Intern
Arbeitsgruppe Finze

2015–2019

Veröffentlichungen (Peer-Review) & Patente

2019

127.   I. Simon, J. Hornung, J. Barthel, J. Thomas, M. Finze, R. A. Fischer, C. Janiak
Synthesis of nickel/gallium nanoalloys using a dual-source approach in 1-alkyl-3-methylimidazole ionic liquids
Beilstein J. Nanotechnol. 2019, 10, 1754–1767.
DOI: 10.3762/bjnano.10.171
126.   T. Ribbeck, C. Kerpen, C. Schmidle, F. Keppner, J. A. P. Sprenger, M. Arrowsmith, H. Braunschweig, N. V. Ignat’ev, M. Finze
Hydroxytricyanoborate Anion: Synthetic Aspects and Structural, Chemical, and Spectroscopic Properties
Inorg. Chem. 201958, 16689–16702.
DOI: 10.1021/acs.inorgchem.9b02802
125.   J. He, F. Rauch, A. Friedrich, D. Sieh, T. Ribbeck, I. Krummenacher, H. Braunschweig, M. Finze, T. B. Marder
N-Heterocyclic Olefins as Electron Donors in Combination with Triarylborane Acceptors: Synthesis, Optical and Electronic Properties of D–π–A Compounds
Chem. Eur. J. 2019, 25, 13777–13784.
DOI: 10.1002/chem.201903118
124.   N. V. Ignat'ev, M. Finze
Cyaonoborates
Eur. J. Inorg. Chem. 2019, 3539–3560.
DOI: 10.1002/ejic.201900403
Cover Profile
- Front Cover -

123.  

M. Hailmann, A. Himmelspach, F. Keppner, P. T. Hennig, R. Bertermann, M. Finze, B. Hupp, A. Steffen
Carba-closo-dodecaboranylethynyl ligands facilitating luminescent reversed charge-transfer excited states in gold/silver complexes
Chem. Commun2019, 55, 9351–9354.
DOI: 10.1039/C9CC05060D
122.   P. T. Hennig, J. A. P. Sprenger, L. N. Schneider, N. V. Ignat'ev, M. Finze
The pentafluoroethylhydridoborate anion: From shock sensitive salts to stable room temperature ionic liquids    
Chem. Commun. 2019, 55, 6110–6113.
DOI: 10.1039/C9CC02935D
121.   R.-J. Li, M. Han, J. Tessarolo, J. J. Holstein, J. Lübben, B. Dittrich, C. Volkmann, M. Finze, C. Jenne, G. H. Clever
Successive Photoswitching and Derivatization Effects in Photochromic Dithienylethene-Based Coordination Cages
ChemPhotoChem 2019, 3, 378–383.
DOI: 10.1002/cptc.201900038
120.   L. A. Bischoff, M. Drisch, C. Kerpen, P. T. Hennig, J. Landmann, J. A. P. Sprenger, R. Bertermann,  M. Grüne,  Q. Yuan, J. Warneke, X. Wang, N. Ignat'ev, M. Finze
Cyanohydridoborate Anions: Synthesis, Salts, and Low-viscosity Ionic Liquids
Chem. Eur. J. 2019, 25, 3560–3574.
DOI: 10.1002/chem.201804698
119.   T. Ribbeck, C. Kerpen, D. Löw, A. E. Sedykha, K. Müller-Buschbaum, N. V. Ignat’ev, M. Finze
Lanthanide trifluoromethyltricyanoborates: Synthesis, crystal structures and thermal properties
J. Fluor. Chem2019, 219, 70–78.
DOI: 10.1016/j.jfluchem.2018.12.013
118.   M. Lucas, S. J. Brotton, J. A. P. Sprenger, M. Finze, S. K. Sharma, R. I. Kaiser
Oxidation of a Levitated 1‑Butyl-3-methylimidazolium Dicyanoborate Droplet by Nitrogen Dioxide
J. Phys. Chem. A  2019, 123, 780–795.
DOI: 10.1021/acs.jpca.8b11796
117.   J. Warneke, M. Rohdenburg, J. K. Y. Liu, E. Johnson, X. Ma, R. Kumar, P. Su, E. Aprà, X.-B. Wang, C. Jenne, M. Finze, H. I. Kenttämaa, J. Laskin
Gas phase fragmentation of adducts between dioxygen and closo-borate radical anions
Int. J. Mass Spectr. 2019, 436, 71–78.
DOI: 10.1016/j.ijms.2018.11.005
116.   J. Warneke, S. Z. Konieczka, G.-L. Hou, E. Aprà, C. Kerpen, F. Keppner, T. C. Schäfer, M. Deckert, Z. Yang, E. J. Bylaska, G. E. Johnson, J. Laskin, S. S. Xantheas, X.-B. Wang, M. Finze
Properties of perhalogenated {closo-B10} and {closo-B11} multiply charged anions and a critical comparison with {closo-B12} in the gas and the condensed phase
Phys. Chem. Chem. Phys2019, 21, 5903–5915.
DOI: 10.1039/C8CP05313H
- Back Cover -

