg. Chem. 2015, 5639–5649. DOI: 10.1039/C5CC00555H |
79. | N. V. Ignat’ev, M. Finze, J. A. P. Sprenger, C. Kerpen, E. Bernhardt, H. Willner New hydrophobic ionic liquids with perfluoroalkyl phosphate and cyanofluoroborate anions J. Fluor. Chem. 2015, 177, 46-54. DOI: 10.1016/j.jfluchem.2015.03.007 |
78. | J. Landmann, J. A. P. Sprenger, M. Hailmann, V. Bernhardt-Pitchougina, H. Willner, N. Ignat'ev, E. Bernhardt, M. Finze The Hexacyanodiborane(6) Dianion [B2(CN)6]2– Angew. Chem. Int. Ed. 2015, 54, 11259–11264. DOI: 10.1002/anie.201504579 Das Hexacyanodiboran(6)-Dianion [B2(CN)6]2– Angew. Chem. 2003, 127, 11411–1116. DOI: 10.1002/ange.201504579 |
77. | S. Z. Konieczka, M. Drisch, K. Edkins, M. Hailmann, M. Finze Polyfluorinated carba-closo-dodecaboranes with amino and ammonio substituents bonded to boron Dalton Trans. 2015, 44, 19576–19586. DOI: 10.1039/C5DT02055G – Hot Article – |
76. | J. A. P. Sprenger, J. Landmann, M. Drisch, N. Ignat'ev, M. Finze Syntheses of Tricyanofluoroborates M[BF(CN)3] (M = Na, K): (CH3)3SiCl Catalysis, Countercation Effect, and Reaction Intermediates Inorg. Chem. 2015, 54, 3403–3412. DOI: 10.1021/ic503077c |
75. | J. Landmann, J. A. P. Sprenger, R. Bertermann, N. Ignat'ev, V. Bernhardt-Pitchougina, E. Bernhardt, H. Willner, M. Finze Convenient Access to the Tricyanoborate Dianion B(CN)32– and Selected Reactions as a Boron-centred Nucleophile Chem. Commun. 2015, 51, 4989–4992. DOI: 10.1039/C5CC00555H |
74. | A. Himmelspach, J. Warneke, M. Schäfer, M. Hailmann, M. Finze Salts of the Dianions [Hg(12-X-closo-1-CB11H10)2] (X = I, C≡CH, C≡CFc, C≡CSiiPr3): Synthesis and Spectroscopic and Structural Characterization Organometallics 2015, 34, 462–469. DOI: 10.1021/om5009956 |
73. | M. Schäfer, I. Krummenacher, H. Braunschweig, M. Finze Boron Clusters with a Ferrocenylalkynyl Group Bonded to Boron: Synthesis, Characterization, and Electrochemical Trends Z. Anorg. Allg. Chem. 2015, 641, 660–668. DOI: 10.1002/zaac.201400524 |
72. | S. H. Zottnick, J. R. Sorg, J. A. P. Sprenger, M. Finze, K. Müller-Buschbaum 1∞[Pr(BSB)3(py)2]: A Lanthanide Bis(salicylato)borate at the Junction between Solvothermal and Ionothermal Conditions Z. Anorg. Allg. Chem. 2015, 641, 164–167. DOI: 10.1002/zaac.201400498 |
71. | J. A. P. Sprenger, M. Schäfer, N. Ignatiev, M. Finze Salts of Novel Chelatoborate Anions: [RFBX(ox)]– (RF = CF3, C2F5; X = F, OMe; ox = oxalato) and [RFB(OMe)(cat)]– (RF = CF3, C2F5; cat = catecholato) J. Fluorine Chem. 2015, 174, 30–35. DOI: 10.1016/j.jfluchem.2014.08.003 |
70. | J. A. P. Sprenger, J. Landmann, L. A. Bischoff, M. Finze, N. Ignatyev Merck Patent GmbH, 64293 Darmstadt (Germany) Method for preparing salts containing monohydrido-cyano-borate anions WO2015185183A1, 17.12.2015 (06.06.2014). |
69. | J. A. P. Sprenger, M. Finze, N. Ignatyev Merck Patent GmbH, 64293 Darmstadt (Germany) Method for preparing tetracyanoborate salts WO2015185178A1, 17.12.2015 (06.06.2014). |
68. | J. A. P. Sprenger, J. Landmann, M. Finze, N. Ignatyev, E. Bernhardt, H. Willner, M. Schulte, K. Kawata, T. Goto Merck Patent GmbH, 64293 Darmstadt (Germany) Kobaltkomplexsalze DE102013021029A1, 02.07.2015 (17.12.2013). |
67. | J. A. P. Sprenger, J. Landmann, M. Finze, V. Bernhardt-Pitchougina, N. Ignatyev, E. Bernhardt, H. Willner Merck Patent GmbH, 64293 Darmstadt (Germany) Hexacyanodiborates WO2015/022048A1, 19.02.2015 (16.08.2013). |