Publications

1961

1
Greene, F.D.; Adam, W.; Cantrill, J.E.
Diacyl Peroxide-Olefin Reactions. Evidence for a Direct Reaction J. Am. Chem. Soc., 1961, 83, 3461-3468

1962

 

1963

2
Greene, F.D.; Adam, W.
Autoxidation of Galvinoxyl
J. Org. Chem., 1963, 28, 3550-3551

3
Adam, W.
Studies on the Cyclobutadienyl Dianion
Tetrahedron Lett., 1963, 1387-1392

1964

4
Greene, F.D.; Adam, W.
Diacyl Peroxide-Olefin Reactions. Epoxidation of Tetramethylethylene by an Aroyl Peroxide
J. Org. Chem., 1964, 29, 136-139

5
Adam, W.
Die thermische Isomerisierung von 3,4-disubstituierten Tetramethylcyclobutenen
Chem. Ber., 1964, 97, 1811-1817

1965

6
Adam, W.; Grimison, A.
Extended Hückel Theory Applied to Nucleophilic Substitution in Pyridine, Quinoline and Isoquinoline
Tetrahedron, 1965, 21, 3417-3422

1966

7
Adam, W.; Grimison, A.
Extended Hückel Theory Applied to Electrophilic Substitution in Imidazole
Tetrahedron, 1966, 22, 835-839

8
Greene, F.D.; Adam, W.; Knudsen, G.A., Jr.
A Cyclic Peroxy Ester, ß-Methyl-ß-phenyl-ß-peroxypropiolactone
J. Org. Chem., 1966, 31, 2087-2090

1967

9
Adam, W.; Grimison, A.; Rodriguez, G.
Effects of Protonation on Electron Densities in Nitrogen Heterocyclic Molecules
Tetrahedron, 1967, 23, 2513-2521

10
Adam, W.; Grimison, A.
Sigma-Polarization in 5-Membered Heterocyclic Ring Systems
Theoret. Chim. Acta (Berlin), 1967, 7, 342-351

1968

11
Adam, W.; Grimison, A.; Hoffmann, R.; Zuazaga de Ortiz, C.
Hydrogen Bonding in Pyridine
J. Am. Chem. Soc., 1968, 90, 1509-1516

1969

12
Adam, W.; Grimison, A.; Rodriguez, G.
Average-Excitation-Energy Approximation in the Calculation of Carbon-13 Chemical Shifts of Nitrogen Heterocyclics
J. Chem. Phys., 1969, 50, 645-654

13
Adam, W.; Grimison, A.; Hoffmann, R.
Hetaryne Intermediates
J. Am. Chem. Soc., 1969, 91, 2590-2599

14
Adam, W.; Ramirez, R.J.; Tsai, S.-C.
Cyclic Peroxyesters II. A Novel Ketene Elimination and Decarboxylation Reaction
J. Am. Chem. Soc., 1969, 91, 1254-1256

15
Adam, W.; Cheng, Y.M.
Cyclic Peroxyesters III. Kinetics and Products of the Rearrangement of Thermally Generated Oxygen Diradicals
J. Am. Chem. Soc., 1969, 91, 2109-2110

16
Adam, W.; Cheng, Y.M.; Wilkerson, C.; Zaidi, W.A.
Cyclic Peroxyesters. IV. Stereochemistry of the Rearrangement of Thermally Generated Oxygen Diradicals
J. Am. Chem. Soc., 1969, 91, 2111-2112

17
Adam, W.
Differential Scanning Calorimetry
Rev. Col. Quim. Puerto Rico, 1969, 28, 2-6

18
Adam, W.; Chang, J.C.
The Kinetics and Thermochemistry of Valence Isomerization by Differential Scanning Calorimetry: The Case of Hexamethylprismane and Hexamethyldewarbenzene
Int. J. Chem. Kin., 1969, 1, 487-492

1970

19
Adam, W.
Lone-Pair Interactions in Six-Membered Ring Nitrogen Heterocycles
Jerusalem Symp. Quant. Chem., 1970, 2, 118-127

20
Adam, W.; Grimison, A.; Sprangle, P.-A.
Convergence of the Perturbation Theory Expansion for Spin-Spin Coupling Constants
Theoret. Chim. Acta (Berlin), 1970, 18, 385-388

1971

21
Adam, W.; Rios, A.
Ionic Peroxide Reactions. The Mechanism of the Reaction of Peroxycarbonates with Trivalent Phosphorus Nucleophiles
J. Org. Chem., 1971, 36, 407-411

22
Adam, W.; Rucktäschel, R.
Cyclic Peroxides: V. An a-Lactone Intemediate via Photodecarboxylation of a Monomeric Malonyl Peroxide
J. Am. Chem. Soc., 1971, 93, 557-559

23
Adam, W.; Chiu, W.T.
The Mechanism of a Rate-Controlled Cross-Disproportionation between Phenoxyl Radicals
J. Am. Chem. Soc., 1971, 93, 3687-3693

24
Adam, W.; Rios, A.
Perhydrolysis of Epoxides
Chem. Commun., 1971, 822-823

25
Adam, W.; Santiago Aponte, G.
Cyclic Peroxides. VI. Oxatrimethylene Diradicals via Photodecarboxylation of ß-Peroxylactones
J. Am. Chem. Soc., 1971, 93, 4300-4301

26
Adam, W.; Szendrey, L.M.
Synthesis of g-Methyl-g-peroxyvalerolactone, its Thermolysis and Photolysis
Chem. Commun., 1971, 1299-1300

27
Adam, W.; Wilkerson, C.
Suprafacial Alkyl 1,2-Shift in the Rearrangement of Thermally Generated Oxygen Diradicals
Chem. Commun., 1971, 1569-1570

28
Adam, W.; Sanabia, J.
Differential Scanning Calorimetry Applied to the Thermolysis of Peroxalates
Thermal Analysis, 1971, 2, 475-485

1972

29
Adam, W.; Baeza, J.; Liu, J.-C.
Stereospecific Introduction of Double Bonds via Thermolysis of ß-Lactones
J. Am. Chem. Soc., 1972, 94, 2000-2006

30
Adam, W.; Liu, J.-C.
Photooxygenation (Singlet Oxygen) of Tetrathioethylenes
J. Am. Chem. Soc., 1972, 95, 1206-1209

31
Adam, W.; Arce, J.
Stereospecific Dehalogenation of vic-Dibromides by Sodium Naphthalenide
J. Org. Chem., 1972, 37, 507-508

32
Adam, W.; Sanabia, J.
Synthesis of a Novel Cyclic Peroxalate, its Thermolysis and Photolysis
Chem. Commun., 1972, 174-175

33
Adam, W.; Baeza, J.
Conformational Effects in the Rearrangement of Thermally Generated Oxygen Diradicals
Chem. Commun., 1972, 103-104

34
Chapman, O.L.; Wojtkowski, P.W.; Adam, W.; Rodriguez, O.; Rucktäschel, R.
Synthesis and Chemistry of a-Lactones
J. Am. Chem. Soc., 1972, 95, 1365-1367

35
Adam, W.; Duran, N.
Thermolysis of 1,2-Dioxolanes
Chem. Commun., 1972, 1357-1358

36
Adam, W.; Duran, N.
Photolysis of 1,2-Dioxolanes
Tetrahedron Lett., 1972, 1357-1358

37
Adam, W.; Liu, J.-C.
Singlet Oxygen Addition to Thioethylenes
Chem. Commun., 1972, 73-74

38
Wieringa, J.H.; Strating, J.; Wynberg, H.; Adam, W.
Adamantylideneadamantane Peroxide. A Stable 1,2 Dioxetane
Tetrahedron Lett., 1972, 2, 169-172

39
Adam, W.
The Chemistry of Bioluminescence
Rev. Col. Quim. Puerto Rico, 1972, 31, 11-18

40
Adam, W.; Liu, J.-C.
An a-Peroxylactone. Synthesis and Chemiluminescence
J. Am. Chem. Soc., 1972, 94, 2894-2895

41
Adam, W.; Duran, N.
1,2,4-Trioxepans: Synthesis and Mass Spectral Behaviour
Chem. Commun., 1972, 798-799

42
Adam, W.; Szendrey, L.M.
Perhydrolysis of g-Lactones. A Novel Bayer-Villiger Oxidation
Tetrahedron Lett., 1972, 2669-2672

43
Adam, W.; Steinmetzer, H.-C.
(1-Adamantyl)-a-peroxylactone: Synthesis, Kinetics and Luminescence
Angew. Chem., 1972, 94, 590-592; Angew. Chem., Int. Ed. Engl., 1972, 11, 540-542

44
Adam, W.; Diehl, J.W.
Triphenylphosphine Deoxygenation of Malonyl Peroxides. A Novel Route to Malonyl Anhydrides
Chem. Commun., 1972, 797-798

45
Adam, W.; Rojas, C.I.
Novel Synthesis of ß-Peroxylactones via Perhydrolysis of ß-Lactones
Synthesis, 1972, 616-618

46
Adam, W.; Rucktäschel, R.
Cyclic Peroxides XVII. Solvolysis of Di-n-butylmalonoyl Peroxide
J. Org. Chem., 1972, 37, 4128-4133

1973

47
Adam, W.; Duran, N.
1,3-Diradicals via Thermolysis of 1,2-Dioxolanes
J. Org. Chem., 1973, 38, 1434-1436

48
Adam, W.; Liu, J.-C.; Rodriguez, O.
Bis(trifluoromethyl)acetolactone, a Stable a-Lactone
J. Org. Chem., 1973, 38, 2269-2270

49
Adam, W.; Arce de Sanabia, J.; Fischer, H.
CIDNP Evidence for Radical Pair Mechanism in Photo-Fries Rearrangement
J. Org. Chem., 1973, 38, 2571-2572

50
Adam, W.; Fischer, H.; Hansen, H.-J.; Heimgartner, H.; Schmid, H.; Waespe, H.-R.
CIDNP Evidence for Divergent Behavior of Singlet and Triplet Radical Pair Encounters in the Photo-Claisen Rearrangement
Angew. Chem., 1973, 85, 669-671; Angew. Chem., Int. Ed. Engl., 1973, 12, 662-663

51
Adam, W.; Sanabia, J.
Concerted Fragmentation of a 1,6-Diradical on Thermolysis of 1,2-Dioxanes
Angew. Chem., 1973, 85, 914-915; Angew. Chem., Int. Ed. Engl., 1973, 12, 843-845

52
Adam, W.
Biologisches Licht
Chemie in unserer Zeit, 1973, 7, 182-192

1974

53
Turro, N.J.; Lechtken, P.; Schuster, G.B.; Orell, J.; Steinmetzer, H.-C.; Adam, W.
Indirect Chemiluminescence by 1,2-Dioxetanes. Evaluation of Triplet Singlet Excitation Efficiencies. A Long Range Singlet-Singlet Energy Transfer and an Efficient Triplet-Singlet Energy Transfer
J. Am. Chem. Soc., 1974, 96, 1627-1629

54
Batich, C.; Adam, W.
The Photoelectron Spectra of Alkyl Peroxides
Tetrahedron Lett., 1974, 1467-1470

55
Adam, W.
The Synthesis of Unusual Organic Molecules Using Cyclic Peroxides
Angew. Chem., 1974, 8, 683-691; Angew. Chem., Int. Ed. Engl., 1974, 13, 619-628

56
Adam, W.
The Multiplicity of the Photo-Fries Rearrangement
Chem. Commun., 1974, 289-290

57
Adam, W.; Simpson, G.A.; Yany, F.
Mechanism of Direct and Rubrene Enhanced Chemiluminescence during a-Peroxylactone Decarboxylation
J. Phys. Chem., 1974, 78, 2559-2569

58
Adam, W.; Szendrey, L.M.
Intervention of the 1,4-Diradical 1-Oxatetramethylene in the Thermodecarboxylation of g-Peroxylactones
J. Am. Chem. Soc., 1974, 96, 7135-7137

1975

59
Adam, W.; Arce, J.
Thermolysis of the Cyclic Peroxide 4-Ethylidene-3,3,5,5-tetramethyl-1,2-dioxolane. Generation and Trapping of a 1,5-Diradical
J. Am. Chem. Soc., 1975, 97, 926-928

60
Adam, W.
Singlet Molecular Oxygen and its Role in Organic Peroxide Chemistry
Chem.-Zeitung, 1975, 99, 142-155

61
Schuster, G.B.; Turro, N.J.; Steinmetzer, H.-C.; Schaap, A.P.; Faler, G.; Adam, W.; Liu, J.-C.
Adamantylideneadamantane-1,2-dioxetane. An Investigation of the Chemiluminescence and Decomposition Kinetics of an Usually Stable 1,2-Dioxetane
J. Am. Chem. Soc., 1975, 97, 7110-7118

62
Adam, W.; Duran, N.; Simpson, G.A.
Singlet Acetone Efficiency and Importance of Triplet Acetone Induced Decomposition of Tetramethyl-1,2-dioxetane from Direct Chemiluminescence
J. Am. Chem. Soc., 1975, 97, 5464-5467

63
Adam, W.
Biological Light: Peroxylates as Bioluminescent Intermediates
J. Chem. Educ., 1975, 52, 138-145

64
Adam, W.
The Synthesis of Unusual Organic Molecules Using Cyclic Peroxide
New Synthetic Methods, 1975, 1, 109-132

1976

65
Adam, W.; Liu, J.-C.; Rodriguez, O.
Bis(Trifluoromethyl)acetolactone
Org. Photochem. Synth., 1976, 2, 13-16

66
Adam, W.; Liu, J.-C.; Strating, J.; Wieringa, J. H.; Wynberg, H.
Bisadamantylidene-1,2-dioxetane
Org. Photochem. Synth., 1976, 2, 10-12

67
Adam, W.; Cueto, O.; Ehrig, V.
a-Hydroperoxy Acids via Direct Oxygenation
J. Org. Chem., 1976, 41, 370-371

68
Adam, W.; Ehrig, V.
Direct a-Lithiation of 4,5-Dihydro-1,3-thiazole-4-carboxylic Acids and Electrophilic Substitution
Synthesis, 1976, 817-820

69
Duran, N.; Pernas, A.; Adam, W.
Espectrometria de Masas de g-Hidroperoxi Alcoholes y g-Dioles
Rev. Latinoam. Quim., 1976, 7, 106-111

1977

70
Adam, W.; Cueto, O.
A Convenient and Efficient Preparation of Aromatic a-Hydroperoxy Acids via Oxygenation of a-Lithio Enolates, Prepared by Direct a-Lithiation of Arylacetic Acids
J. Org. Chem., 1977, 42, 38-40

71
Adam, W.; Tsai,S.-C.
Electron Impact Behaviour of ß-Peroxylactones
J. Org. Chem., 1977, 42, 537-541

72
Adam, W.
The Chemistry of 1,2-Dioxetanes
Adv. Het. Chem., 1977, 21, 437-481

73
Adam, W.; Duran, N.
Prostanoid Endoperoxide Model Compounds: 1-Oxatrimethylene Diradicals in the Thermolysis and Photolysis of 1,2-Dioxolanes
J. Am. Chem. Soc., 1977, 99, 2729-2734

74
Adam, W.; Sanabia, J.
Prostanoid Endoperoxide Model Compounds: 1,6-Diradicals in the Thermolysis and Photolysis of 1,2-Dioxanes and Cyclic Peroxalates
J. Am. Chem. Soc., 1977, 99, 2735-2739

75
Adam, W.; Yany, F.
Determination of Polymer-Supported Carbodiimides
Anal. Chem., 1977, 49, 676

76
Adam, W.; Alzerreca, A.; Liu, J.-C.; Yany, F.
a-Peroxylactones via Dehydrative Cyclization of a-Hydroperoxy Acids
J. Am. Chem. Soc., 1977, 99, 5768-5773

77
Adam, W.; Cilento, G.; Rodriguez, L.O.; Rodriguez, O.; Sarma, A.S.; Zinner, K.
Acid-Dependent Fluorescence Quantum Yield and Tetramethyl-1,2-Dioxetane Chemi-Energized Flurescence of Ergostatetraenone
Photochem. Photobiol., 1977, 26, 299-303

78
Turro, N.J.; Ito, Y.; Chow, M.-F.; Adam, W.; Rodriguez, O.; Yany, F.
Synthesis of a-Peroxylactones by Direct Oxygenation of Ketenes. Evidence for an Intermediate
J. Am. Chem. Soc., 1977, 99, 5836-5838

79
Adam, W.; Eggelte, H.J.
2,3-Dioxabicyclo[2.2.2]octane by Selective Reduction of Double Bonds with Azodicarboxylate
Angew. Chem., 1977, 89, 726; Angew. Chem., Int. Ed. Engl., 1977, 16, 713-714

80
Adam, W.; Eggelte, H.J.
Prostanoid Endoperoxide Model Compounds: 2,3-Dioxabicyclo[2.2.1]heptane via Selective Diimide Reduction
J. Org. Chem., 1977, 42, 3987-3988

1978

81
Adam, W.; Fick, H.H.
Direct a-Lithiation of Phenoxyacetic Acid and Electrophilic Substitution
J. Org. Chem., 1978, 43, 772-773

82
Adam, W.; Cueto, O.; Yany, F.
On the Mechanism of the Rubrene-Enhanced Chemiluminescence of a-Peroxylactones
J. Am. Chem. Soc., 1978, 100, 2587-2589

83
Adam, W.; Birke, A.; Cadiz, C.; Diaz, S.; Rodriguez, A.
Prostanoid Endoperoxide Model Compounds: Preparation of 1,2-Dioxolanes from Cyclopropanes
J. Org. Chem., 1978, 43, 1154-1158

84
Adam, W.; del Fierro, J.
Synthesis of a-Hydroperoxy Esters by Singlet Oxygenation of Ketene Acetals
J. Org. Chem., 1978, 43, 1159-1161

85
Adam, W.; Cueto, O.; Guedes, L.N.; Rodriguez, L.O.
Solvent Effects and Secondary Isotope Effects for Probing Diradical Character in the Thermal Decarboxylation of ß-Peroxy Lactones
J. Org. Chem., 1978, 43, 1466-1467

86
Adam, W.; Bloodworth, A.J.; Eggelte, H.J.; Loveitt, M.E.
Regioselective Synthesis of Isomeric Bicyclic Peroxides
Angew. Chem., 1978, 90, 216; Angew. Chem., Int. Ed. Engl., 1978, 17, 209-210