2018

115.   S. H. Zottnick, W. G. Daul, C. Kerpen, M. Finze, K. Müller-Buschbaum
Lanthanide Coordination Polymers and MOFs based on the Dicyanodihydridoborate Anion
Chem. Eur. J. 2018, 24, 15287–15294.
DOI: 10.1002/chem.201802627
114.   S. H. Zottnick, J. A. P.  Sprenger, M. Finze, K. Müller-Buschbaum
Transformation of [EMIm][BPB] into a Cationic Luminescent Ln‐Coordination Polymer with the Bis(phthalato)borate Anion
Z. Anorg. Allg. Chem2018, 644, 1445–1450.
DOI: 10.1002/zaac.201800254
113.   L. A. Bischoff, J. A. P. Sprenger, P. T. Hennig, N. V. Ignat'ev, M. Finze
Chlorocyanoborates: Synthesis, Spectroscopic and Structural Characterization, and Properties of Ionic Liquids
Z. Anorg. Allg. Chem2018, 644, 1285–1292.
DOI: 10.1002/zaac.201800268
112.   S. Z. Konieczka, F. Schlüter, C. Sindorf, C. Kerpen, E. Bernhardt, M. Finze
Stepwise Introduction of Cyano Groups into nido- and closo-Undecaborate Clusters
Chem. Eur. J. 2018, 24, 3528–3538.
DOI: 10.1002/chem.201704860

111.

S. Santner, J. A. P. Sprenger, M. Finze, S. Dehnen
The Role of [BF4] and [B(CN)4] Anions in the Ionothermal Synthesis of Chalcogenidometalates
Chem. Eur. J201824, 3474–3480.
DOI: 10.1002/chem.201705297
110.   J. A. P. Sprenger, C. Kerpen, N. Ignat'ev, M. Finze
Convenient Synthesis of Perfluoroalkyltrifluoroborates
J. Fluor. Chem. 2018, 206, 54–60.
DOI: 10.1016/j.jfluchem.2017.12.004

109.

J. Landmann, J. A. P. Sprenger, P. T. Hennig, R. Bertermann, M. Grüne, F. Würthner, N. V. Ignat'ev, M. Finze
Perfluoroalkyltricyanoborate and Perfluoroalkylcyanofluoroborate Anions: Building Blocks for Low-viscoity Ionic Liquids
Chem. Eur. J. 2018, 24, 608–623.
DOI: 10.1002/chem.201703685
- Front Cover -
108.   M. Drisch, N. Ignatiev, M. Finze
Merck Patent GmbH, 64293 Darmstadt (Germany)
Verbindungen mit ein-, bis- und mehrfach geladenen schwach koordinierenden Anionen
DE102016010488A1, 01.03.18 (30.08.2016).
107.   J. A. P. Sprenger, P. T. Hennig, L. N. Schneider, N. Ignatiev, M. Finze
Merck Patent GmbH, 64293 Darmstadt (Germany)
Fluoralkylhydrido- und Fluoralkylcyanohydridoborate
DE102016009846A1, 22.02.2018 (16.08.2016).

2017

106.   M. Hailmann, N. Wolf, R. Renner, B. Hupp, A. Steffen, M. Finze
Silver(I) Clusters with Carba-closo-dodecaboranylethynyl Ligands: Synthesis, Structure, and Phosphorescence
Chem. Eur. J. 2017, 23, 11684–11693.
DOI: 10.1002/chem.201702515
105.   S. H. Zottnick, M. T. Seuffert, C. Kerpen, M. Finze
Homoleptic Luminescent Lanthanide Frameworks with the Tricyanohydridoborate Anion
Eur. J. Inorg. Chem. 2017, 4668–4672.
DOI: 10.1002/ejic.201700547
104.   J. Landmann, P. T. Hennig, N. V. Ignat'ev, M. Finze
Borylation of Fluorinated Arenes with the Boron-centered Nucleophile B(CN)32-– a Unique Entry to Aryltricyanoborates
Chem. Sci. 2017, 8, 5962–5968.
DOI: 10.1039/C7SC02249B
103.   Y. T. A. Wong, J. Landmann, M. Finze, D. L. Bryce
Dynamic Disorder and Electronic Structures of Electron-Precise Dianionic Diboranes: Insights from Solid-State Multinuclear Magnetic Resonance Spectroscopy
J. Am. Chem. Soc. 2017, 139, 8200–8211.
DOI: 10.1021/jacs.7b01783
102.   N. Wolf, M. Hailmann, M. Finze
Silver(I) Complexes of 12-Phenylalkynyl- and 12-Triisopropylalkynylcarba-closo-dodecaborate Anions
Eur. J. Inorg. Chem. 2017, 4459–4466.
DOI: 10.1002/ejic.201700379
101.   S. H. Zottnick, M. Finze, K. Müller-Buschbaum
Transformation of the Ionic Liquid [EMIM][B(CN)4] into Anionic and Neutral Lanthanum Tetracyanoborate Coordination Polymers by Ionothermal Reactions
Chem. Commun. 2017, 53, 5193–5195.
DOI: 10.1039/C7CC01378G

100.

F. Falk, L. Herkert, L. Hackbarth, K. Müller-Buschbaum, M. Finze, M. Köckerling
Syntheses and Structures of New Rare Earth Metal Tetracyanidoborates
Z. Anorg. Allg. Chem. 2017, 643, 625–630.
DOI: 10.1002/zaac.201700040
99.   S. Zottnick, J. A. P. Sprenger, M. Finze, K. Müller-Buschbaum
Bis-Salicylatoborate as Versatile Sensitizer for Highly Luminescent Ln-oxoborates from UV to NIR with 4f- and 5d-Participation of the Lanthanides
Eur. J. Inorg. Chem. 2017, 10, 1355–1363.
DOI: 10.1002/ejic.201601512
98.   T. Ribbeck, S. H. Zottnick, C. Kerpen, J. Landmann, N. V. Ignat'ev, K. Müller-Buschbaum, M. Finze
Anhydrous, Homoleptic Lanthanide Frameworks with the Pentafluoroethyltricyanoborate Anion
Inorg. Chem. 2017, 56, 2278–2286.
DOI: 10.1021/acs.inorgchem.6b02984
97.   C. Kerpen, J. A. P. Sprenger, L. Herkert, M. Schäfer, L. A. Bischoff, P. Zeides, M. Grüne, R. Bertermann, F. A. Brede, K. Müller-Buschbaum, N. V. Ignat'ev, M. Finze
Protonation versus Oxonium Salt Formation: Basicity and Stability Tuning of Cyanoborate Anions
Angew. Chem. Int. Ed. 2017, 56, 2800–2804.
DOI: 10.1002/anie.201611901
Protonierung kontra Oxoniumsalz-Bildung: Abstimmung der Basizität und Stabilität von Cyanoborat-Anionen
Angew. Chem. 2017, 129, 2844–2848.
DOI: 10.1002/ange.201611901
- Front Cover -
96.   J. Landmann, F. Keppner, D. B. Hoffmann, J. A. P. Sprenger, M. Häring, S. H. Zottnick, K. Müller-Buschbaum, N. V. Ignat'ev, M. Finze
Deprotonation of Hydridoborate Anion
Angew. Chem. Int. Ed. 2017, 56, 2795–2799.
DOI: 10.1002/anie.201611899
Deprotonierung eines Hydridoborat-Anions
Angew. Chem. 2017, 129, 2389–2843.
DOI: 10.1002/ange.201611899
- Front Cover -