87
Adam, W.; Erden, I.
Trapping of Unstable Fulvene/Singlet Oxygen Adducts by Reduction with Diazene
Angew. Chem., 1978, 90, 223; Angew. Chem., Int. Ed. Engl., 1978, 17, 210-211

88
Adam, W.; Erden, I.
Trapping of Unstable a-Pyrone/Singlet Oxygen Adducts by Reduction with Diazene
Angew. Chem., 1978, 90, 223; Angew. Chem., Int. Ed. Engl., 1978, 17, 211-212

89
Adam, W.; Cancio, E.M.; Rodriguez, O.
The Mechanism of the 9,10-Dibromoanthracene-Mediated Triplet-Singlet Energy Transfer in the Tetramethyl-1,2-dioxetane Energized Rubrene Luminescence
Photochem. Photobiol., 1978, 27, 617-624

90
Adam, W.; Sakanishi, K.
Mercuric Trifluoroacetate-Catalyzed Decomposition of an Allylic Hydroperoxide via a Mercury-Substituted 1,2-Dioxetane
J. Am. Chem. Soc., 1978, 100, 3935-3936

91
Campos, V.; Robeson, J.; Duran, N.; Adam, W.
New Peroxides and their Antimicrobial Acitivity
Rev. Brasil. Pesquisa Med. Bio., 1978, 11, 131-133

92
Adam, W.; Erden, I.
Synthesis and Characterization of 7-Spirocyclopropyl-2,3-dioxabicyclo(2.2.1)hept-2-ene
J. Org. Chem., 1978, 43, 2737-2738

93
Adam, W.; Ruchtäschel, R.
Photolysis and Thermolysis of Di-n-Butylmalonyl Peroxide. Evidence for a-Lactone Intermediates
J. Org. Chem., 1978, 43, 3886-3890

94
Adam, W.; Eggelte, H.J.
2,3-Dioxa-7-thiabicyclo[2.2.1]heptane: A New Heterocyclic System Possessing the Thiaozonide Structure
Angew. Chem., 1978, 90, 811; Angew. Chem., Int. Ed. Engl., 1978, 17, 765

95
Adam, W.; Rodriguez, O.; Zinner, K.
Triplet-Singlet Energy-Transfer Parameters from Tetramethyl-1,2-dioxetane Chemi-Energized 9,10-Dibromoanthracene Fluorescene in Polymer Matrices
J. Org. Chem., 1978, 43, 4495-4498

96
Adam, W.
Bioluminescence: Its Biology, Chemistry and Physics
Revista/Review Interamericana, 1978, 8, 85-98

97
Adam, W.; Fick, H.H.
Synthesis of Phenyl Enol Ethers via Decarboxylation of ß-Lactones Derived from the Lithium a-Phenoxy-a-lithioacetate Synthon
J. Org. Chem., 1978, 43, 4574-4577

98
Adam, W.; Arias Encarnacion, L.A.; Fick, H.H.
Generation of the Lithium a-Benzyloxy- and a,a-Diphenoxy-a-lithioacetate Synthons and Their Alkylation
Synthesis, 1978, 828-830

99
Adam, W.; Balci, M.
Norcaradiene and Cycloheptatriene Endoperoxides
Angew. Chem., 1978, 90, 1014-1015; Angew. Chem., Int. Ed. Engl., 1978, 17, 954-955

100
Adam, W.
Singlet Molecular Oxygen and its Role in Organic Peroxide Chemistry
W.M. Weigert, Ed., Hüthig Verlag: Heidelberg, 1978

101
Adam, W.; Bloodworth, A.J.
Organic Peroxides, Biological and Synthetic Aspects
Ann. Reports (B), 1978, 342-369

102
Srinivasan, R.; Brown, K. H.; Ors, J.A.; Adam, W.
Organic Photochemistry with 6.7 eV Photons: Ascaridole
In Proceedings of 7th IUPAC Symposium on Photochemistry; Catholic University, Louvain, Belgium 1978; pp 313-316

1979

103
Adam, W.; Fick, H.H.
Synthesis of Ketene Diphenyl Acetals via Decarboxylation of ß-Lactones Derived from the Lithium a,a-Diphenoxy-a-Lithioacetate Synthon
J. Org. Chem., 1979, 44, 356-359

104
Adam, W.; Cheng, C.-C.; Cueto, O.; Sakanishi, K.; Zinner, K.
Chemical Titration of Thermally Generated Triplets
J. Am. Chem. Soc., 1979, 101, 1324-1325

105
Adam, W.; Erden, I.; Cox, O.
Dienic Reactivity of 3,5-Cycloheptadien-1-one
J. Org. Chem., 1979, 44, 861-864

106
Adam, W.; Carballeira, N.; Cheng, C.-C.; Sakanishi, K.; Gleiter, R.
Differentiation in Singlet Oxygenation Rates of 2,3-Diaryl-2-butenes as a Function of cis-trans Isomerism
J. Org. Chem., 1979, 44, 851-853

107
Adam, W.; Balci, M.
endo- and exo-7-Cyanonorcaradiene Endoperoxides: Synthesis, Characterization, and Transformations
J. Org. Chem., 1979, 44, 1189-1190

108
Adam, W.; Zinner, K.
Excited States in Chemistry and Biochemistry
B. Pullman and N. Goldblum, Eds.; D. Reidel Publishers, 1977, Vol. 10, Photochem. Photobiol. (Book Review) 1979; 29, 857

109
Adam, W.; Erden, I.
Dienic Reactivity of 3,5-Cycloheptadienone: Reaction with Singlet Oxygen
Tetrahedron Lett., 1979, 1975-1978

110
Adam, W.; Takayama, K.
1,4-Dimethyl-2,3,7-trioxabicyclo(2.2.1)hept-5-ene
J. Org. Chem., 1979, 44, 1727-1728

111
Adam, W.; Eggelte, H.J.; Rodriguez, A.
A Convenient Method for the Preparation of Bicyclic Ozonides Possessing the 2,3,7-Trioxabicyclo(2.2.1)heptane Structure
Synthesis, 1979, 383-384

112
Adam, W.; Arias Encarnacion, L.A.
Benzyl Enol Ethers via Decarboxylation of a-Benzyloxy-ß-lactones Derived from the Lithium a-Benzyloxy-a-lithioacetate Synthon
Synthesis, 1979, 388-390

113
Adam, W.; Cheng, C.-C.; Cueto, O.; Erden, I.; Zinner, K.
A Stable Bisdioxetane
J. Am. Chem. Soc., 1979, 101, 4735-4736

114
Adam, W.; De Lucchi, O.; Erden, I.
Polycyclic Azoalkanes via Dipolar Cycloaddition of 4-Phenyl-1,2,4-triazoline-3,5-dione with Strained Bicyclic Olefins
Angew. Chem., 1979, 91, 512-515; Angew. Chem., Int. Ed. Engl., 1979, 18, 468-469

115
Adam, W.; Erden, I.
Singlet Oxygenation of Cycloocta-1,3,5-triene: Formation of (4.2.2)- and (2.2.2)-Cycloadducts
Tetrahedron Lett., 1979, 2781-2784

116
Adam, W.; Sakanishi, K.
Lack of Heavy Atom Effect on the Activation Parameters of Bromine Substituted 1,2-Dioxetanes
Photochem. Photobiol., 1979, 30, 45-48

117
Adam, W.; Cilento, G., Eds.
Chemi- and Bioenergized Processes
Photochem. Photobiol., 1979, 30, 1

118
Adam, W.; Erden, I.
a-Pyrone Endoperoxides. Synthesis, Thermal Decomposition, and Chemiluminescence
J. Am. Chem. Soc., 1979, 101, 5692-5696

119
Adam, W.; Balci, M.; Pietrzak, B.
Reaction of 7-Substituted Cycloheptatrienes with Singlet Oxygen and 4-Phenyl-1,2,4-triazoline-3,5-dione
J. Am. Chem. Soc., 1979, 101, 6285-6291

120
Adam, W.; Balci, M.; Cueto, O.; Pietrzak, B.
8,9-Dioxa-6-methylbicyclo[5.2.0]nona-2,4-diene: A 1,2-Dioxetane formed by [2+2]-Cycloaddition of Singlet Oxygen to 7-Methyl-1,3,5-Cycloheptatriene
Tetrahedron Lett., 1979, 4137-4140

121
Adam, W.; Cueto, O.
Fluorescencer-Enhanced Chemiluminescence of a-Peroxylactones via Electron Exchange
J. Am. Chem. Soc., 1979, 101, 6511-6515

122
Adam, W.; Bakker, B.H.
Singlet Oxygenation of cis,cis-1,5-Cyclooctadiene: A Convenient Synthetic Entry into 5,8-Difunctionalized Oxygen Derivatives of 1,3-Cyclooctadiene
Tetrahedron Lett., 1979, 4171-4174

123
Adam, W.; De Lucchi, O.
Cycloaddition of 4-Phenyl-1,2,4-triazoline-3,5-dione (PTAD) to Bicycloalkenes via Rearrangement of Zwitterionic Intermediates
Tetrahedron Lett., 1979, 4367-4370

124
Adam, W.; De Lucchi, O.; Quast, H.; Recktenwald, R.; Yany, F.
A 3-Imino-1,2-dioxetane via Singlet Oxygenation of a Ketenimine
Angew. Chem., 1979, 91, 855-856; Angew. Chem., Int. Ed. Engl., 1979, 18, 788-789

125
Adam, W.
Oxygen Diradicals Derived from Cyclic Peroxides
Acc. Chem. Res., 1979, 11, 390-396

126
Srinivasan, R.; Brown, K.H.; Ors, J.A.; White, L.S.; Adam, W.
Organic Photochemistry with 6.7 eV Photons: Ascaridole
J. Am. Chem. Soc., 1979, 101, 7424-7425

127
Adam, W.; Balci, M.
Photooxygenation of 1,3,5-Cycloheptatrine: Isolation and Characterization of Endoperoxides
J. Am. Chem. Soc., 1979, 101, 7537-7541

128
Adam, W.; Balci, M.
Photooxygenation of 1,3,5-Cycloheptatriene: Transformation of Endoperoxides
J. Am. Chem. Soc., 1979, 101, 7542-7547

129
Adam, W.; Balci, M.; Rivera, J.
A Convenient Synthesis of Homobenzoquinones
Synthesis, 1979, 807-808

130
Adam, W.; Rodriguez, A.
Bis(trimethylsilyl) Monoperoxysulfate: Convenient Baeyer-Villiger Oxidant
J. Org. Chem., 1979, 44, 4969-4970

1980

131
Adam, W.; Rodriguez, A.
Oxygen-Atom Transfer by Furan Endoperoxides
J. Am. Chem. Soc., 1980, 102, 404-406

132
Adam, W.; Takayama, K.
a-Lithio-3-indolyl Acetate Synthons: Generation and Synthetic Utilization
J. Org. Chem., 1980, 45, 447-452

133
Adam, W.; Balci, M.
Stereoselective Synthesis of Cycloheptatriene Trioxides
Angew. Chem., 1980, 92, 54-55; Angew. Chem., Int. Ed. Engl., 1980, 19, 48-49

134
Adam, W.; Balci, M.
The Stereoselective Synthesis of the Three Trioxides of 1,3,5-Cycloheptatriene via the Endoperoxide-Diepoxide Rearrangement
J. Am. Chem. Soc., 1980, 102, 1961-1966

135
Adam, W.; Cueto, O.; Guedes, L.N.
On the Mechanism of ß-Peroxylactone Decarboxylation
J. Am. Chem. Soc., 1980, 102, 2106-2107

136
Adam, W.; Carballeira, N.; De Lucchi, O.
2,3-Benzobicyclo-[2.2.2]oct-2-ene-5,7-diyl Diradical as a Common Intermediate in the Di-p-methane Rearrangement of 6,7-Benzobicyclo[3.2.1]octa-2,6-diene and the Denitrogenation of the Corresponding Tricycloazoalkane
J. Am. Chem. Soc., 1980, 102, 2107-2109

137
Adam, W.; De Lucchi, O.
Unusual Thermal and Photochemical Transformations of the Azoalkane 2,3-Diaza-7,8-benzotricyclo[4.3.0.04,9]nona-2,7-diene
J. Am. Chem. Soc., 1980, 102, 2109-2110

138
Adam, W.; Del Fierro, J.; Quiroz, F.; Yany, F.
Singlet Oxygenation of Ketene Acetals: Formation of 1,2-Dioxetanes and Their Thermal Rearrangmeent to a-Peroxy Esters
J. Am. Chem. Soc., 1980, 102, 2127-2128

139
Adam, W.; Yany, F.
Thermal Generation of Electronically Excited States by a-Peroxylactones: Activation Parameters and Excitation Yields as a Function of a-Deuteration
Photochem. Photobiol., 1980, 31, 267-272

140
Adam, W.
Thermische Erzeugung elektronisch angeregter Moleküle
Chemie in unserer Zeit, 1980, 14, 44-55

141
Adam, W.; Balci, M.
Cyclic Polyepoxides: Synthetic, Structural and Biological Aspects
Tetrahedron, 1980, 36, 833-858

142
Gleiter, R.; Schang, P.; Adam, W.; Eggelte, H.J.; Erden, I.; Bloodworth, A.J.
Photoelectron Spectra of Bicyclic Peroxides
J. Electron. Spec. Rel. Phenom., 1980, 19, 223-230

143
Adam, W.; Cadilla, C.; Cueto, O.; Rodriguez, L.O.
Fluorescer-Enhanced Chemiluminescence of a Cyclic Peroxalate via Electron Exchange
J. Am. Chem. Soc., 1980, 102, 4802-4805

144
Adam, W.; De Lucchi, O.; Erden, I.
Bicyclic Azoalkanes via Urazoles Derived from Cycloaddition of N-Phenyl-1,2,4-triazoline-3,5-dione with Strained Bicycloalkanes
J. Am. Chem. Soc., 1980, 102, 4806-4809

145
Adam, W.; Cilento, G.; Zinner, K.
External Heavy Atom Effect in the Energy Transfer from Chemi-Excited Triplet Acetone to Anthracene
Photochem. Photobiol., 1980, 32, 87-90

146
Adam, W.; De Lucchi, O.
The Synthesis of Unusual Organic Molecules from Azoalkanes
Angew. Chem., 1980, 92, 815-832; Angew. Chem., Int. Ed. Engl., 1980, 19, 762-779

147
Adam, W.; De Lucchi, O.
Thermal Rearrangement of 5,6-Benzotricyclo[3.2.0.02,7]hept-5-ene into 2-Vinylidene via an Intramolecular Retro-Diels-Alder Reaction
J. Org. Chem., 1980, 45, 4167-4168

148
Adam, W.; Balci, M.; Pietrzak, B.; Rebollo, H.
Oxygen Functionalization of Cycloheptatriene via Sensitized Photooxygenation
Synthesis, 1980, 10, 820-823

149
Adam, W.; Mazenod, F.
Facile Liquid-Phase Denitrogenation of Reluctant Azoalkanes on Photolysis with 185-nm Radiation
J. Am. Chem. Soc., 1980, 102, 7131-7132

150
Adam, W.
Thermal Generation of Electronic Excitation with Hyperenergetic Molecules
Pure & Appl. Chem., 1980, 52, 2591-2608

151
Adam, W.; Cueto, O.; De Lucchi, O.
Oxygen Functionalization in Cyclooctatetraene via Singlet Oxygenation: Synthesis and Transformation of anti-7,8-Dioxytricyclo[4.2.2.02,5]deca-3,9-diene, the Endoperoxide of the Bicyclic Valence Tautomer of Cyclooctatetraene
J. Org. Chem., 1980, 45, 5220-5221

1981

152
Adam, W.; De Lucchi, O.
[2+2]-Cycloaddition of Triazolinediones to Strained Bicycloalkenes
Tetrahedron Lett., 1981, 22, 929-932

153
Adam, W.; Cadiz, C.; Mazenod, F.P.
Vacuum Flash Pyrolysis (VFP) of Malonyl Peroxides: Decarboxylation versus Decarbonylation of the Intermediary a-Lactones
Tetrahedron Lett., 1981, 22, 1203-1206

154
Adam, W.; Fuß, A.; Mazenod, F.P.; Quast, H.
Reluctant Azoalkanes: The Short Wavelength (185 nm) Liquid Phase Photolysis and High Temperature (400-1000 oC) Gas-Phase Pyrolysis of 3,3,5,5-Tetramethylpyrazolin-4-one
J. Am. Chem. Soc., 1981, 103, 998-1000

155
Adam, W.; Curci, R.
Hyperenergetic Molecules: Dioxiranes and 1,2-Dioxetanes
Chimia e Industria, 1981, 63, 20-28

156
Adam, W.; De Lucchi, O.
Thermal and Photochemical Denitrogenation of a Polycylic Azoalkane as Mechanistic Probe for the Di-p-Methane Rearrangement of 7,7-Dimethylenebenzonorbornadiene
Angew. Chem., 1981, 93, 408-409; Angew. Chem., Int. Ed. Engl., 1981, 20, 400-401

157
Adam, W.; Yany, F.
Direct Photochemical cis-trans Isomerization with 185-nm Radiation: A Facile Preparation of cis-Di-tert-Butylethylene
Z. Naturforsch., 1981, 36b, 658

158
Adam, W.; Cueto, O.; De Lucchi, O.; Peters, K.; Peters, E.-M.; von Schnering, H.G.
Triepoxides of Bicyclo[4.2.0]octa-2,4,7-triene
Angew. Chem., 1981, 93, 618-619; Angew. Chem., Int. Ed. Engl., 1981, 20, 580-581

159
Adam, W.; Arias, L.A.; De Lucchi, O.
Hydrazinolysis of Urazoles: A Convenient and Mild Method for the Preparation of Azoalkanes
Synthesis, 1981, 543-545

160
Adam, W.; Rebollo, H.
Singlet Oxygenation of Cycloheptatriene: Isolation and Characterization of 1,2-Dioxetane
Tetrahedron Lett., 1981, 3049-3052

161
Adam, W.; Martinez, G.; Thompson, J.; Yany, F.
ß-Lactones as Convenient Precursors to Sterically Congested Olefins
J. Org. Chem., 1981, 46, 3359-3361

162
Adam, W.; Bloodworth, A.J.
Chemistry of Saturated Bicyclic Peroxides (The Prostaglandin Connection)
Top. Curr. Chem., 1981, 97, 121-158

163
Adam, W.; De Lucchi, O.
Reaction of Bicyclo[3.2.1]octadiene with 4-Methyl-1,2,4-triazoline-3,5-dione: Competitive Dipolar and Homo Cycloaddition
Tetrahedron Lett., 1981, 22, 3501-3504