95.

S. H. Zottnick, J. R. Sorg, J. A. P. Sprenger, M. Finze, K. Müller-Buschbaum
Unexpected Dimeric Spiro-Borate Complexes from Lewis-Acid Induced Transformation of Oxalatoborates
Z. Anorg. Allg. Chem. 2017, 643, 53–59.
DOI: 10.1002/zaac.201600319
94.   N. Arnold, R. Bertermann, F. M. Bickelhaupt, H. Braunschweig, M. Drisch, M. Finze, F. Hupp, J. Poater, J. A. P. Sprenger
Formation of a Trifluorophosphane Platinum (II) Complex via P-F Bond Activation of Phosphorus Pentafluoride with a Pt(0) Complex
Chem. Eur. J. 2017, 23, 5948–5952.
DOI: 10.1002/chem.201604997
93.   J. A. P. Sprenger, M. Finze, N. Ignatiev
Merck Patent GmbH, 64293 Darmstadt (Germany)
Verfahren zur Herstellung von Salzen mit Monofluorotricyanoboratanionen
DE102015016401A1, 22.06.2017 (18.12.2015).
92.   J. A. P. Sprenger, M. Finze, N. Ignatiev
Merck Patent GmbH, 64293 Darmstadt (Germany)
Verfahren zur Herstellung von Salzen mit Perfluoralkyltricyanoboratanionen oder Tetracyanoboratanionen
DE102015016400A1, 22.06.2017 (18.12.2015).
91.   L. A. Bischoff, J. A. P. Sprenger, M. Finze, N. Ignatyev, M. Schulte
Merck Patent GmbH, 64293 Darmstadt (Germany)
Verfahren zur Herstellung von Kaliummonofluorotricyanoborat
DE102016001344A1, 16.03.2017 (08.02.2016).

2016

90.   K. Duda, A. Himmelsbach, J. Landmann, F. Kraus, M. Finze
Synthesis of the Fluorohydridoborate Anions [BHF3] and [1-HF2B-9,12-X2-closo-1,2-C2B10H9] (X = H, I): Deboronation of 1,2- and 1,7-dicarba-closo-dodecaboranes with anhydrous [Me4N]F
Chem. Commun. 2016, 52, 13241–13244.
DOI: 10.1039/C6CC07711K
89.   M. Arrowsmith, D. Auerhammer, R. Bertermann, H. Braunschweig, G. Bringmann, M. A. Celik, R. D. Dewhurst, M. Finze, M. Grüne, M. Hailmann, T. Hertle, I. Krummenacher
Generation of Dicoordinate Boron(I) Units by Fragmentation of a Tetra-Boron(I) Molecular Square
Angew. Chem. Int. Ed. 2016, 55, 14464–14468.
DOI: 10.1002/anie.201608429
Erzeugung zweifach koordinierter Bor(I)-Einheiten durch Fragmentierung eines molekularen Tetra-Bor(I)-Quadrats
Angew. Chem. 2003, 128, 14680–14684.
DOI: 10.1002/ange.201608429
88.   M. Hailmann, N. Wolf, R. Renner, T. C. Schäfer, B. Hupp, A. Steffen, M. Finze
Unprecedented Efficient Structure Controlled Phosphorescence of Silver(I) Clusters Stabilized by Carba-closo-dodecaboranylethynyl Ligands
Angew. Chem. Int. Ed2016, 55, 10507–10511.
DOI: 10.1002/anie.201604198
Ungewöhnlich effiziente strukturdirigierte Phosphoreszenz in Silber(I)-Clustern, realisiert mit Carba-closo-dodecaboranylethinyl-Liganden
Angew. Chem. 2016, 128, 10663–10667.
DOI: 10.1002/ange.201604198
87.   J. Warneke, T. Dülcks, D. Kemken, M. Finze
Identification of a neutral loss from precursor ions with nearly Gaussian-shaped isotopic patterns via inverted isotopic patterns of product ions 
Rapid Commun. Mass. Spectrom. 2016, 30, 985–991.
DOI: 10.1002/rcm.7522
86.   J. A. P. Sprenger, M. Finze, J. Landmann, A. Lennert, U. Schmid-Großmann, J. Eichhorn
Merck Patent GmbH, 64293 Darmstadt (Germany)
Polymere enthaltend polymerisierte ionische Flüssigkeiten und deren Anwendung in Membranen
DE102015006493A1, 24.11.2016 (22.05.2015).
85.   J. Landmann, F. Keppner, J. A. P. Sprenger, M. Finze, N. Ignatyev
Merck Patent GmbH, 64293 Darmstadt (Germany)
Verfahren zur Herstellung von Verbindungen mit Tricyanoborat-Dianionen
DE20141018103 20141209, 09.06.2016 (09.12.2014).
84.   M. Drisch, L. A. Bischoff, L. Herkert, J. A. P. Sprenger, M. Finze, N. Ignatyev, R. Van Hal
Merck Patent GmbH, 64293 Darmstadt (Germany)
Method for producing salts having hydridocyanoborate anions
WO2016074760A1, 19.05.2016 (19.10.2015).
83.   J. A. P. Sprenger, M. Finze, N. Ignatyev
Merck Patent GmbH, 64293 Darmstadt (Germany)
Method for producing perfluoralkylfluoroborate salts
WO2016074756A1, 19.05.2016 (15.10.2015).
82.   J. A. P. Sprenger, L. A. Bischoff, M. Drisch, L. Herkert, M. Finze, H. Willner, E. Bernhardt, N. Ignatyev, M. Schulte
Merck Patent GmbH, 64293 Darmstadt (Germany)
Method for producing compounds with monofluorotricyanoborate anions
WO2016058665A1, 21.04.2016 (18.09.2015).
81.   J. A. P. Sprenger, L. A. Bischoff, M. Finze, N. Ignatyev, M. Schulte
Merck Patent GmbH, 64293 Darmstadt (Germany)
Method for producing salts having hydridocyanoborate anions 
WO2016015811A1, 04.02.2016 (03.07.2014).