164
Adam, W.; Rodriguez, A.
Intramolecular Silyl Migration in the Singlet Oxygenation of 2-Methyl-5-trimethylsilylfuran
Tetrahedron Lett., 1981, 22, 3505-3508

165
Adam, W.; Rodriguez, A.
On the Question of Carbonyl Oxide Intermediates in the Oxygen Transfer by Furan Endoperoxides and Bicyclic Ozonides: Intramolecular Trapping Experiments
Tetrahedron Lett., 1981, 22, 3509-3512

166
Adam, W.; Cueto, O.; De Lucchi, O.; Peters, K.; Peters, E.-M.; von Schnering, H.G.
Synthesis of the Endoperoxide anti-7,8-Dioxatricyclo[4.2.2.02,5]deca-3,9-diene via Singlet Oxygenation of the Bicyclic Valence Tautomer of Cyclooctatetraene and its Transformations
J. Am. Chem. Soc., 1981, 103, 5822-5828

167
Adam, W.; Zinner, K.; Krebs, A.; Schmalstieg, H.
Electron-Exchange Chemiluminescence from a Sterically Stabilized Cyclobutadiene-1,2-dioxetane
Tetrahedron Lett., 1981, 22, 4567-4570

168
Adam, W.; De Lucchi, O.
Generation of 2,3-Benzobicyclo[2.2.1]hept-2-ene-5,7-diyl Diradicals via Denitrogenation of Appropriate Azoalkanes and their Mechanistic Implications in the Di-p-methane Rearrangement of Benzonorbornadienes
J. Org. Chem., 1981, 46, 4133-4238

169
Adam, W.; Carballeira, N.; De Lucchi, O.
Thermolysis and Photolysis of the Azoalkane 2,3-Diazatricyclo[4.3.0.04,9]non-2-ene: Generation and Transformation of the Bicyclo[2.2.1]heptane-2,7-diyl Diradical
J. Am. Chem. Soc., 1981, 103, 6406-6409

170
Adam, W.; De Lucchi, O.; Scheutzow, D.
Cycloaddition of Substituted Bicyclo(3.2.1)octa-2,6-diene with 4-Phenyl-1,2,4-triazoline-3,5-dione
J. Org. Chem., 1981, 46, 4130-4132

171
Adam, W.
Die Singulettsauerstoff-Story
Chemie in unserer Zeit, 1981, 15, 190-196

172
Adam, W.; Cueto, O.; Schmidt, E.; Takayama, K.
Dihydrodioxetobenzodioxins: Synthesis and Chemiluminescence
Angew. Chem., 1981, 93, 1100-1103; Angew. Chem., Int. Ed. Engl., 1981, 20, 1031-1032

173
Adam, W.; Cueto, O.
3,3-Dimethyl-4(2-methyl-1-propenyl)-1,2-Dioxetane: Its Thermal Stability and Chemiluminescent Properties
Z. Naturforsch., 1981, 36b, 1653-1654

1982

174
Adam, W.; Cueto, O.; Rebollo, H.
Formation of Singlet Oxygen in the Reversible Autoxidation of Enolates Derived from Carboxylic Acids
Angew. Chem., 1982, 94, 82-83; Angew. Chem., Int. Ed. Engl., 1982, 21, 75

175
Adam, W.; Arias, L.A.; De Lucchi, O.
Unusual Cycloaddition Behavior of 2-Substituted Norbornadienes with Triazolinediones
Tetrahedron Lett., 1982, 23, 399-402

176
Adam, W.; De Lucchi, O.; Peters, K.; Peters, E.-M.; von Schnering, H.G.
Reaction of Bicyclo(3.2.1)octa-2,6-diene with 1,2,4-Triazoline-3,5-diones: Competitive Dipolar and Homocycloaddition
J. Am. Chem. Soc., 1982, 104, 161-166

177
Adam, W.; Rebollo, H.; Dürr, H.; Pauly, K.-H.; Peters, K.; Peters, E.-M.; von Schnering, H.G.
Cycloaddition of Singlet Oxygen and Triazolinedione (TAD) with Spirocyclopentadienyl-1,3,5-Cycloheptatrienes: Tropilidene versus Norcaradiene Reactivity
Tetrahedron Lett., 1982, 23, 923-926

178
Adam, W.; Cueto, O.; De Lucchi, O.
[4+2]-Cycloaddition of Singlet Oxygen and Phenyltriazolinedione with Bicyclo[6.1.0]nona-2,4,6-triene and Derivatives
Chem. Ber., 1982, 115, 1170-1177

179
Adam, W.; De Lucchi, O.; Hill, K.
Reaction of 4-Phenyl-1,2,4-triazoline-3,5-dione (PTAD) with Bicyclic Monoterpenes
Chem. Ber., 1982, 115, 1982-1989

180
Adam, W.; Schmidt, E.; Takayama, K.
A Convenient Synthesis of 2,3-Disubstituted 1,4-Benzodioxins via Lithiation and Alkylation
Synthesis, 1982, 322-324

181
Adam, W.; Fritz, G.
The Discovery of Singlet Oxygen: Hans Kautsky, 1891-1966
EPA Newsletter, 1982, 8-24

182
Adam, W.; De Lucchi, O.; Hill, K.
Generation and Rearrangement of the 2-Oxabicyclo[2.2.1]heptane-6,7-diyl Diradical via Nitrogen Extrusion from the Azoalkane 2,3-Diazatricyclo[4.3.0.04,9]non-2-en-8-one
J. Am. Chem. Soc., 1982, 104, 2934-2936

183
Adam, W.; Arias, L.A.; Scheutzow, D.
Spiroadamantyl Stabilization of Sulfur-Substituted 1,2-Dioxetanes
Tetrahedron Lett., 1982, 23, 2835-2836

184
Adam, W.; Klug, G.; Scheutzow, D.; Peters, K.; Peters, E.-M.; von Schnering, H.G.
Cycloaddition of Singlet Oxygen and 4-Methyl-1,2,4-triazoline-3,5-dione (MTAD) to Methoxycyclooctatetraene (MCOT)
Tetrahedron Lett., 1982, 23, 2837-2840

185
Adam, W., Arias, L.A.; Zahn, A.; Zinner, K.; Peters, K.; Peters, E.-M.; von Schnering, H.G.
X-Ray Structural Parameters and the Thermal Stability of 1,2-Dioxetanes
Tetrahedron Lett., 1982, 23, 3251-3254

186
Adam, W.; Arias Encarnacion, L.A.
The Synthesis of Spiro(adamanantane-1,2-dioxetanes)
Chem. Ber., 1982, 115, 2592-2605

187
Adam, W.; Klug, G.
The Synthesis of the Endoperoxide of Cyclooctatetraene via Photosensitized Singlet Oxygenation
Tetrahedron Lett., 1982, 23, 3155-3158

188
Adam, W.; Cilento, G.
Chemical and Biological Generation of Excited States
Adam, W.; Cilento, G., Eds.; Academic Press: New York 1982

189
Adam, W.
Determination of Chemiexcitation Yields in the Thermal Generation of Electronic Excitation from 1,2-Dioxetanes
In Chemical and Biological Generation of Excited States, Adam, W.; Cilento, G., Eds.; Academic Press: New York 1982; Chap. 4, pp 115-152

190
Adam, W.; Zinner, K.
Determination of Activation Parameters and the Thermal Stability of 1,2-Dioxetanes
In Chemical and Biological Generation of Electronic Excited States, Adam, W. and Cilento, G. Eds.; Academic Press: New York 1982; Chap. 5, pp 153-189

191
Adam, W.; Baader, W.J.
Das Experiment : Singulettsauerstoff - Chemische Erzeugung und Chemilumineszenz
Chemie in unserer Zeit, 1982, 16, 169-171

192
Adam, W.; Rebollo, H.
Singlet Oxygenation of 7-Aryl- and 7-Alkyl-1,3,5-cycloheptatrienes: Substituent Effects on the Product Distribution of Tropilidene- and Norcaradiene-Derived Endoperoxides
Tetrahedron Lett., 1982, 23, 4907-4910

193
Adam, W.; De Lucchi, O.; Peters, K.; Peters, E.-M.; von Schnering, H.G.
Photochemical and Thermal Denitrogenation of Azoalkanes as Mechanistic Probes for the Diradical Intermediates Involved in the Di-p-methane Rearrangement of Dibenzobarrelene
J. Am. Chem. Soc., 1982, 104, 5747-5753

194
Peters, K.; Peters, E.-M.; von Schnering, H.G.; Adam, W.; Rebollo, H.
Crystal Structure of 4-Phenyl-2,4,6-triazatetracyclo(5.3.2.02,6.08,10)dodec-11-ene-3,5-dione
Z. Kristallogr., 1982, 160, 145-148

195
Peters, K.; Peters, E.-M.; von Schnering, H.G.; Adam, W.; Rebollo, H.
Crystal Structure of 4-Phenyl-2,4,6-triazatricyclo[5.3.2.02,6]dodeca-9,11-dien-3,5,8-trione
Z. Kristallogr., 1982, 160, 149-152

196
Adam, W.; Oppenländer, T.
The 185-nm Photochemistry of 2,3-Diazabicyclo[2.2.1]heptene and of its Denitrogenation Products Bicyclo[2.1.0]pentane and Cyclopentene
Tetrahedron Lett., 1982, 23, 5391-5394

197
Schmidt, R.; Brauer, H.-D.; Adam, W.; Zinner, K.
Mediumabhängige Energiewanderung bei der Energietransfer-Chemilumineszenz des Systems Tetramethyl-1,2-dioxetan-9,10-Dibromanthracen in polymeren Matrizen
Z. Physik. Chem., 1982, 131, 129-138

1983

198
Adam, W.; Hannemann, K.
The Azoalkane 7,8-Benzo-2,3-diazatricyclo[4.3.0.04,9]nona-2,7-diene as Spin-State-Specific Titrant of Singlet and Triplet Excitation Generated in the Thermolysis of Dioxetanes
J. Am. Chem. Soc., 1983, 105, 714-719

199
Adam, W.; Arias Encarnacion, L.A.; Zinner, K.
Thermal Stability of Spiro(adamantane-1,2-dioxetanes)
Chem. Ber., 1983, 116, 839-846

200
Adam, W.; Gillaspey, W.D.
Competitive Diradical and Diazoalkane Formation in the Thermolysis and Photolysis of the Azoalkane 7,7,8-Trimethyl-2,3-diazatricyclo[4.2.1.04,8]non-2-ene
Tetrahedron Lett., 1983, 24, 1699-1702

201
Adam, W.; Peters, E.-M.; Peters, K.; Schmidt, E.; von Schnering, H.G.
Bis(3-phenyl-1,4-benzodioxin-2-yl) Sulfide: Formation and Structure Elucidation
Chem. Ber., 1983, 116, 1686-1689

202
Adam, W.; Adamsky, F.; Klärner, F.-G.; Peters, E.-M.; Peters, K.; Rebollo, H.; Rüngeler, W.; von Schnering, H.G.
Stereochemistry and Product Distribution in the Singlet Oxygen Cycloaddition with 7,7-Disubstituted 1,3,5-Cycloheptatrienes
Chem. Ber., 1983, 116, 1848-1859

203
Böhm, M.C.; Gleiter, R.; Adam, W.; Narita, N.
The Photoelectron Spectra of Cyclic Peroxylactones
Z. Naturforsch., 1983, 38b, 501-503

204
Adam, W.; Cilento, G.
Four-Membered-Ring Peroxides as Excited State Equivalents: A New Dimension in Bioorganic Chemistry
Angew. Chem., 1983, 95, 525-538; Angew. Chem., Int. Ed. Engl., 1983, 22, 529-542

205
Adam, W.; Schmidt, E.; Peters, E.-M.; Peters, K.; von Schnering, H.G.
Crystal Structure of 2,4,5,7,9,10-Hexaoxa-1,3,6,8-tetraphenyltricyclo(6.2.0.0.03,6)decane: An Authentic Bisdioxetane
Angew. Chem., 1983, 95, 566-567; Angew. Chem., Int. Ed. Engl., 1983, 22, 546-547

206
Adam, W.; Carballeira, N.; Peters, E.-M.; Peters, K.; von Schnering, H.G.
Facile Synthesis of Substituted Brendanes via Spirocyclopropane Participation
J. Am. Chem. Soc., 1983, 105, 5132

207
Adam, W.; Mazenod, F.; Nishizawa, Y.; Engel, P.S.; Baughman, S.A.; Chae, W.-K.; Horsey, D.W.; Quast, H.; Seiferling, B.
Reluctant Azoalkanes: The Photochemical Behavior of Acyclic, Bridgehead-Centered Azoalkanes at 185-nm and 350-nm Irradiation
J. Am. Chem. Soc., 1983, 105, 6141-6145

208
Adam, W.; Carballeira, N.; Gillaspey, W.D.
Photolysis of the Azoalkane 2,3-Diazatricyclo(4.2.0.04,9)non-2-ene: Direct Observation of 4-Cyclohexenyldiazomethane
Tetrahedron Lett., 1983, 24, 5473-5476

209
Adam, W.; Beinhauer, A.; De Lucchi, O.; Rosenthal, R.J.
Dienophilic and Dipolar Additions to Bicyclo(2.1.0)pent-2-ene
Tetrahedron Lett., 1983, 24, 5727-5730

210
Adam, W.; Carballeira, N.; De Lucchi, O.; Hill, K.
The Di-p-methane Rearrangement Revisited
In Stereochemistry and Reactivity of Systems Containing p-Electrons (Vol. 3) by W.H. Watson, Ed.; Verlag Chemie Int.: Deer 1983; Chap. 7, pp 241-278

211
Adam, W.
Four-Membered Ring Peroxides: 1,2-Dioxetanes and a-Peroxylactones
In The Chemistry of Functional Groups, Peroxides, by S. Patai, Ed.; John Wiley & Sons: New York, 1983; Chap. 24, pp 830-920

212
Berkessel, A.; Adam, W.
Photolysis of the Divinyl Ethers of 1,1'-Oxydiphenylethene and 1,1'-Oxydi-2-methyl-1-propene in Solution
In Book of Abstracts, 8th Meeting of GDCh Fachgruppe Photochemie in Tuebingen, Germany; Gesellschaft Deutscher Chemiker, Fra 1983; pp 53-57

1984

213
Adam, W.; Hannemann, K.; Hössel, P.
Preparative UV-Laser Photochemistry of the Azoalkane Spiro-2,3-diazabicyclo(2.2.1)hept-2-ene-7',1-cyclopropane: Trapping of the 1,4-Diradical-2-(3-cyclopentenyl)ethyl by Molecular Oxygen
Tetrahedron Lett., 1984, 25, 181-184

214
Adam, W.; Carballeira, N.; Scheutzow, D.; Peters, K., Peters, E.-M.; von Schnering, H.G.
On the Mechanism of the Formation of Rearrangement Products in the Addition of Arenesulfenyl Chloride and 4-Phenyl-4H-1,2,4-triazole-3,5-dione to Benzonorbornadienes
Chem. Ber., 1984, 117, 1139-1152

215
Adam, W.; Baader, W.J.
1,2-Dioxetane: Synthesis, Characterization, Stability and Chemiluminescence
Angew. Chem., 1984, 96, 156; Angew. Chem., Int. Ed. Engl., 1984, 23, 166-167

216
Adam, W.; Narita, N.; Nishizawa, Y.
On the Mechanism of the Triphenylphosphine-Azodicarboxylate (Mitsunobu Reaction) Esterification
J. Am. Chem. Soc., 1984, 106, 1843-1845

217
Adam, W.; De Lucchi, O.; Gillaspey, W.D.; Rosenthal, R.J.
Acid-Catalyzed Cyclization of the Ene Product Derived from a-Pinene and PTAD
Chem. Ber., 1984, 117, 1977-1979

218
Adam, W.; Rebollo, H.
Substituent, Temperature and Solvent Effects in the Singlet Oxygenation of 7-Alkyl- and 7-Aryl-substituted 1,3,5-Cycloheptatrienes
Israel. J. Chem., 1984, 23, 399-404

219
Adam, W.; Babatsikos, C.; Cilento, G.
Functionalized 1,2-Dioxetanes as Potentially Useful Biological and Chemotherapeutic Agents
Z. Naturforsch., 1984, 39b, 679-682

220
Adam, W.; Dürr, H.; Pauly, K.-H.; Peters, E.-M.; Peters, K.; Rebollo, H.; von Schnering, H.G.
Singlet Oxygenation and Triazolinedione Addition to Spirofluorene-1,3,5-cycloheptatriene
J. Org. Chem., 1984, 49, 1333-1338

221
Adam, W.; Oppenländer, T.
Absolute Intensity Method for the Determination of Quantum Yields in 185-nm Photochemistry: Application to the Azoalkane 2,3-Diazabicyclo(2.2.1)hept-2-ene
Photochem. Photobiol., 1984, 39, 719-723

222
Adam, W.; Carballeira, N.
On the Mechanism of the Cycloaddition of 1,2,4-Triazoline-3,5-diones with Bicycloalkenes Leading to Rearranged Urazoles
J. Am. Chem. Soc., 1984, 106, 2874-2882

223
Adam, W.; Peters, E.-M.; Peters, K.; Rebollo, H.; Rosenthal, R.J.; von Schnering, H.G.
Cycloaddition of Singlet Oxygen and 4-Methyl-4H-1,2,4-triazole-3,5-dione to 7-Adamantylidene-1,3,5-cycloheptatriene and Derivatives
Chem. Ber., 1984, 117, 2393-2408

224
Adam, W.; Arias Encarnacion, L.A.; Cilento, G.; Haun, M.; Nassi, L.
Excitation of Chlorophyll during the Peroxidase-Catalyzed Oxidation of Ethyl a-Formylphenylacetate
Photochem. Photobiol., 1984, 40, 189-192

225
Adam, W.; Gretzke, N.; Klug, G.
Thermolysis of 7,8-Dioxabicyclo[4.2.2]deca-2,4,9-trienes. An Unusual Decomposition Mode of Endoperoxides
J. Am. Chem. Soc., 1984, 106, 4300-4301

226
Adam, W.; Oppenländer, T.
Direct Photochemical Cleavage of the Cyclobutane Ring in Bicyclo[4.2.0]octane on 185-nm Irradiation in Solution
Angew. Chem., 1984, 94, 599; Angew. Chem., Int. Ed. Engl., 1984, 23, 641-642