2015

80.   J. A. P. Sprenger, S. Z. Konieczka, F. A. Brede, C. Kerpen, M. Hailmann, K.-D. Franz, N. Ignat'ev, G. J. Reiss, W. Frank, M. Finze
N,N'-Bis(trifluoromethylsulfonyl)oxamidates – Syntheses, Thermal, Electrochemical, Spectroscopic, and Structural Properties 
Eur. J. Inorg. Chem. 2015, 5639–5649.
DOI: 10.1039/C5CC00555H
79.   N. V. Ignat’ev,  M. Finze, J. A. P. Sprenger, C. Kerpen, E. Bernhardt,  H. Willner
New hydrophobic ionic liquids with perfluoroalkyl phosphate and cyanofluoroborate anions
J. Fluor. Chem. 2015, 177, 46-54.
DOI: 10.1016/j.jfluchem.2015.03.007
78.   J. Landmann, J. A. P. Sprenger, M. Hailmann, V. Bernhardt-Pitchougina, H. Willner, N. Ignat'ev, E. Bernhardt, M. Finze
The Hexacyanodiborane(6) Dianion [B2(CN)6]2– 
Angew. Chem. Int. Ed. 201554, 11259–11264.
DOI: 10.1002/anie.201504579
Das Hexacyanodiboran(6)-Dianion [B2(CN)6]2– 
Angew. Chem. 2003, 127, 11411–1116.
DOI: 10.1002/ange.201504579
77.   S. Z. Konieczka, M. Drisch, K. Edkins, M. Hailmann, M. Finze
Polyfluorinated carba-closo-dodecaboranes with amino and ammonio substituents bonded to boron 
Dalton Trans. 2015, 44, 19576–19586.
DOI: 10.1039/C5DT02055G
– Hot Article –
76.   J. A. P. Sprenger, J. Landmann, M. Drisch, N. Ignat'ev, M. Finze
Syntheses of Tricyanofluoroborates M[BF(CN)3] (M = Na, K): (CH3)3SiCl Catalysis, Countercation Effect, and Reaction Intermediates 
Inorg. Chem. 201554, 3403–3412.
DOI: 10.1021/ic503077c
75.   J. Landmann, J. A. P. Sprenger, R. Bertermann, N. Ignat'ev, V. Bernhardt-Pitchougina, E. Bernhardt, H. Willner, M. Finze
Convenient Access to the Tricyanoborate Dianion B(CN)32– and Selected Reactions as a Boron-centred Nucleophile
Chem. Commun. 201551, 4989–4992.
DOI: 10.1039/C5CC00555H
74.   A. Himmelspach, J. Warneke, M. Schäfer, M. Hailmann, M. Finze
Salts of the Dianions [Hg(12-X-closo-1-CB11H10)2] (X = I, C≡CH, C≡CFc, C≡CSiiPr3): Synthesis and Spectroscopic and Structural Characterization 
Organometallics 201534, 462–469.
DOI: 10.1021/om5009956
73.   M. Schäfer, I. Krummenacher, H. Braunschweig, M. Finze
Boron Clusters with a Ferrocenylalkynyl Group Bonded to Boron: Synthesis, Characterization, and Electrochemical Trends
Z. Anorg. Allg. Chem. 2015641, 660–668.
DOI: 10.1002/zaac.201400524
72.   S. H. Zottnick, J. R. Sorg, J. A. P. Sprenger, M. Finze, K. Müller-Buschbaum
1[Pr(BSB)3(py)2]: A Lanthanide Bis(salicylato)borate at the Junction between Solvothermal and Ionothermal Conditions 
Z. Anorg. Allg. Chem. 2015641, 164–167.
DOI: 10.1002/zaac.201400498
71.   J. A. P. Sprenger, M. Schäfer, N. Ignatiev, M. Finze
Salts of Novel Chelatoborate Anions: [RFBX(ox)] (RF = CF3, C2F5; X = F, OMe; ox = oxalato) and [RFB(OMe)(cat)] (RF = CF3, C2F5; cat = catecholato)
J. Fluorine Chem. 2015174, 30–35.
DOI: 10.1016/j.jfluchem.2014.08.003
70.   J. A. P. Sprenger, J. Landmann, L. A. Bischoff, M. Finze, N. Ignatyev
Merck Patent GmbH, 64293 Darmstadt (Germany)
Method for preparing salts containing monohydrido-cyano-borate anions 
WO2015185183A1, 17.12.2015 (06.06.2014).
69.   J. A. P. Sprenger, M. Finze, N. Ignatyev
Merck Patent GmbH, 64293 Darmstadt (Germany)
Method for preparing tetracyanoborate salts    
WO2015185178A1, 17.12.2015 (06.06.2014).
68.   J. A. P. Sprenger, J. Landmann, M. Finze, N. Ignatyev, E. Bernhardt, H. Willner, M. Schulte, K. Kawata, T. Goto
Merck Patent GmbH, 64293 Darmstadt (Germany)
Kobaltkomplexsalze    
DE102013021029A1, 02.07.2015 (17.12.2013).
67.   J. A. P. Sprenger, J. Landmann, M. Finze, V. Bernhardt-Pitchougina, N. Ignatyev, E. Bernhardt, H. Willner
Merck Patent GmbH, 64293 Darmstadt (Germany)
Hexacyanodiborates    
WO2015/022048A1, 19.02.2015 (16.08.2013).