227
Adam, W.; Haas, W.; Sieker, G.
Thianthrene-5-Oxide as Mechanistic Probe in Oxygen-Transfer Reactions: The Case of Carbonyl Oxides versus Dioxiranes
J. Am. Chem. Soc., 1984, 106, 5020-5022

228
Adam, W.; Baader, W.J.; Babatsikos, C.; Schmidt, E.
Four-Membered-Ring Peroxide Heterocycles: Photochemistry through the Backdoor
Bull. Soc. Chim. Belg., 1984, 93, 605-617

229
Adam, W.; Peters, E.-M.; Peters, K.; Platsch, H.; Schmidt, E.; von Schnering, H.G.; Takayama, K.
Synthesis, Thermal Stability, and Chemiluminescence Properties of the Dioxetanes Derived from 1,4-Dioxins
J. Org. Chem., 1984, 49, 3920-3928

230
Adam, W.; Hannemann, K.; Wilson, R.M.
UV-Laser Photochemistry of the Azoalkane 2,3-Diazabicyclo[2.2.2]oct-3-ene: Trapping of the Short-Lived Triplet Biradical 1,4-Cyclohexadiyl by Molecular Oxygen
J. Am. Chem. Soc., 1984, 106, 7646-7647

231
Peters, K.; Peters, E.-M.; von Schnering, H.G.; Adam, W.; De Lucchi, O.
Crystal Structure of 8-Chloro-2,4,6-triazatricyclo[7.2.1.02,6]dodeca-7,10-diene-3,5-dione
Z. Kristallogr., 1984, 168, 145-148

1985

232
Adam, W.; Baader, W.J.
Effects of Methylation on the Thermal Stability and Chemiluminescence Properties of 1,2-Dioxetanes
J. Am. Chem. Soc., 1985, 107, 410-416

233
Adam, W.; Berkessel, A.; Krimm, S.
Photochemistry of Bis(2-methyl-1-propenyl) Ether and 2,2,4,4-Tetramethyl-6-oxabicyclo[3.1.0]hexan-3-one: On the Search for the Oxydi-p-methane Rearrangement
Tetrahedron Lett., 1985, 26, 619-622

234
Adam, W.; Yany, F.
1,2-Dioxetanes and a-Peroxylactones
In Small Ring Heterocycles, Hassner, A. Ed.; John Wiley and Sons: New York, 1985; Vol. 42, Part 3, Chap 4, pp 351-429

235
Adam, W.; Gillaspey, W.D.; Peters, E.-M.; Peters, K.; Rosenthal, R.J.; von Schnering, H.G.
Thermolysis and Photolysis of the Azoalkane 4,5-Diaza-7,8,8-trimethyltricyclo-[4.2.1.03,7]non-4-ene: 1,3-Diradical and Diazoalkane Formation
J. Org. Chem., 1985, 50, 580-586

236
Adam, W.; Dörr, M.; Hill, K.; Peters, E.-M.; Peters, K.; von Schnering, H.G.
Synthesis, Photolysis and Thermolysis of Azoalkanes Derived from Spirocyclopropane-Substituted Norbornenes: Competitive Nitrogen Loss and Diazoalkane Formation
J. Org. Chem., 1985, 50, 587-595

237
Adam, W.; Hannemann, K.; Peters, E.-M.; Peters, K.; von Schnering, H.G.; Wilson, R.M.
Laser Photolysis of the Bisazoalkane 7-syn, 7'-anti-Bis-2,3-diazabicyclo[2.2.1]hept-2-ene
Angew. Chem., 1985, 97, 417-418; Angew. Chem., Int. Ed. Engl., 1985, 24, 421-422

238
Adam, W.; Klug, G.; Peters, E.-M.; Peters, K.; von Schnering, H.G.
Synthesis of Endoperoxides Derived from Cyclooctatetraenes via Singlet Oxygenation
Tetrahedron, 1985, 41, 2045-2056

239
Adam, W.; Hill, K.
Synthesis, Thermolysis and Photolysis of the Azoalkane 4,5-Diazatricyclo[4.3.0.03,7]nona-4,8-diene: Denitrogenation versus Azirane Formation
J. Am. Chem. Soc., 1985, 107, 3686-3689

240
Adam, W.; Oppenländer, T.; Zang, G.
185-nm Photochemistry of Cyclobutane and Bicyclo[1.1.0]butane
J. Am. Chem. Soc., 1985, 107, 3921-3924

241
Adam, W.; Oppenländer, T.
185-nm Photochemistry of Bicyclo[2.1.0]pentane and Cyclopentene
J. Am. Chem. Soc., 1985, 107, 3924-3928

242
Adam, W.; Berkessel, A.; Peters, E.-M.; Peters, K.; von Schnering, H.G.
Photolysis of 1,1,4,4-Tetraphenyl-3-buten-2-one: Ketene Formation from an Acyclic a,ß-Unsaturated Ketone
J. Org. Chem., 1985, 50, 2811-2814

243
Adam, W.; Oppenländer, T.; Zang, G.
185-nm Photochemistry of the Azoalkane 2,3-Diazabicyclo[2.2.1]hept-2-ene: On the Questions of One-Bond vs Two-Bond Cleavage During the Denitrogenation, Cyclization versus Rearrangement of the 1,3-Diradicals and Double Inversion
J. Org. Chem., 1985, 50, 3303-3312

244
Adam, W.; De Lucchi, O.; Hill, K.; Peters, E.-M.; Peters, K.; von Schnering, H.G.
Synthesis, Thermolysis, and Photolysis of the Azoalkanes Spiro-4,5-diazatricyclo-[4.3.0.03,7]non-4-ene and 4,5-Diazatricyclo[4.3.0.03,7]non-4-en-8-one: On the Mechanism of the Oxadi-p-methane Rearrangement of 5-Norbornen-2-one
Chem. Ber., 1985, 118, 3070-3088

245
Adam, W.; Gretzke, N.; Hasemann, L.; Klug, G.; Peters, E.-M.; Peters, K.; von Schnering, H.G.; Will, B.
Cycloaddition of Singlet Oxygen and 4-Phenyl-4H-1,2,4-triazole-3,5-dione to 7-Substituted 1,3,5-Cyclooctatrienes
Chem. Ber., 1985, 118, 3357-3379

246
Adam, W.; Platsch, H.; Schmidt, E.
Synthesis, Thermal Stability, and Chemiluminescence Properties of Bisdioxetanes Derived from p-Dioxins
Chem. Ber., 1985, 118, 4385-4403

247
Adam, W.; Oppenländer, T.
Photoreluctant Azoalkanes: 185-nm Photolysis of E- and Z-Diazacyclooct-1-ene
Can. J. Chem., 1985, 63, 1829-1832

248
Adam, W.; Baader, W.J.; Catalani, L.H.; Cilento, G.; Rychla, L.
Energy Transfer from Chemiexcited Acetone to Substances that Display Anomalous Fluorescence
Photochem. Photobiol., 1985, 42, 587-589

249
Adam, W.; Berkessel, A.; Krimm, S.
Synthesis and Homo-Diels-Alder Cleavage of the Epoxyazoalkane exo-3-Oxa-6,7-diazatricyclo[3.2.1.02,4]oct-6-ene
Chem. Ber., 1985, 118, 5018-5023

250
Adam, W.; Berkessel, A.; Hildenbrand, K.; Peters, E.-M.; Peters, K.; von Schnering, H.G.
The Photochemistry of Bis(2,2-diphenylvinyl) Ether: A Search for the 3-Oxadi-p-methane Rearrangement
J. Org. Chem., 1985, 50, 4899-4909

251
Adam, W.; Griesbeck, A.G.
Synthesis of the First a-Methylene-ß-peroxylactone: Regioselective Ene Reaction of Singlet Oxygen with a,ß-Unsaturated Carboxylic Acids
Angew. Chem., 1985, 97, 1071-1072; Angew. Chem., Int. Ed. Engl., 1985, 24, 1070-1071

252
Adam, W.; Hannemann, K.; Wilson, R.M.
Sensitized UV-Laser Photolysis of Azoalkanes: Conformational Influences on Intersystem-Crossing and Lifetimes of Triplet Diradicals
Angew. Chem., 1985, 97, 1072-1073; Angew. Chem., Int. Ed. Engl., 1985, 24, 1071-1072

1986

253
Adam, W.; Dürr, H.; Haas, W.; Lohray, B.B.
Thianthrene 5-Oxide as Mechanistic Probe in Oxygen Transfer Reactions: The Nucleophilic Character of Carbonyl Oxides
Angew. Chem., 1986, 98, 41-43; Angew. Chem., Int. Ed. Engl., 1986, 25, 101-103

254
Adam, W.; Lohray, B.B.
Thianthrene 5-Oxide as Mechanistic Probe in Oxygen Transfer Reactions: Substrate Complexation in Oxidations with Transition-Metal Peroxides
Angew. Chem., 1986, 98, 185-186; Angew. Chem., Int. Ed. Engl., 1986, 25, 188-189

255
Adam, W.; Hannemann, K.; Wilson, R.M.
UV Laser Photochemistry: Triplet Biradical Trapping Efficiencies and Lifetimes
J. Am. Chem. Soc., 1986, 108, 929-935

256
Adam, W.; Griesbeck, A.G.; Staab, E.
A Simple Access to 2-Epoxy Alcohols: Titanium(IV)-Catalyzed Oxygen Transfer from Allylic Hydroperoxides
Angew. Chem., 1986, 98, 279-280; Angew. Chem., Int. Ed. Engl., 1986, 25, 269-270

257
Adam, W.; Bhushan, V.; Dirnberger, T.; Fuchs, R.
Functionalized 1,2-Dioxetanes as Potential Chemotherpeutic Agents: The Synthesis of Dioxetane-Substituted Carbamates
Synthesis, 1986, 330-332

258
Adam, W.; Griesbeck, A.G.; Staab, E.
A Convenient One-Pot Synthesis of Epoxy Alcohols via Photooxygenation of Olefins in the Presence of Titanium(IV) Catalyst
Tetrahedron Lett., 1986, 27, 2839-2842

259
Adam, W.; Kliem, U.; Lucchini, V.
Preparative UV-Vis Laser Photochemistry: Molecular Oxygen Trapping of the Paterno-Büchi Triplet Diradicals Derived from 1,4-Dioxene
Tetrahedron Lett., 1986, 27, 2953-2956

260
Adam, W.; Baader, W.J.; Cilento, G.
Enols of Aldehydes in the Peroxidase-Oxidase-Promoted Generation of Excited Triplet Species
Biochim. Biophys. Acta, 1986, 881, 330-336

261
Adam, W.; Crämer, E.
Transannular Ring Expansion of the Spirocyclopropane Moiety in the Acid-Catalyzed Rearrangement of Oxiranes Derived from Norbornane and Bicyclo[2.2.2]octane
Tetrahedron Lett., 1986, 27, 3361-3364

262
Adam, W.; Berkessel, A.; Krimm, S.
Photochemical Decarbonylation of 2,2,4,4-Tetramethyl-6-oxabicyclo[3.1.0]hexan-3-one: An Entry into the Diradical Manifold of the Novel 3-Oxadi-p-methane Rearrangement
J. Am. Chem. Soc., 1986, 108, 4556-4561

263
Adam, W.; Oppenländer, T.
185-nm Photochemistry of Olefins, Strained Hydrocarbons and Azoalkanes
Angew. Chem., 1986, 98, 659-670; Angew. Chem., Int. Ed. Engl., 1986, 25, 661-672

264
Adam, W.; Dörr, M.; Hössel, P.
UV-VIS Laser Photochemistry: Intermediary Formation of Diazoalkanes versus Direct So,T1 Transitions in the Photolysis of Azoalkanes
Angew. Chem., 1986, 98, 820-822; Angew. Chem., Int. Ed. Engl., 1986, 25, 818-819

265
Adam, W.; Dörr, M.
Synthesis of Urazoles via Cycloaddition by Employing 4-Phenyl-4H-1,2,4-triazole-3,5-dione (PTAD) Transfer
Synthesis, 1986, 854-855

266
Adam, W.; Lucchini, V.; Pasquato, L.; Peters, E.-M.; Peters, K.; von Schnering, H.G.; Seguchi, K.
Unusual Rearrangement in the Cycloaddition of 4-Phenyl-4H-1,2,4-triazole-3,5-dione (PTAD) with Substituted 7-Methylenenorbornenes
Chem. Ber., 1986, 119, 2932-2941

267
Adam, W.; Griesbeck, A.; Klärner, F.-G.; Schöer, D.
[p2+p2]-Cycloaddition of 4-Phenyl-4H-1,2,4-triazole-3,5-dione and Singlet Oxygen with Homofuran
Angew. Chem., 1986, 98, 1006-1007; Angew. Chem., Int. Ed. Engl., 1986, 25, 989-990

268
Adam, W.; Griesbeck, A.
Regioselective Synthesis of 3-Hydroperoxy-2-methylenebutyric Acid Functionalities via Photooxygenation of Tiglic Acid Derivatives
Synthesis, 1986, 1050-1052

269
Adam, W.; Griesbeck, A.; Kappes, D.
On the Reaction of a-Methylene-ß-Peroxy Lactones with Olefins
J. Org. Chem., 1986, 51, 4479-4481

270
Adam, W.; Catalani, L.H.; Griesbeck, A.
Diastereoselective Ene Reaction in the Photooxygenation of the Silyl Cyanohydrins of a,ß-Unsaturated Aldehydes: Necessity for a Common Symmetrical Intermediate of the Perepoxide Type
J. Org. Chem., 1986, 51, 5494-5496

271
Adam, W.; Beinhauer, A.; Epe, B.; Fuchs, R.; Griesbeck, A.; Hauer, H.; Mützel, P.; Nassi, L.; Schiffmann, D.; Wild, D.
Genotoxic Effects of 1,2-Dioxetanes
In Friedberg, T.; Oesch, F. ,Eds.; Primary Changes and Control Factors in Carcinogenesis, Deutscher Fachschriften-Verlag: Wie 1986

1987

272
Adam, W.; Pasquato, L.
3,4-Epoxy-5-hydroxycyclopentene via Titanium(IV)-Catalyzed Photooxygenation and its Pyrolysis to 2,4-Pentadienoic Acid
Tetrahedron Lett., 1987, 28, 311-314

273
Adam, W.; Platsch, H.
Reliable and Selective Reagent for Cyclic Azo Compounds
Chem. Ber., 1987, 120, 251-252

274
Adam, W.; Dörr, M.
Evidence for Diazenyl Diradical in the Photoisomerization of 4-Methylene-3,3,5,5-tetramethylpyrazoline
J. Am. Chem. Soc., 1987, 109, 1240-1241

275
Adam, W.; Dörr, M.
Wagner-Meerwein Rearrangements of Radical Cations Generated by Triphenylpyrylium Tetrafluoroborate-Sensitized Electron Transfer of Azoalkanes
J. Am. Chem. Soc., 1987, 109, 1570-1572

276
Adam, W.; Carballeira, N.; Crämer, E.; Peters, E.-M.; Peters, K.; von Schnering, H.G.
Transannular Ring Expansion in Electrophilic Reactions of Spirocyclopropane-Substituted Norbornene and its Oxirane and Azirane Derivatives
Chem. Ber., 1987, 120, 521-529

277
Adam, W.; De Lucchi, O.; Pasquato, L.; Will, B.
Cycloaddition Behavior of 2-Substituted Norbornadienes towards 4-Phenyl-4H-1,2,4-triazole-3,5-dione (PTAD): Homo Diels-Alder Reactivity versus Insertion, Rearrangement and [2+2] Cycloaddition
Chem. Ber., 1987, 120, 531-535

278
Adam, W.; Carballeira, N.; Crämer, E.; Lucchini, V.; Peters, E.-M.; Peters, K.; von Schnering, H.G.
1,3-Dipolar Cycloadditions with the Keto- and Spirocyclopropane-Substituted Norbornenes Bicyclo[2.2.1]hept-5-en-2-one and Spiro(bicyclo[2.2.1]hept-5-ene-2,1'-cyclopropane)
Chem. Ber., 1987, 120, 695-703

279
Adam, W.; Crämer, E.; Peters, E.-M.; Peters, K.; von Schnering, H.G.
Transannular Ring Expansion in the Acid-Catalyzed Reaction of the Oxirane Derived from Spirocyclopropane-Substituted Bicyclo[2.2.2]oct-2-ene
Chem. Ber., 1987, 120, 705-712

280
Adam, W.; Chan, Y.-Y.; Cremer, D.; Gauss, J.; Scheutzow, D.; Schindler, M.
Spectral and Chemical Properties of Dimethyldioxirane as Determined by Experiment and ab initio Calculations
J. Org. Chem., 1987, 52, 2800-2803

281
Adam, W.; Beinhauer, A.; Fischer, R.; Hauer, H.
Psoralen-Substituted Dioxetanes as Intercalators for Photogenotoxic Studies
Angew. Chem., 1987, 99, 817 - 818; Angew. Chem., Int. Ed. Engl., 1987, 26, 796-797

282
Adam, W.; Casado, A.; Miranda, M.A.
Cerium(VI)-Catalyzed Single-Electron Transfer (SET) on Acenaphthene and 1,4-Dihydronaphtho[1,8-d,e][1,2]diazepine: Chemical Evidence for Distinct Radical Cations
Angew. Chem., 1987, 99, 818-819; Angew. Chem., Int. Ed. Engl., 1987, 26, 797-798

283
Adam W.; Hannemann, K.; Peters, E.-M.; Peters, K.; von Schnering, H.G.; Wilson, R.M.
Nitrogen Extrusion from the Bis-Azoalkane [(anti(syn))]-7,7'-Bi-2,3-diazabicyclo[2.2.1]hept-2-ene
J. Am. Chem. Soc., 1987, 109, 5250-5260

284
Nassi, L.; Epe, B.; Schiffmann, D.; Adam, W.; Beinhauer, A.; Griesbeck, A.G.
Induction of Morphological Transformation and Micronuclei in Syrian Hamster Embryo Fibroblasts by 1,2-Dioxetanes. Correlation with Single Strand Breaks in HL-60 Cells
Carcinogenesis, 1987, 8, 947-953

285
Adam, W.; Bhushan, V.; Fuchs, R.; Kirchgäßner, U.
Functionalized 1,2-Dioxetanes as Potential Phototherapeutic Agents: The Synthesis of Carboxylate, Carbonate, Carbamate and Ether Derivatives of 3-(Hydroxymethyl)-3,4,4-trimethyl-1,2-dioxetane
J. Org. Chem., 1987, 52, 3059-3062

286
Adam, W.; Fuchs, R.; Kirchgäßner, U.
Functionalized 1,2-Dioxetanes as Potential Photogenotoxic Agents: 1,2-Dioxetanes with Electrophilic Chemical Handles for the Functionalization with Protic Nucleophiles
Chem. Ber., 1987, 120, 1565-1571

287
Adam, W.; Günther, E.; Hössel, P.; Platsch, H.; Wilson, R.M.
UV-Laser Photochemistry: Evidence for Through-Bond Coupling in the Lifetime of 2,2-Dimethyl-1,3-cyclopentadiyl Triplet Diradicals
Tetrahedron Lett., 1987, 28, 4407-4410

288
Adam, W.; Crämer, E.; Lucchini, V.; Peters, E.-M.; Peters, K.; von Schnering, H.G.; Staab, E.
Transannular Ring Expansion in the Acid-Catalyzed Reaction of the Oxirane Derived from Spirocyclopropane-Substituted Bicyclo[3.2.1]octene
Chem. Ber., 1987, 120, 1719-1729

289
Adam, W.; Dörr, M.; Kron, J.; Rosenthal, R.J.
On the Question of Diradical Intermediates in the Di-p-Methane Rearrangement of Benzobicyclo[3.2.1]octadienes: Azoalkanes as Mechanistic Probes
J. Am. Chem. Soc., 1987, 109, 7074-7081

290
Adam, W.; Hössel, P.; Hümmer, W., Platsch, H.; Wilson, R.M.
UV-Laser Photochemistry: Diffusion-Controlled Trapping of Cyclic 1,3-Diradials by Molecular Oxygen - Conformational Effects on Triplet Lifetimes
J. Am. Chem. Soc., 1987, 109, 7570-7572

291
Adam, W.; Grabowski, S.; Wilson, R.M.; Hannemann, K.; Wirz, J.
UV-Laser Photochemistry of the Azoalkane 1-Phenyl-2,3-diazabicyclo[2.2.2]oct-2-ene: Detection and Lifetime Determination of the Triplet Diradical 1-Phenyl-1,4-cyclohexanediyl by Trapping with Molecular Oxygen and by Time-Resolved UV Spectroscopy (Flash Photolysis)
J. Am. Chem. Soc., 1987, 109, 7572-7573

292
Adam, W.; Miranda, M.A.
Thermal and Photochemical Reactions of Bicyclic Azoalkanes in Concentrated Sulfuric Acid
J. Org. Chem., 1987, 52, 5498-5500

293
Adam, W.; Crämer, E.
Acid-Catalyzed Reactions of 1-Oxadispiro[2.2.2.1]nonane: In Search of Transannular Ring Expansion in Monocyclic Substrates
Chem. Ber., 1987, 120, 1921-1924

294
Adam, W.; Grabowski, S.; Hinz, R.F.; Lucchini, V.; Peters, E.-M.; Peters, K.; Rebollo, H.; von Schnering, H.G.
Synthesis and Transformations of Urazoles Derived from 7,7-Dicarboxynorcaradiene: Formation of 2,4-Dioxahexahydro-1,3,5-triazines via an Unusual Base-Catalyzed Rearrangement
Chem. Ber., 1987, 120, 2075-2079

1988

295
Adam, W.; Lupón, P.
Quinol Epoxides from p-Cresol and Estrone by Photooxygenation and Titanium(IV)- or Vanadium(V)-Catalyzed Oxygen Transfer
Chem. Ber., 1988, 121, 21-25

296
Adam, W.; Grabowski, S.; Miranda, M.A.; Rübenacker, M.
Generation of the 1,4-Diphenylcyclohexane-1,4-diyl Radical Cation by Ce(IV)-Catalyzed Denitrogenation of the Azoalkane 1,4-Diphenyl-2,3-diazabicyclo[2.2.2]oct-2-ene and its Reluctance to Undergo Cope Rearrangement
Chem. Commun., 1988, 142-143

297
Adam, W.; Staab, E.
Regio-Controlled Functionalization of 2,5-Dimethyl-2,4-hexadiene into Epoxy Alcohols by Photooxygenation in the Presence of Titanium (IV) or Vanadium (V)
Tetrahedron Lett., 1988, 29, 531-534

298
Adam, W.; Catalani, L.H.; Griesbeck, A.G.
Trialkylsilyl Protecting Groups in the Synthesis of a-Hydroperoxy Carbonyl Compounds
In Silicon Chemistry: Corey, E.J., Corey, J.Y., Gaspar, P.P., Eds.; Ellis Horwood Ltd.: Chichester, England 1988; pp 15-24

299
Nassi, L.; Schiffmann, D.; Favre, A.; Adam, W.; Fuchs, R.
Induction of the SOS Function sfiA in E.coli by Systems which Generate Triplet Ketones
Mutat. Res., 1988, 198, 53-60

300
Adam, W.; Epe, B.; Schiffmann, D.; Vargas, F.; Wild, D.
Facile Reduction of 1,2-Dioxetanes by Thiols such as Glutathione as Potential Protective Measure against Photochemical Damage of Cellular DNA
Angew. Chem., 1988, 100, 443-445; Angew. Chem., Int. Ed. Engl., 1988, 27, 429-431

301
Adam, W.; Griesbeck, A.G.; Gollnick, K.; Knutzen-Mies, K.
1,2-Dioxetanes Derived from 4,5-Dimethyl-2,3-dihydrofuran and 4,5-Dimethyl-2,3-dihydrothiophene: Synthesis via Photooxygenation, Activation Parameters, and Excitation Properties
J. Org. Chem., 1988, 53, 1492-1495

302
Adam, W.; Kliem, U.; Lucchini, V.; Peters, E.-M.; Peters, K.; von Schnering, H.G.
[4+2] Cycloaddition of Disubstituted Homobenzoquinones with Cyclopentadiene
Chem. Ber., 1988, 121, 1063-1067

303
Adam, W.; Staab, E.
Regio- and Stereo-Controlled Oxygen Functionalization of Cholesterol by Photooxygenation in the Presence of Tetraisopropoxide
Liebigs Ann. Chem., 1988, 757-759

304
Adam, W.; Schwarm, M.
How Mechanistically Equivalent are Singlet Oxygen and Triazolinedione? Regiochemical and Stereochemical Differences in their Ene Reactions with Allyl Silanes
J. Org. Chem., 1988, 53, 3129-3130

305
Cilento, G.; Adam, W.
Photochemistry and Photobiology without Light
Photochem. Photobiol., 1988, 48, 361-368

306
Adam, W.; Kliem, U.; Lucchini, V.
Preparative UV-Vis Laser Photochemistry: Photocycloaddition of Methylenelactones with Benzophenone and p-Benzoquinone. Oxygen Trapping of Paterno-Büchi Triplet 1,4-Diradicals as Model Reactions for Qinghaosu-Type 1,2,4-Trioxanes
Liebigs Ann. Chem., 1988, 869-875

307
Epe, B.; Mützel, P.; Adam, W.
DNA Damage by Oxygen Radicals and Excited State Species: A Comparative Study Using Enzymatic Probes in vitro
Chem.-Biol. Interactions, 1988, 67, 149-165

308
Adam, W.; Kliem, U.; Mosandl, T.; Peters, E.-M.; Peters K.; von Schnering, H.G.
Preparative Visible-Laser Photochemistry: Qinghaosu-Type 1,2,4-Trioxanes by Molecular Trapping of Paterno-Büchi Triplet 1,4-Diradicals Derived from 3,4- Dihydro-4,4-dimethyl-2H-pyran-2-one and Quinones
J. Org. Chem., 1988, 53, 4986-4992

309
Adam, W.; Kliem, U.; Peters, E.-M.; Peters, K.; von Schnering, H.G.
Preparative Vis-Laser Photochemistry: Qinghaosu-Type 1,2,4-Trioxanes by Molecular-Oxygen Trapping of Paterno-Büchi Triplet 1,4-Diradicals Derived from the Bicyclic Enol Lactones D1,6- and D 1,10-2-Oxabicyclo[4.4.0]decen-2-one and p-Benzoquinone
J. Prakt. Chem., 1988, 330, 391-405

310
Adam, W.; Hasemann, L.; Prechtl, F.
alpha-Methylene-beta-Lactone: A Novel Heterocyclic Ring System via Deoxygenation of alpha-Methylene-beta-peroxylactones with Triphenylphosphine
Angew. Chem., 1988, 100, 1594-1595; Angew. Chem., Int. Ed. Engl., 1988, 27, 1536-1537

311
Adam, W.; Grabowski, S.; Scherhag, F.
UV-Laser Photochemistry: Generation of the Triplet Spiro[2.6]nona-4,7-diyl Diradical by Nitrogen Extrusion from the Azoalkane 6,7-Diazaspiro[bicyclo(3.2.2)nona-6-ene-2,1'-cyclopropane]. Conformational Influence on the Lifetime of a 1,4-Cycloheptadiyl as Determined by the Cyclopropylcarbinyl "Free-Radical Clock"
Tetrahedron Lett., 1988, 29, 5637-5640

312
Adam, W.; Kömmerling, S.; Peters, E.-M.; Peters, K.; von Schnering, H.G.; Schwarm, M.; Staab, E.; Zahn, A.
Regioselective Ene Reaction in the Photooxygenation of Symmetrically Tetrasubstituted Ethenes and the Ti(IV)-Catalyzed Epoxy-Hydroxylation of their Allylic Hydroperoxides
Chem. Ber., 1988, 121, 2151-2155

313
Adam, W.; Grabowski, S.
UV-Laser Photochemistry: Nitrogen Extrusion from the Azoalkane 4,5-Diazatricyclo[4.4.0.0.3,8]dec-4-ene. Lifetime Determination of Bicyclo[2.2.2]octa-2,5-diyl by Dioxygen Trapping
Tetrahedron Lett., 1988, 29, 6605-6608

314
Adam, W.; Hasemann, L.; Vargas, F.; Epe, B.; Schiffmann, D.; Wild, D.
Single-Electron Transfer (SET) Leading to Radical Species in the Redox Reactions of Cyclic Peroxides with Biological Substrates
In Organic Free Radicals, Fischer, H., Heimgartner, H., Eds.; Springer Verlag: Berlin 1988; pp 219-220

1989

315
Adam, W.; Vargas, F.; Epe, B.; Schiffmann, D.; Wild, D.
Single-Electron Transfer in the Reduction of 1,2-Dioxetanes by Biologically Active Substrates
Free Rad. Res. Comm., 1989, 5, 253-258

316
Adam, W.; Braun, M.; Griesbeck, A.; Lucchini, V.; Staab, E.; Will, B.
Photooxygenation of Olefins in the Presence of Titanium (IV) Catalyst: A Convenient One-Pot Synthesis of Epoxy Alcohols
J. Am. Chem. Soc., 1989, 111, 203-212

317
Adam, W.; Lucchini, V.; Peters, M.-E.; Peters, K.; Pasquato, L.; von Schnering, H.G.; Seguchi, K.; Walter, H.; Will, B.
Cycloaddition of 4-Phenyl-4H-1,2,4-triazole-3,5-dione (PTAD) to 7-Alkylidene-2,3-benzonorbornadienes
Chem. Ber., 1989, 122, 133-143

318
Adam, W.; Catalani, L.H.; Saha-Möller, C.R.; Will, B.
Synthesis of Trialkylsilylated a-Hydroperoxy Aldehydes and Ketones via Ozonolysis of Protected Allylic Hydroperoxides
Synthesis, 1989, 121-124

319
Adam, W.; Grabowski, S.; Platsch, H.; Hannemann, K.; Wirz, J.; Wilson, R.M.
UV-Laser Photochemistry of Azoalkanes: Surprising Effects of Phenyl Substitution on the Lifetimes of 1,3-Cyclopentadiyl and 1,4-Cyclohexanediyl Triplet Diradicals
J. Am. Chem. Soc., 1989, 111, 751-753

320
Adam, W.; Grabowski, S.; Wilson, R.M.
UV-Laser Photochemistry: Trapping of the Norrish Type II Triplet Diradical 1-Hydroxy-4-methyl-1-phenyl-1,4-pentanediyl with Molecular Oxygen
Chem. Ber., 1989, 122, 561-564

321
Adam, W.; Curci, R.; Edwards, J.O.
Dioxiranes: A New Class of Powerful Oxidants
Acc. Chem. Res., 1989, 22, 205-211

322
Adam, W.; De Lucchi, O.; Dörr, M.
On the Mechanism of the Di-p-methane Rearrangement of Bicyclo[3.2.1]octa-2,6-diene: Deuterium Labeling and Generation of Diradical Intermediates via Photolysis and Thermolysis of Appropriate Azoalkanes
J. Am. Chem. Soc., 1989, 111, 5209-5213

323
Adam, W.; Platsch, H.; Wirz, J.
Oxygen Trapping and Thermochemistry of a Hydrocarbon Singlet Biradical: 1,3-Diphenylcyclopentane-1,3-diyl
J. Am. Chem. Soc., 1989, 111, 6896-6898

324
Adam, W.; Hadjiarapoglou, L.; Jäger, V.; Seidel, B.
Epoxidation of g-Methylene-b-Butyrolactones by Dimethyldioxirane
Tetrahedron Lett., 1989, 30, 4223-4226

325
Adam, W.; Beinhauer, A.; Hauer, H.
Activation Parameters and Excitation Yields of 1,2-Dioxetane Chemiluminescence
In Handbook of Organic Photochemistry: Scaiano, J.C., Ed.; CRC Press: Boca Raton, Florida, USA 1989; Vol. II, pp 271-327

326
Adam, W.; Hückmann, S.; Vargas, F.
Direct Observation of Electron Transfer Between Phenothiazines and 1,2-Dioxetanes
Tetrahedron Lett., 1989, 30, 6315-6318

327
Adam, W.; Hadjiarapoglou, L.; Wang, X.
Epoxidation of Silyl Enol Ethers, Phthalides, and Enol Esters by Dimethyldioxirane
Tetrahedron Lett., 1989, 30, 6497-6500

1990

328
Adam, W.; Hadjiarapoglou, L.; Nestler, B.
Dimethyldioxirane Epoxidation of a,b-Unsaturated Ketones, Acids and Esters
Tetrahedron Lett., 1990, 31, 331-334

329
Camporeale, M.; Fiorani, T.; Troisi, L.; Adam, W.; Curci, R.; Edwards, J.O.
On the Mechanism of the Bayer-Villiger Oxidation of Ketones by Bis(trimethylsilyl) Peroxomonosulfate. Intermediacy of Dioxiranes
J. Org. Chem., 1990, 55, 93-98

330
Adam, W.; Finzel, R.
UV-Laser Photochemistry: Retro Cleavage in the Benzophenone-Sensitized Photolysis of D3-1,3,4-Oxadiazolines into Diazoalkanes
Tetrahedron Lett., 1990, 31, 863-866

331
Adam, W.; Wang, X.
Photooxygenation of 1,2-Bis(Silyloxy)cycloalkenes
Tetrahedron Lett., 1990, 31, 1245-1248

332
Adam, W.; Kades, E.; Wang, X.
Photooxygenation of 3- and 2-Silyloxybenzofurans Rearrangement of Dioxetanes via a-Silylperoxy Ketones into Ketoester Cleavage Products
Tetrahedron Lett., 1990, 31, 2259-2262

333
Adam, W.; Grabowski, S.; Wilson, R.M.
Localized Cyclic Triplet Diradicals. Lifetime Determination by Trapping with Molecular Oxygen
Acc. Chem. Res., 1990, 23, 165-172

334
Adam, W.; Platsch, H.; Reinhard, G.; Wirz, J.
Effect of 2,2-Dimethyl Substitution on the Lifetimes of Cyclic Hydrocarbon Triplet 1,3-Biradicals
J. Am. Chem. Soc., 1990, 112, 4570-4571

335
Adam, W.; Hasemann, L.
a-Methylene-ß-S-thiolactone: Synthesis of a New Heterocycle via Sulfurization of a-Methylene-ß-lactone and its Structure
Chem. Ber., 1990, 123, 1449-1451

336
Simpson, C.J.S.M.; Price, J.; Holmes, G.; Adam, W.; Martin, H.D.; Bish, S.
Dynamics of the Thermal Dissociation of Unsaturated Cyclic Ketones: Nascent Vibrational Energy Distributions in the Products
J. Am. Chem. Soc., 1990, 112, 5089-5094

337
Adam, W.; Mello, R.; Curci, R.
Oxygen-Atom Insertion into Silicon-Hydrogen Bonds by Dioxiranes: A Stereoselective and Direct Conversion into Silanols
Angew. Chem., 1990, 102, 916-917; Angew. Chem., Int. Ed. Engl., 1990, 29, 890-891

338
Adam, W.; Beinhauer, A.; Hauer, H.; Saha-Möller, C.R.
Activation Parameters and Excitation Yields of 1,2-Dioxetanes of Photogenotoxic Interest
J. Prakt. Chem., 1990, 332, 161-168

339
Neuman,Jr., R.C.; Berge, C.T.; Binegar, G.A.; Adam, W.; Nishizawa, Y.
cis-Diazenes: Pressure Effects on their Thermal Deazatization and Isomerization Reactions.
J. Org. Chem., 1990, 55, 4564-4568

340
Adam, W.; Hadjiarapoglou, L.; Siegmeier, R.
Verfahren zur Herstellung von Glycidylethern durch Epoxidation der Allylether
Deutsche Patentanmeldung, Patentnummer P 40 23 741.9, 26.07.1990. 1990

341
Adam, W.
Chemiluminescence and Bioluminescence.
In Ullmann's Encyclopedia of Industrial Chemistry, Luminescent Materials; VCH: Weinheim, Germany 1990; Vol.A 15, Chap 2, pp 548-557

342
Adam, W.; Hadjiarapoglou, L.
Epoxidation of ß-Keto Enol Ethers by Dimethyldioxirane
Chem. Ber., 1990, 123, 2077-2079

343
Adam, W.; Beinhauer, A.; Mosandl, T.; Saha-Möller, C.R.; Vargas, F.; Epe, B.; Müller. E.; Schiffmann, D.; Wild, D.
Photobiological Studies with Dioxetanes in Isolated DNA, Bacteria and Mammalian Cells
Environmental Health Perspectives, 1990, 88, 89-97

344
Albrecht, S.; Brandl, H.; Adam, W.
Chemilumineszenz Reaktionen. Die Chemilumineszenz und ihre Anwendung in der klinischen Chemie, Biochemie und Medizin
Chemie in unserer Zeit, 1990, 24, 227-238

345
Adam, W.; Hadjiarapoglou, L.; Klicic, J.
Dimethyldioxirane Epoxidation of Enol Phosphates
Tetrahedron Lett., 1990, 31, 6517-6520

346
Adam, W.; Nestler, B.
A Regio- and Diastereoselective Ene Reaction of Singlet Oxygen with Dialkyl-Substituted Acrylic Esters
Liebigs Ann. Chem., 1990, 1051-1053

347
Adam, W.; Hauer, H.; Mosandl, T.; Saha-Möller, C.R.; Wagner, W.; Wild, D.
Furocoumarin-, Naphthofuran-, and Furoquinoline-Annulated 1,2-Dioxetanes: Synthesis, Thermolysis, and Mutagenicity
Liebigs Ann. Chem., 1990, 1227-1236

1991

348
Adam, W.; Albrecht, O.; Feineis, E.; Reuter, I.; Saha-Möller, C.R.; Seufert-Baumbach, P.; Wild, D.
Benzofuran Dioxetanes, a New Class of Mutagenic Agents: Synthesis by Photooxygenation of Benzofuran Derivatives
Liebigs Ann. Chem., 1991, 33-40

349
Adam, W.; Hadjiarapoglou, L.; Smerz, A.
Dioxirane Epoxidation of alpha,beta-Unsaturated Ketones
Chem. Ber., 1991, 124, 227-232

350
Adam, W.; Balci, M.; Ceylan, Z.; Hinz, R.F.
Reactions of Benzocycloheptatrienes with Dienophiles
Chem. Ber., 1991, 124, 383-386

351
Adam, W.; Hadjiarapoglou, L.; Mosandl, T.; Saha-Möller, C.R.; Wild, D.
Synthesis of 2,3-Epoxide of 2,3-Dimethylbenzo[b]furan, the Proposed Ultimate Mutagen of the Benzofuran Dioxetanes
Angew. Chem., 1991, 103, 187-189; Angew. Chem., Int. Ed. Engl., 1991, 30, 200-202

352
Adam, W.; Golsch, D.; Hadjiarapoglou, L.; Patonay, T.
Dimethyldioxirane Epoxidation of Flavones
Tetrahedron Lett., 1991, 32, 1041-1044

353
Adam, W.; Hadjiarapoglou, L.; Wang, X.
Dimethyldioxirane Epoxidation of Alkenes with Two Electron-Donating Substituents
Tetrahedron Lett., 1991, 32, 1295-1298

354
Adam, W.; Heil, M.
The Photochemical Generation of a-Sulfur-Substituted Cyclopropylcarbinyl Radicals and their Utilization as Mechanistic Probe for Electron Transfer in the Peroxide-Sulfide Reaction
J. Am. Chem. Soc., 1991, 113, 1730-1736

355
Adam, W.; Bottle, S.E.
Benzophenone-Sensitized Photolysis of the Azoalkane Diazabicyclo[2.2.1]hept-2-ene (DBH): Trapping of the 1,3-Cyclopentadiyl Triplet Diradical by a Nitroxide
Tetrahedron Lett., 1991, 32, 1405-1408

356
Adam, W.; Mosandl, T.; Dall'Acqua, F.; Vedaldi, D.
Photobinding of Psoralen to DNA via Triplet Ketones Generated Thermally from Dioxetanes
J. Photochem. Photobiol. B: Biol., 1991, 8, 431-437

357
Adam, W.; González Nuñez, M.E.
Oxygen Transfer by Dissociative Electron Transfer, Reaction of Tetranitromethane with Diazo Compounds and Sulfides
Tetrahedron Lett., 1991, 47, 3773-3778

358
Adam, W.; Finzel, R.; Kita, F.
Benzophenone-Sensitized Two-Photon Chemistry of Azoalkanes in the Laser/Liquid Jet: Evidence for Photoinduced Hydrogen 1,2-Shift in 1,3-Cyclopentadiyl Triplet Diradicals
Tetrahedron Lett., 1991, 32, 2211-2214

359
Adam, W.; Brünker, H.-G.; Nestler, B.
Photooxygenation of 2-Alkenyl-Substituted Chiral Oxazolines: Stereochemical Evidence Favoring the cis Effect in the Regio-Selective Ene Reaction of Singlet Oxygen with a,b-Unsaturated Carbonyl Derivatives
Tetrahedron Lett., 1991, 32, 1957-1960

360
Abou-Elzahab, M.; Adam, W.; Saha-Möller, C.R.
Epoxidation of Allylic Hydroperoxides by Dimethyldioxirane and Peroxy Acids
Liebigs Ann. Chem., 1991, 445-450

361
Adam, W.; Alt, C.; Braun, M.; Denninger, U.; Zang, G.
Central and Lateral Bicyclo[1.1.0]butane Bond Cleavage with Subsequent Wagner-Meerwein Rearrangement or Carbene Formation in the 185-nm Photolysis of Tricyclo[3.1.0.02,6]hexane, Tricyclo[4.1.0.02,7]heptane and Tricyclo[5.1.0.02,8 ]octane
J. Am. Chem. Soc., 1991, 113, 4563 - 4571

362
Adam, W.; Zang, G.
185-nm Photolysis and Pyrolysis of the Spirocyclopropane-Substituted Azoalkanes of 2,3-Diazatricyclo[4.3.0.04,9]non-2-ene and their Denitrogenated Hydrocarbon Products, the Tricyclo[3.2.0.02,7]heptanes
J. Org. Chem., 1991, 56, 3315-3323

363
Simpson, C.J.S.M.; Wilson, G.J.; Adam, W.
The Dynamics of the Thermal Decomposition of 2,3-Diazabicyclo[2.2.1]hept-2-ene
J. Am. Chem. Soc., 1991, 113, 4728-4732

364
Adam, W.; Bottle, S.E.; Mello, R.
Photolysis of Dioxiranes in the Presence of a Nitroxide Radical Scavenger: The Intermediacy of Radical Anion and Diyl Species in the Production and Trapping of Methyl and Trifluoromethyl Radicals
Chem. Commun., 1991, 771-773

365
Adam, W.; Wang, X.
Photooxygenation of Silyl Ketene Acetals: Dioxetanes as Precursors to a-Silylperoxy Esters in the Silatropic Ene Reaction
J. Org. Chem., 1991, 56, 4737-4741

366
Adam, W.; Haas, W.; Lohray, B.B.
Thianthrene-5-Oxide as Mechanistic Probe for Assessing the Electronic Character of Oxygen-Transfer Agents
J. Am. Chem. Soc., 1991, 113, 6202-6208

367
Adam, W.; Bottle, S.E.; Peters, K.
Cycloaddition of Nitrosobenzene to a Trimethylenemethane Diradical: The First Case of Isoxazoline Formation from in situ Generated Nitroxides through Spin Trapping
Tetrahedron Lett., 1991, 32, 4283-4286

368
Abou-Elzahab, M.M.; Adam, W.; Saha-Möller, C.R.
Photooxygenation of Some Potentially Skin-Photosensitizing Furocoumarines: Imperatorin, Alloimperatorin and its Methyl Ether and Acetate Derivatives
Liebigs Ann. Chem., 1991, 967-970

369
Adam, W.; Albert, R.; Dachs Grau, N.; Hasemann, L.; Nestler, B.; Peters, E.-M.; Peters, K.; Prechtl, F.; von Schnering, H.G.
Synthesis of alpha-Methylene-beta-lactones, Novel Heterocycles
J. Org. Chem., 1991, 56, 5778-5781

370
Adam, W.; Albert, R.; Hasemann, L.; Nava Salgado, V.O.; Nestler, B.; Peters, E.M.; Peters, K.; Prechtl, F.; von Schnering, H.G.
a-Methylene-b-lactones as Masked Allenes and Allene Equivalents: Some Selected Chemical Transformations
J. Org. Chem., 1991, 56, 5782-5785

371
Adam, W.; Andler, S.; Heil, M.
Novel Reactions of Disubstituted 1,2-Dioxetanes with Olefins as p-Nucleophiles: Cycloaddition Products from Intermediary 1,6-Dipoles
Angew. Chem., 1991, 103, 1395-1396; Angew. Chem., Int. Ed. Engl., 1991, 30, 1365-1366

372
Adam, W.; Curci, R.; González Nuñez, M.E.; Mello, R.
Thermally and Photochemically Initiated Radical Chain Decomposition of Ketone-Free Methyl(trifluoromethyl)dioxirane
J. Am. Chem. Soc., 1991, 113, 7654-7658

373
Adam, W.; Hadjiarapoglou, L.; Jäger, V.; Klicic, J.; Seidel, B.; Wang, X.
Epoxidation of Enol Silyl Ethers, Phosphates, Esters and Lactones by Dimethyldioxirane
Chem. Ber., 1991, 124, 2361-2368

374
Adam, W.; Prechtl, F.
Highly Efficient Hydroxylation of Carbonyl Compounds with Dimethyldioxirane
Chem. Ber., 1991, 124, 2369-2372

375
Adam, W.; Bialas, J.; Hadjiarapoglou, L.
A Convenient Preparation of Acetone Solutions of Dimethyldioxirane
Chem. Ber., 1991, 124, 2377

376
Adam, W.; Hadjiarapoglou, L.; Mosandl, T.; Saha-Möller, C.R.; Wild, D.
Chemical Studies on the Mutagenesis of Benzofuran Dioxetanes in the Ames Test: Evidence for the Benzofuran Epoxide as Ultimate Mutagen
J. Am. Chem. Soc., 1991, 113, 8005-8011

377
De Lucchi, O.; Adam, W.
Di-p-methane Photoisomerizations
In Comprehensive Organic Synthesis, B.M. Trost, I. Fleming; Eds. in-Chief; Combining C-C p-Bonds; Paquette, L.A., Ed.; Per 1991; Vol. 5, pp 193-214

378
Adam, W.; Bottle, S.E.; Peters, K.; Peters, E.-M.; von Schnering, H.G.
Crystal Structure of 2,4,4-Triphenyl-2-aza-3-oxabicyclo[3.3.0]oct-5-ene, C24H21NO
Z. Kristallogr., 1991, 197, 309-311

379
Adam, W.; Hadjiarapoglou, L.; Meffert, A.
Dimethyldioxirane Epoxidation of 6,6-Disubstituted Fulvenes
Tetrahedron Lett., 1991, 32, 6697-6700

380
Wilson, R.M.; Adam, W.; Schulte-Oestrich, R.
The Photochemistry of Photochemical Transients: Multiple-Photon Chemistry in an Argon-Ion Laser Jet
Spectrum, 1991, 4, 8-17

381
Adam, W.; Hasemann, L.
a-Methylene-b-Lactones as Novel Allene Equivalents: Regioselective [4+2] Cycloaddition and Stereoselective Decarboxylation for the Introduction of exo-Alkylidene Functionalitites
Tetrahedron Lett., 1991, 32, 7033-7036

382
Ess, C.; Gerson, F.; Adam, W.
The Radical Anions of Cyclic Azoalkanes: An ESR, ENDOR, and TRIPLE-Resonance Study
Helv. Chim. Acta, 1991, 74, 2078-2093

383
Adam, W.; Wang, X.
E/Z Isomerization, Solvolysis, Addition, and Cycloaddition Reactions of (E)-tert-Butylketene Methyl tert-Butyldimethylsilyl Acetal
J. Org. Chem., 1991, 56, 7244-7250

384
Adam, W.; Golsch, D.; Hadjiarapoglou, L.; Patonay, T.
Epoxidation of Flavones by Dimethyldioxirane
J. Org. Chem., 1991, 56, 7292-7297

1992

385
Adam, W.; Bialas, J.; Hadjiarapoglou, L.; Sauter, M.
Epoxidation of 2,3-Dimethylbenzofurans by Dimethyldioxirane
Chem. Ber., 1992, 125, 231-234

386
Adam, W.; Heil, M.
Novel Transformation of 1,2-Dioxetanes. b-Hydroxy Ethers by Addition of Alkyllithium Reagents
Chem. Ber., 1992, 125, 235-241

387
Adam, W.; Richter, M.
Regio- and Diastereoselective Ene Reaction of Triazolinedione with Vinylsilanes
Chem. Ber., 1992, 125, 243-246

388
Adam, W.; Schönberger, A.
Dimethyldioxirane Oxidation of Hydroquinones into Quinones and 2,3-Dihydroxycyclohexene-1,4-diones
Tetrahedron Lett., 1992, 33, 53-56

389
Adam, W.; Hadjiarapoglou, L.
a-Oxo Sulfones by Dimethyldioxirane Oxidation of Thiol Esters
Tetrahedron Lett., 1992, 33, 469-470

390
Adam, W.; Asensio, G.; Curci, R.; González-Nuñez, M.E.; Mello, R.
Oxygen Atom Insertion into the Benzylic Carbon-Hydrogen Bond of R(-)-2-Phenylbutane by Methyl-(trifluoromethyl)dioxirane: An Efficient and Mild Regio- and Stereoselective Synthesis of S(-)-2-Phenyl-2-butanol
J. Org. Chem., 1992, 57, 953-955

391
Adam, W.; Bottle, S.; Finzel, R.; Kammel, T.; Peters, E.-M.; Peters, K.; von Schnering, H.G.; Walz, L.
Trapping of Cyclopentanediyl and Trimethylenemethane Triplet Diradicals with the Nitroxide 1,1,3,3-Tetramethyl-1,3-dihydroisoindolin-2-yloxyl
J. Org. Chem., 1992, 57, 982-988

392
Adam, W.; Bialas, J.; Hadjiarapoglou, L.; Patonay, T.
Direct Epoxidation of [E]-2'-Hydroxychalcones by Dimethyldioxirane
Synthesis, 1992, 49-51

393
Adam, W.; Griesbeck, A.G.; Klug, P.; Nestler, B.; Richter, M.; Wang, X.
Selective Oxygen Transfer I: Singlet Oxygen
In Selective Reactions of Metal Activated Molecules; H.Werner; A.G.Griesbeck; W.Adam; G.Bringmann, W.Kiefer, Eds.; Vieweg Ver 1992; pp 149-152

394
Adam, W.; Hadjiarapoglou, L.; Prechtl, F.; Saha-Möller, C.R.; Sauter, M.; Schuhmann, R.M.
Selective Oxygen Transfer II: Dioxiranes
In Selective Reactions of Metal Activated Molecules; H.Werner; A.G.Griesbeck; W.Adam, G.Bringmann, W.Kiefer, Eds.; Vieweg-Ver 1992; pp 153-156

395
Adam, W.; Griesbeck, A.G.; Wang, X.
Photooxygenation of a-Ionone and Oxygen Transfer Reactions of the Resulting Allylic Hydroperoxides
Liebigs Ann. Chem., 1992, 193-197

396
Oppenländer, T.; Zang, G.; Adam, W.
Rearrangements and Photochemical Reactions Involving Alkanes and Cycloalkanes
In The Chemistry of Alkanes and Cycloalkanes, S. Patai; Z. Rappoport, Eds.; John Wiley and Sons: New York 1992; pp 681-741

397
Adam, W.; Walter, H.; Chen, G.-F.; Williams, F.
Photochemical and ESR Spectral Evidence for a Stereoselective Rearrangement of Radical Cations Derived from Azoalkanes and Bicyclopentanes
J. Am. Chem. Soc., 1992, 114, 3007-3014

398
Adam, W.; Ouchi A.
Two-Photon Chemistry of 1,8-Bis(bromomethyl)naphthalene in the Laser-Jet: Generation of Acenaphthene by Intramolecular C-C Bond Formation
Tetrahedron Lett., 1992, 33, 1875-1878

399
Albrecht, S.; Brandl, H.; Adam, W.
Biochemische Analytik: Angewandte Chemilumineszenz
Nachr. Chem. Lab. Tech., 1992, 40, 547-554

400
Albrecht, S.; Brandl, H.; Schönfels, C.; Adam, W.
Angewandte Biolumineszenz: Luciferasen in der biochemischen Analytik
Chemie in unserer Zeit, 1992, 26, 63-69

401
Adam, W.; Andler, S.; Heil, M.; Voerckel, V.
a-Alkoxy Ketones from the Nucleophilic Substitution on the Peroxide Bond of 3,3-Disubstituted 1,2-Dioxetanes by Enamines
J. Org. Chem., 1992, 57, 2680-2682

402
Adam, W.; Hadjiarapoglou, L.; Lévai, A.
Dimethyldioxirane Epoxidation of Aurones and Isoflavones
Synthesis, 1992, 435-438

403
Adam, W.; Peters, E. M.; Peters, K.; von Schnering, H.G.; Voerckel, V.
Epoxidation of Enamines by Dimethyldioxirane: Formation of 1,4-Dioxanes by Enamine Epoxide Dimerization
Chem. Ber., 1992, 125, 1263-1266

404
Adam, W.; Finzel, R.
Cyclopropylcarbinyl Ring Opening as Mechanistic Probe for Differentiation between the Singlet and Triplet Spin States of Trimethylenemethane Diradicals (Non-Kekulé Species)
J. Am. Chem. Soc., 1992, 114, 4563-4568

405
Adam, W.; Finzel, R.; Goller, K.; Griesbeck, A.G.
Photolysis and Thermolysis of a Tetracyclic Bisazoalkane: Nitrogen Extrusion Induced by b-Cleavage
J. Am. Chem. Soc., 1992, 114, 4558-4562

406
Adam, W.; Richter, M.
Highly Regio- and Diastereoselective Synthesis of Epoxy Alcohols Directly from Vinylsilanes by Photooxygenation and Titanium-Catalyzed Oxygen Transfer
Tetrahedron Lett., 1992, 33, 3461-3464

407
Adam, W.; Azzena, U.; Prechtl, F.; Hindahl, K.; Malisch, W.
Conversion of Ferriosilanes to Ferriosilanols by Selective Oxidation of the SiH Function by Dimethyldioxirane
Chem. Ber., 1992, 125, 1409-1411

408
Adam, W.; Denninger, U.; Finzel, R.; Kita, F.; Platsch, H.; Walter, H.; Zang, G.
Comparative Study of the Pyrolysis, Photoinduced Electron Transfer (PET), Laser-Jet and 185-nm Photochemistry of Alkyl-Substituted Bicyclic Azoalkanes
J. Am. Chem. Soc., 1992, 114, 5027-5035

409
Jimenez, R.; Kable, S.H.; Loison, J.-C.; Simpson, C.J.S.M.; Adam, W.; Houston, P.L.
Photodissociation Dynamics of 3-Cyclopentenone: Using the Impact Parameter Distribution as a Criterion for Concertedness
J. Phys. Chem., 1992, 96, 4188-4195

410
Adam, W.; Heil, M.
Reaction of 1,2-Dioxetanes with Heteroatom Nucleophiles: Adduct Formation by Nucleophilic Attack at the Peroxide Bond
J. Am. Chem. Soc., 1992, 114, 5591-5598

411
Adam, W.; Schulte Oestrich, R.
Two-Photon Chemistry in the Laser Jet: Photoionization of the Diphenylmethyl Radical Generated by Norrish Type I Photocleavage of Benzhydryl Phenyl Ketone
J. Am. Chem. Soc., 1992, 114, 6031-6034

412
Schenk, W.A.; Frisch, J.; Adam, W.; Prechtl, F.
Ligand-Centered Oxidations of Organometallic Thiolates Using Dimethyldioxirane
Inorg. Chem., 1992, 31, 3329-3331

413
Abou-Elzahab, M.M.; Adam, W.; Saha-Möller, C.R.
Synthesis of Furocoumarin-Type Potential Intercalative Alkylating and Oxidizing Agents of DNA Through Dimethyldioxirane Epoxidation of Imperatorin and its Derivatives
Liebigs Ann. Chem., 1992, 731-733

414
Adam, W.; Heil, M.; Hutterer, R.
Electron versus Hydride-Ion Transfer in the Reduction of b-Halogen-Substituted 1,2-Dioxetanes by 1,4-Dihydronicotinamides
J. Org. Chem., 1992, 57, 4491-4495

415
Adam, W.; Deufel, T.; Finzel, R.; Griesbeck, A.G.; Hirt, J.
Generation and Interception of Isodicyclopentadiene Tautomers by Diene Transmissive Diels-Alder Reaction of a 1,5-Dihydropentalene with a Variety of Dienophiles
J. Org. Chem., 1992, 57, 3991-3994

416
Adam, W.; Nestler, B.
Photooxygenation of Chiral Allylic Alcohols: Hydroxy-Directed Regio- and Diastereoselective Ene Reaction
J. Am. Chem. Soc., 1992, 114, 6549-6550

417
Curci, R.; D'Accolti, L.; Fiorentino, M.; Fusco, C.; Adam, W.; González Nuñez, M.E.; Mello, R.
Oxidation of Acetals, an Orthoester, and Ethers by Dioxiranes Through a-CH Insertion
Tetrahedron Lett., 1992, 33, 4225-4228

418
Adam, W.; Schönberger, A.
Application of the Marcus Theory on the Reaction of Substituted Benzoyl Peroxides with Hydroquinones: Evidence for an Inner-Sphere Electron-Transfer (ET) Mechanism
Chem. Ber., 1992, 125, 2149-2153

419
Adam, W.; Asensio, G.; Curci, R.; González Nuñez, M.E.; Mello, R.
One-Electron Reduction of Methyl(trifluoromethyl)dioxirane by Iodide Ion. Evidence for an Electron-Transfer Chain Reaction Mediated by the Superoxide Ion
J. Am. Chem. Soc., 1992, 114, 8345-8349

420
Adam, W.; Hadjiarapoglou, L.; Curci, R.; Mello, R.
Dioxiranes, 3-Membered-Ring Cyclic Peroxides
In Organic Peroxides; W. Ando, Ed.; John Wiley and Sons: Chichester 1992; pp 195-219

421
Adam, W.; Heil, M.; Mosandl, T.; Saha-Möller, C.R.
Dioxetanes and a-Peroxy Lactones, Four-Membered-Ring Cyclic Peroxides
In Organic Peroxides; W. Ando, Ed.; John Wiley and Sons: Chischester 1992; pp 221-254

422
Adam, W.
Introductory Remarks
In Organic Peroxides; W. Ando, Ed.; John Wiley and Sons: Chichester 1992

423
Adam, W.; Asencio, G.; Curci, R.; Marco, J. A.; González Nuñez, M.E.; Mello, R.
One-Electron Transfer Chain Decomposition of Trifluoroacetone Diperoxide: The First 1,2,4,5-Tetroxane with Oxygen-Transfer Capability
Tetrahedron Lett., 1992, 33, 5833-5836

424
Adam, W.; Sauter, M.
Oxidation of 8-Methoxypsoralen (8-MOP) by Dimethyldioxirane. Evidence for the Formation of a Furocoumarin Epoxide by Methanol Trapping, a Potential Mutagenic Agent
Liebigs Ann. Chem., 1992, 1095-1096

425
Adam, W.; Schulte Oestrich R.
Two-Photon Chemistry in the Laser Jet: Photochemistry of the Diphenylhydroxymethyl Radical
Chem. Ber., 1992, 125, 2463-2466

426
Adam, W.; Schulz, M.H.
Base-Induced Chemiluminescence from Acetoxy-Substituted Benzofuran Dioxetanes through an Intramolecular Electron Transfer (CIEEL) Mechanism
Chem. Ber., 1992, 125, 2455-2461

427
Adam, W.; Heil, M.
Evidence for a 1,4-Dioxyl Diradical as an Intermediate in the Thermal Decomposition of 3,3-Dibenzyl-1,2-dioxetane
J. Am. Chem. Soc., 1992, 114, 8807-8809

428
Adam, W.; Finzel, R.; Schulte Oestrich, R.; Sendelbach, J.
UV Laser Photochemistry: Intersystem Crossing Phenomena and Photosensitized Transformation of Radical and Triplet Diradical Species
In Proceedings of the 8th Conference on Physical Organic Chemistry, Florianopolis (Brazil), Actualidades de Fisica Quimica Or 1992; 21-40

429
Adam, W.; Ahrweiler, M.; Paulini, K.; Reissig, H.-U.; Voerckel, V.
Dimethyldioxirane Oxidation of Enamines: First Spectral Evidence for Enamine Oxides by Stabilization through N-Silylation
Chem. Ber., 1992, 125, 2719-2721

430
Adam, W.; Albert, R.
Synthesis and Reactions of the Cyclic Silyl Peroxide 1,1,4,4-Tetramethyl-2,3-dioxa-1,4-disilacyclohexane
Tetrahedron Lett., 1992, 52, 8015-8016

431
Epe, B.; Müller, E.; Adam, W.; Saha-Möller, C.R.
Photochemical DNA Modifications Induced by 1,2-Dioxetanes
Chem.-Biol. Interactions, 1992, 85, 265-281

1993

432
Adam, W.; Qian, X.; Saha-Möller, C. R.
Synthesis and Photooxygenation of 2,3,6-Trimethylfuro[2,3-b][1]naphtho[4a,7a-e,f]pyrida-5,7-dione: A Potential Chemiluminescent Probe for Singlet Oxygen
Tetrahedron, 1993, 49, 417-422

433
Adam, W.; Nestler, B.
(Z)-3-Methyl-3-penten-2-ol as Stereochemical Probe for 1,2- versus 1,3-Allylic Strain in the Photooxygenation and Epoxidation of Chiral Allylic Alcohols
Tetrahedron Lett., 1993, 34, 611-614

434
Peters, K.; Peters, E.-M.; von Schnering, H.G.; Adam, W.; Hill, K.
Crystal Structure of (Z-8-Phenylmethylene-4,5-diazatricyclo-[4.3.0.03,7]non-4-ene
Z. Kristallogr., 1993, 203, 101-103

435
Adam, W.; Ahrweiler, M.; Sauter, M.
Photosensitized Oxygenation of an Acyl Furan: Isolation of the First Furan Dioxetane by Rearrangement of its Endoperoxide and Selected Chemical Transformations
Angew. Chem., 1993, 105, 104-105; Angew. Chem., Int. Ed. Engl., 1993, 32, 80-81

436
Adam, W.; Hadjiarapoglou, L.
Dioxiranes: Oxidation Chemistry Made Easy
Top. Curr. Chem., 1993, 164, 45-62

437
Adam, W.; Fell, R.T.; Schulz, M.H.
Synthesis and Fluoride Ion-Triggered Chemiluminescence (CIEEL Mechanism) of Siloxy-Substituted Benzofuran Dioxetanes
Tetrahedron, 1993, 49, 2227-2238

438
Adam, W.; Platsch, H.; Sendelbach, J.; Wirz, J.
Determination of the Triplet Lifetimes of 1,3-Cyclopentadiyl Biradicals Derived from the Photodenitrogenation of Azoalkanes with Time-Resolved Photoacoustic Calorimetry
J. Org. Chem., 1993, 58, 1477-1482

439
Adam, W.; Ganeshpure, P.A.
Oxidation of Arenes to para-Quinones with Hydrogen Peroxide Catalyzed by Hexafluoroacetone Hydrate
Synthesis, 1993, 280-282

440
Adam, W.; Ahrweiler, M.; Saha-Möller, C.R.; Sauter, M.; Schönberger, A.; Epe, B.; Müller, E.; Schiffmann, D.; Stopper, H.; Wild, D.
Genotoxicity Studies of Benzofuran Dioxetanes and Epoxides with Isolated DNA, Bacteria and Mammalian Cells
Toxicol. Lett., 1993, 67, 41-55

441
Banks, J.T.; Scaiano, J.C.; Adam, W.; Schulte Oestrich, R.
Thermal and Photochemical Fragmentation of a,a-Dialkoxybenzyl Radicals: A Comparison of the Thermal Reactions with Laser-Induced Fragmentations by Using Laser-Flash and Laser-Jet Photolyses
J. Am. Chem. Soc., 1993, 115, 2473-2477

442
Epe, B.; Henzel, H.; Adam, W.; Saha-Möller, C.R.
Endonuclease-Sensitive DNA Modifications Induced by Acetone and Acetophenone Photosensitization
Nucleic Acid Res., 1993, 21, 863-869

443
Adam, W.; Brünker, H.-G.
Diastereoselective and Regioselective Photooxygenation of a Chiral Allylic Amine and its Acyl Derivatives: Stereochemical Evidence for a Steering Effect by the Amino Group in the Ene Reaction of Singlet Oxygen
J. Am. Chem. Soc., 1993, 115, 3008-3009

444
Adam, W.; Ouchi, A.
Laser-Jet Photolysis of 1,8-Bis(substituted-methyl)naphthalenes: The Effect of Heteroatom Leaving Groups on the Two-Photon C-C Bond Formation
Chem. Commun., 1993, 628-629

445
Adam, W.: Schulte-Oestrich, R.
Two-Photon Cleavage of Benzil in the Laser-Jet: Intermolecular Reactions of Transient Benzoyl and tert-Butoxy Radicals in the Photolysis of tert-Butyl Peroxide Mixtures
J. Am. Chem. Soc., 1993, 115, 3455-3457

446
Adam, W.; Prein, M.
Diastereoselective [4+2] Cycloaddition of Singlet Oxygen in the Photooxygenation of Chiral Naphthyl Alcohols: Evidence for a Hydroxy Group-Directing Effect
J. Am. Chem. Soc., 1993, 115, 3766-3767

447
Adam, W.; Nestler, B.
Titanium-Catalyzed Epoxy-Hydroxylation of Allylic Alcohols: A Convenient Diastereoselective Synthesis of Epoxy Diols
Angew. Chem., 1993, 105, 767-769; Angew. Chem., Int. Ed. Engl., 1993, 32, 733-735

448
Adam, W.; Hadjiarapoglou, L.; Peters, K.; Sauter, M.
Epoxidation of 2-Methyl-3-phenylbenzofurans with Dimethyldioxirane: A Novel, Reversible Valence Isomerization between Labile Benzofuran Epoxides and Quinone Methides, their Rearrangement, Methanolysis and Cycloaddition Chemistry
Angew. Chem., 1993, 105, 769-770; Angew. Chem., Int. Ed. Engl., 1993, 32, 735-736

449
Adam, W.; Golsch, D.
SN2 Reaction versus Electron Transfer in the Oxygen Transfer by Dimethyldioxirane to Nitrogen Heteroarenes
Angew. Chem., 1993, 105, 770-773; Angew. Chem., Int. Ed. Engl., 1993, 32, 737-739

450
Adam, W.; Nava Salgado, V.O.; Peters, E.-M.; Peters, K.; von Schnering H.-G.
Synthesis of a,b-trans-Spiro-b-lactones by Diels-Alder of 1,3-Dienes to a-Methylene-b-lactone and their Decarboxylation by Pyrolysis to (E)-Alkylidenecycloalkenes, a Convenient Olefination Method
Chem. Ber., 1993, 126, 1481-1486

451
Adam, W.; Nava Salgado, V.O.; Wegener, B.; Winterfeldt E.
Diels-Alder Reaction of Racemic b-Isopropyl-a-methylene-b-lactone with Enantiomerically Pure 5,6,7,7a-Tetrahydro-7a-methyl-1-phenyl-4H-indene and Retro-Cleavage of the Resulting Spiro-b-lactones: The First Case of a Perfect Topological Resolution
Chem. Ber., 1993, 126, 1509-1510

452
Adam, W.; Nestler, B.
Hydroxy-Directed Regio- and Diastereoselective Ene Reaction of Singlet Oxygen with Chiral Allylic Alcohols
J. Am. Chem. Soc., 1993, 115, 5041-5049

453
Adam, W.; Klug, P.
Photooxygenation of Vinylstannanes: Tin-Substituted Allylic Hydroperoxides through the Regio- and Diastereoselective Ene Reaction with Singlet Oxygen
J. Org. Chem., 1993, 58, 3416-3420

454
Adam, W.; Qian, X.; Saha-Möller, C.R.
Synthesis and Photooxygenation of the 2H-4,8,9-Trimethylfuro[2',3':5,6]naphtho[1,2-b]pyran-2-one, an Unnatural Furocoumarin with a Benzene Spacer
J. Org. Chem., 1993, 58, 3769-3771

455
Patonay, T.; Tóth, G.; Adam, W.
A Convenient and General Synthesis of trans-3-Hydroxyflavones from Chalcones by Dimethyldioxirane Epoxidation and Subsequent Base-Catalyzed Cyclization
Tetrahedron Lett., 1993, 34, 5055-5058

456
Adam, W.; Nestler, B.
Direct Epoxy-Hydroxylation of Hydroperoxy Homoallylic Alcohols: Multidentate Oxygen-Donor and Oxygen-Acceptor Substrates in Ti(IV)-Catalyzed Epoxidations
J. Am. Chem. Soc., 1993, 115, 7226-7231

457
Asensio, G.; González Nuñez, M.E.; Boix Bernardini, C.; Mello, R.; Adam, W.
Regioselective Oxyfunctionalization of Unactivated Tertiary and Secondary C-H Bonds of Alkylamines by Methyl(trifluoromethyl)dioxirane in Acid Medium
J. Am. Chem. Soc., 1993, 115, 7250-7253

458
Adam, W.; Epe, B.; Mosandl, T.; Ramaiah, D.; Saha-Möller, C.R.; Wild, D.
Furocoumarin Dioxetanes and Hydroperoxides as Novel Photobiological DNA-Damaging Agents
Quimica Nova, 1993, 316-319

459
Adam, W.; Ahrweiler, M.; Sauter, M.; Schmiedeskamp, B.
Oxidation of Indoles by Singlet Oxygen and Dimethyldioxirane: Isolation of Indole Dioxetanes and Epoxides by Stabilization through Nitrogen Acylation
Tetrahedron Lett., 1993, 34, 5247-5250

460
Adam, W.; Fröhlich, L.; Nau, W.M.; Korth, H.-G.; Sustmann, R.
Substituent Effects on the Zero-Field Splitting Parameters of Localized Triplet 1,3-Cyclopentanediyl Biradicals
Angew. Chem., 1993, 105, 1383-1384; Angew. Chem., Int. Ed. Engl., 1993, 32, 1339-1340

461
Adam, W.; Finzel, R.; Walther, B.
On the Mechanism of the Benzophenone-Sensitized Photolysis of 2,3-Diazabicyclo[2.2.1]hept-2-ene in the Laser Jet: Evidence for Intermolecular Triplet Biradical Reactions
Chem. Ber., 1993, 126, 2137-2141

462
Adam, W.; Hadjiarapoglou, L.; Peters, K.; Sauter, M.
Dimethyldioxirane Epoxidation of Benzofurans: Reversible Thermal and Photochemical Valence Isomerization between Benzofuran Epoxides, Quinone Methides and Benzoxetenes
J. Am. Chem. Soc., 1993, 115, 8603-8608

463
Adam, W.; Sendelbach, J.
Photosensitized Electron Transfer from Azoalkanes: Generation, Fragmentation, and Rearrangement of Radical Cations Structurally Related to Dicyclopentadiene
J. Org. Chem., 1993, 58, 5310-5315

464
Adam, W.; Sendelbach, J.
Denitrogenation of Bicyclic Azoalkanes through Photosensitized Electron Transfer: Generation and Intramolecular Trapping of Radical Cations
J. Org. Chem., 1993, 58, 5316-5322

465
Adam, W.; Fröhlich, L.; Nau, W.M.; Wirz, J.
Effects of Symmetrical Diaryl Substitution on Intersystem Crossing in 1,3-Cyclopentanediyl Triplet Biradicals
J. Am. Chem. Soc., 1993, 115, 9824-9825

466
Adam, W.; Sauter, M.
Photochemical and Thermal Rearrangement of Acyl-Substituted Quinone Methides, Accessible by Dimethyldioxirane Oxidation of Benzofurans and Subsequent Valence Isomerization of the Resulting Epoxides
Chem. Ber., 1993, 126, 2697-2699

467
Epe, B.; Häring, M.; Ramaiah, D.; Stopper, H.; Abou-Elzahab, M.A.; Adam, W.; Saha-Möller, C.R.
DNA Damage Induced by Furocoumarin Hydroperoxides Plus UV (360 nm)
Carcinogenesis, 1993, 14, 2271-2276

468
Adam, W.; Hoch, U.; Saha-Möller, C.R.; Schreier, P.
Enzyme-Catalyzed Asymmetric Synthesis: Kinetic Resolution of Chiral Hydroperoxides by Enantioselective Reduction to Alcohols with Horseradish Peroxidase
Angew. Chem., 1993, 105, 1800-1801; Angew. Chem., Int. Ed. Engl., 1993, 32, 1737-1739

469
Adam, W.; Nau, W.M.; Sendelbach, J.; Wirz, J.
Identification of a Remarkably Long-Lived Azoalkane Triplet State
J. Am. Chem. Soc., 1993, 115, 12571-12572

470
Adam, W.; Richter, M.J.
On the Origin of Geminal Regioselectivity in the Ene Reaction of Singlet Oxygen with Substituted Alkenes
Tetrahedron Lett., 1993, 34, 8423-8426

471
Adam, W.; Prechtl, F.; Richter, M.J.; Smerz, A.K.
Oxidation of Allylic Alcohols by Dimethyldioxirane: Competition Reactions between Epoxidation and C-H Insertion
Tetrahedron Lett., 1993, 34, 8427-8430

1994

472
Adam, W.; Peters, K.; Sauter, M.
Dimethyldioxirane Epoxidation of 3-Phenyl-Substituted Benzofurans: A Reversible Valence Isomerization between Benzofuran Epoxides and Quinone Methides
Synthesis, 1994, 111-119

473
Adam, W.; Käb, G.; Sauter, M.
Thermal and Photochemical Rearrangement of 3-Substituted 2-Methylbenzofuran Epoxides and their Valence-Isomeric Quinone Methides
Chem. Ber., 1994, 127, 433-436

474
Adam, W.; Richter, M.J.
One-Pot Synthesis of a-Trimethylsilyl Enones from Vinylsilanes
Synthesis, 1994, 176-180

475
Adam, W.; Richter, M.J.
Metal-Catalyzed Direct Hydroxy-Epoxidation of Olefins
Acc. Chem. Res., 1994, 27, 57-62

476
Nemes, C.; Lévai, A.; Patonay, T.; Tóth, G.; Boros, S.; Halász, J.; Adam, W.; Golsch, D.
Dioxirane Oxidation of 3-Arylideneflavanones: Diastereoselective Formation of trans,trans-Spiroepoxides from the E Isomers
J. Org. Chem., 1994, 59, 900-905

477
Adam, W.; Gevert, O.; Klug, P.
Photooxygenation of g-Hydroxy Vinylstannanes and their Acyl Derivatives: Mechanistic Insight into the Hydroxy-Directing Effect
Tetrahedron Lett., 1994, 35, 1681-1684

478
Adam, W.; Treiber, A.
1,3-Dioxolane Formation by Nucleophilic Attack of Diazoalkanes on the Peroxide Bond of 1,2-Dioxetanes
J. Org. Chem., 1994, 59, 840-844

479
Adam, W.; Sahin, C.; Sendelbach, J.; Walter, H.; Chen, G.-F.; Williams, F.
Regioselective Rearrangement of Bridgehead-Methyl-Substituted Radical Cations Derived from Bicyclo[2.1.0]pentanes and 2,3-Diazabicyclo[2.2.1]hept-2-enes through Photoinduced Electron Transfer and Radiolytic Oxidation: Product Distribution and Matrix ESR Studies
J. Am. Chem. Soc., 1994, 116, 2576-2584

480
Adam, W.; Prechtl, F.
Enantioselective Oxidation of Chiral Titanium Enolates Derived from Propiophenone by Dimethyldioxirane or 3-Phenyl-2-phenylsulfonyloxaziridine
Chem. Ber., 1994, 127, 667-671

481
Adam, W.; Kita, F.
Photochemistry of the 9-Hydroxyxanthenyl Radical in the Laser Jet: Evidence for Photochemically Induced, Regioselective Radical Coupling
J. Am. Chem. Soc., 1994, 116, 3680-3683

482
Adam, W.; Ahrweiler, M.; Sauter, M.
Ring Cleavage of Benzofurans and Tetrahydrobenzofurans by m-Chloroperbenzoic Acid Epoxidation
Chem. Ber., 1994, 127, 941-946

483
Adam, W.; Peters, K.; Renz, M.
Tridentate b-Hydroperoxy Alcohols as Novel Oxygen Donors for the Titanium-Catalyzed Epoxidation of g,d-Unsaturated a,b -Diols: A Direct Diastereoselective Synthesis of Epoxy Diols
Angew. Chem., 1994, 106, 1159-1161; Angew. Chem., Int. Ed. Engl., 1994, 33, 1107-1108

484
Adam, W.; Miranda, M.A.; Mojarrad, F.; Sheikh, H.
Carbon-Carbon Bond Cleavage of the [2.2]Paracyclophane Radical Cation Generated by Electron Transfer Oxidation with Cerium(IV) Ammonium Nitrate
Chem. Ber., 1994, 127, 875-879

485
Adam, W.; Klug, P.
b-Stannyl Allylic Alcohols through Photooxygenation (Schenck Reaction) of Vinylstannanes and Reduction of the Resulting Allylic Hydroperoxides: Synthesis and Selected Transformations
J. Org. Chem., 1994, 59, 2695-2699

486
Adam, W.; Ahrweiler, M.; Peters, K.; Schmiedeskamp, B.
Oxidation of N-Acylindoles by Dimethyldioxirane and Singlet Oxygen: Substituent Effects on Thermally Persistent Indole Epoxides and Dioxetanes
J. Org. Chem., 1994, 59, 2733-2739

487
Adam, W.; Golsch, D.
Thianthrene 5-Oxide (SSO) as a Mechanistic Probe of the Electrophilic Character in the Oxygen Transfer by Dioxiranes
Chem. Ber., 1994, 127, 1111-1113

488
Adam, W.; Sauter, M.; Zünkler, C.
Preparation of 2H-Benzoxetes by Photoinduced [2+2] Cycloaddition of Quinone Methides, Accessible by Dimethyldioxirane (DMD) Oxidation of 2,3-Dimethylbenzofurans
Chem. Ber., 1994, 127, 1115-1118

489
Adam, W.; Prein, M.
Substituent Effects in the Diastereoselective [4+2] Cycloaddition of Chiral Naphthalene Derivatives with Singlet Oxygen
Tetrahedron Lett., 1994, 35, 4331-4334

490
Adam, W.; Kita, F.; Schulte-Oestrich, R.
Two-Photon Chemistry in the Laser Jet: Generation of Radical Intermediates and their Photochemical Transformations
J. Photochem. Photobiol., 1994, 80A, 187-197

491
Adam, W.; Klug, P.
(Z)-3-Alkylidene-4,5-dihydro-4-hydroxy-5-methyl-2-(3H)-furanones by Regio- and Diastereoselective Ene Reaction of Singlet Oxygen (Schenck Reaction) with g-Hydroxy Vinylstannanes: An Enantioselective Synthesis of Dihydromahubanolide B
Synthesis, 1994, 567-572

492
Adam, W.; Metz, M.; Prechtl, F.; Renz, M.
Facile Synthesis of a-Hydroxy Amides and Esters by Direct Autoxidation of their Titanium Enolates
Synthesis, 1994, 563-566

493
Adam, W.; Shimizu, M.
The Acid-Catalyzed Oxidation of Methoxybenzenes to p-Benzoquinones by Dimethyldioxirane
Synthesis, 1994, 560-562

494
Adam, W.; Klug, P.
A Convenient Stereoselective Synthesis of a-Tributylstannyl Enones by Photooxygenation of Vinylstannanes and Dehydration of the Resulting Hydroperoxides
Synthesis, 1994, 557-559

495
Adam, W.; Richter, M.J.
Regioselectivity of the Singlet Oxygen Ene Reaction (Schenck Reaction) with Vinylsilanes
J. Org. Chem., 1994, 59, 3335-3340

496
Adam, W.; Richter, M.J.
Highly Regio- and Diastereoselective One-Pot Synthesis of Silyl Epoxy Alcohols and Vinylsilanes by Direct Hydroxy-Epoxidation
J. Org. Chem., 1994, 59, 3341-3346

497
Adam, W.; Sauter, M.
Generation of 1,2-Dioxetane Decomposition Products in the Oxidation of 3-Phenyl-2-methylbenzofuran Epoxide by Dimethyldioxirane and the Oxodiperoxomolybdenum Complex
Tetrahedron, 1994, 50, 8393-8398

498
Adam, W.; Andler, S.
Thermolysis of 3,3-Bis(phenylmethyl)-1,2-dioxetane: Radical-Induced Formation of the Unusual Decomposition Product 3-Phenyl-1-(phenylmethoxy)-2-propanone
J. Am. Chem. Soc., 1994, 116, 5674-5678

499
Adam, W.; Reinhardt, D.
Indole Dioxetanes and Epoxides by Oxidation of N-Acylated Indoles with Singlet Oxygen and Dimethyldioxirane: Kinetics and Chemiluminescence Yields of the Thermal Dioxetane Decomposition and Fluoride-Ion-Induced CIEEL Emission
J. Chem. Soc., Perkin Trans. 2, 1994, 1503-1507

500
Adam, W.; Sauter, M.
Dioxirane Oxidation of Furocoumarins and Naphthofurans. Preparation of the Psoralen Epoxides
Liebigs Ann. Chem., 1994, 689-693

501
Adam, W.; Müller, M.; Prechtl, F.
Dimethyldioxirane Oxidation of Titanium Enolates: Diastereoselective a-Hydroxylations
J. Org. Chem., 1994, 59, 2358-2364

502
Adam, W.; Harrer, H.M.; Nau, W.M.; Peters, K.
Electronic Substituent Effects on the Acid-Catalyzed [4+2] Cycloaddition of Isopyrazoles with Cyclopentadiene and the Photochemical and Thermal Denitrogenation of the Resulting 1,4-Diaryl-7,7-dimethyl-2,3-diazabicyclo[2.2.1]hept-2-ene Azoalkanes to Bicyclo[2.1.0]pentanes
J. Org. Chem., 1994, 59, 3786-3797

503
Adam, W.; Balci, M.; Cakmak, O.; Peters, K.; Saha-Möller, C.R.; Schulz, M.H.
Photooxygenation of Tetramethoxybenzobarrelene: Synthesis and Thermal Decomposition of Bisdioxetane and Endoperoxide
Tetrahedron, 1994, 50, 9009-9024

504
Adam, W.; Hadjiarapoglou, L.; Mielke, K.; Treiber, A.
Competitive Epoxidation and Quinone Formation in the Dimethyldioxirane Oxidation of Diazoquinones as Ambident Nucleophiles
Tetrahedron Lett., 1994, 35, 5625-5628

505
Adam, W.; Ahrweiler, M.; Reinhardt, D.; Sauter, M.
Facile Triphenylphosphine Deoxygenation of Benzofuran Dioxetanes, their Epoxides and Valence Isomeric Quinone Methides
Tetrahedron Lett., 1994, 35, 6063-6066

506
Adam, W.; Nau, W.M.; Sendelbach, J.
Temperature Dependence on the a versus b Bond Cleavage in the Direct and Triplet-Sensitized Photolysis of Azoalkanes of the 2,3-Diazabicyclo[2.2.1]hept-2-ene Type
J. Am. Chem. Soc., 1994, 116, 7049-7054

507
Adam, W.; Ahrweiler, M.; Reinhardt, D.
Thermal and Bromide-Ion-Catalyzed Rearrangement of Benzofuran Dioxetanes to 1-Oxaspiro[2.5]-octa-5,7-dien-4-ones
J. Am. Chem. Soc., 1994, 116, 6713-6718

508
Adam, W.; Halász, J.; Lévai, A.; Nemes, C.; Patonay, T.; Tóth, G.
Dimethyldioxirane Oxidation of 3-Arylidenechromanones
Liebigs Ann. Chem., 1994, 795-803

509
Schenk, W.A.; Frisch, J.; Adam, W.; Prechtl, F.
Oxidation of Metal-Coordinated Thioethers with Dimethyldioxirane - A New Stereoselective Synthesis of Chiral Sulfoxides
Angew. Chem., 1994, 106, 1699-1701; Angew. Chem., Int. Ed. Engl., 1994, 33, 1609-1611

510
Adam, W.; Klug, P.
Regio- and Diastereoselective Synthesis of Stannyl Epoxy Alcohols by Direct Hydroxy-Epoxidation of Vinylstannanes
Chem. Ber., 1994, 127, 1441-1445

511
Ouchi, A.; Yabe, A.; Adam, W.
Highly Efficient C-C Bond Formation in the Two-Photon Chemistry of 1,8-Bis(substituted-methyl)Naphthalenes by Direct Excitation of Photoactive Leaving Groups
Tetrahedron Lett., 1994, 35, 6309-6312

512
Adam, W.; Harrer, H.M.; Treiber, A.
Synthesis of 1,4-Dioxa-2l5-phosphorinanes by Insertion of Triphenylalkylidenephosphoranes into the Peroxide Bond of 1,2-Dioxetanes: Thermolysis, Hydrolysis and Wittig Olefination
J. Am. Chem. Soc., 1994, 116, 7581-7587

513
Adam, W.; Nestler, B.
Die Regio- und Diastereoselektive En-Reaktion von 1O2 (Schenck-Reaktion) für die Präparative Organische Chemie
J. Inf. Rec., 1994, 21, 425-431

514
Adam, W.; Sauter, M.
Rearrangement of 2,3-Disubstituted Benzofuran Epoxides Prepared by Dimethyldioxirane Oxidation
Tetrahedron, 1994, 50, 11441-11446

515
Adam, W.; Mitchell, C.M.; Saha-Möller, C.R.
Chemoselective Methyltrioxorhenium(VII)-Catalyzed Sulfoxidations with Hydrogen Peroxide
Tetrahedron, 1994, 50, 13121-13124

516
Adam, W.; Golsch, D.; Hadjiarapoglou, L.; Lévai, A.; Nemes, C.; Patonay, T.
Dioxirane Oxidation of (Z)-1-Thioaurones, (E)-3-Arylidene-1-thiochroman-4-ones and (E)-3-Arylidene-1-thioflavan-4-ones
Tetrahedron, 1994, 50 , 13113-13120

517
Adam, W.; Saha-Möller, C.R.; Veit, M.; Welke, B.
A Convenient Synthesis of Hispidin from Piperonal
Synthesis, 1994, 1133-1134

518
Adam, W.; Sahin, C.
Tris(aryl)aminium Hexachloroantimonates: Convenient One-Electron Oxidants for Chemical Electron Transfer with Bicyclic Azoalkanes and Bicyclo[2.1.0]pentanes
Tetrahedron Lett., 1994, 35, 9027-9030

519
Adam, W.; Ammon, H.; Nau, W.M.; Peters, K.
4-Halo-4H-pyrazoles: Cycloaddition with Cyclopentadiene to Azoalkanes of the 2,3-Diazabicyclo[2.2.1]hept-2-ene Type versus Electrophilic Addition with Cyclopentene
J. Org. Chem., 1994, 59, 7067-7071

520
Nau, W.M.; Harrer, H.M.; Adam, W.
Radical Stabilization and Ground-State Polar Substituent Effects in the Thermal Decomposition of Azoalkanes
J. Am. Chem. Soc., 1994, 116, 10972-10982

521
Peters, K.; Peters, E.-M.; von Schering, H. G.; Adam, W.; Renz, M.
Crystal Structure of 2-Phenyl-1-(3-phenyloxiran-2-yl)-1,2-ethanediol, C16H16O3
Z. Kristallogr., 1994, 209, 989

522
Hoch, U.; Adam, W.; Saha-Möller, C.R.; Schreier, P.
Kinetische Racematspaltung chiraler Hydroperoxide mit Meerrettichperoxidase
Lebensmittelchemie, 1994, 48, 87-91

523
Adam, W.; Herrmann, W.A.; Lin, J.; Saha-Möller, C.R.; Fischer, W.; Correia, J.
Homogeneous Catalytic Oxidation of Arenes and a New Synthesis of Vitamin K3
Angew. Chem., 1994, 106, 2545-2546; Angew. Chem., Int. Ed. Engl., 1994, 33, 2475-2477

524
Adam, W.; Herrmann, W.A.; Lin, J.; Saha-Möller, C.R.
Catalytic Oxidation of Phenols to p-Quinones with the Hydrogen Peroxide and Methyltrioxorhenium(VII) System
J. Org. Chem., 1994, 59, 8281-8283

1995

525
Adam, W.; Cadet, J.; Dall'Acqua, F.; Epe, B.; Ramaiah, D.; Saha-Möller, C.R.
Photosensitized Formation of 8-Hydroxy-2'-desoxyguanosine in Salmon Testes DNA by Furocoumarin Hydroperoxides: A Novel, Intercalating Photo-Fenton Reagent for Oxidative DNA Damage
Angew. Chem., 1995, 107, 91-94; Angew. Chem., Int. Ed. Engl., 1995, 34, 107-110

526
Adam, W.; Schuhmann, R.M.
Synthesis of Epoxyferrocenes by the Oxidation of Acyl- and Allylsubstituted Ferrocenes with Dimethyldioxirane
J. Organomet. Chem., 1995, 487, 273-277

527
Adam, W.; Goller, K.; Kammel, T.; Peters, K.
Urazole-Bridged Bicyclic Azoalkanes: Generation, Nitroxyl Trapping and ESR Spectra of the Heterosubstituted 4,5-Diaza-1,3-cyclopentanediyl Diradicals through Direct and Benzophenone-Sensitized Photochemical Deazetation
J. Org. Chem., 1995, 60, 308-316

528
Peters, K.; Peters, E.-M.; von Schnering, H.G.; Adam, W.; Seguchi, K.
Crystal Structure of N-phenyl-7,8-benzo-5-(E)-methylmethylene-2,3-diazatricyclo-[4.4.0.04,9]non-2-enedicarboximide, C21H17N3O2
Z. Kristallogr., 1995, 210, 158-159

529
Peters, K.; Peters, E.-M.; von Schnering, H.G.; Adam, W.; Seguchi, K.
Crystal Structure of N-phenyl-2,3-diaza-5-(E)-carbomethoxymethylenetricyclo-[4.3.0.04,9]nonane-2,3dicarboximide, C18H17N3O4
Z. Kristallogr., 1995, 210, 160-161

530
Emmert, S.; Epe, B.; Saha-Möller, C.R.; Adam, W.; Rünger, T.M.
Assessment of Genotoxicity and Mutagenicity of 1,2-Dioxetanes in Human Cells Using a Plasmid Shuttle Vector
Photochem. Photobiol., 1995, 61, 136-141

531
Adam, W.; Sahin, C.; Schneider, M.
Mechanism of the Diastereoselective, Boron-Trifluoride-Catalyzed Cyclization of Olefinic Tosylhydrazones to Stereolabeled, Bridgehead-Substituted Azoalkanes
J. Am. Chem. Soc., 1995, 117, 1695-1702

532
Adam, W.; Nava Salgado, V.O.
Stereoselective Synthesis of a-Amino- and a-Thio-b-lactones by Conjugate Addition of Amine and Thiol Nucleophiles to a-Methylene- b-Lactones and their Decarboxylation to Allylamines and Sulfides
J. Org. Chem., 1995, 60, 578-584

533
Adam, W.; Ahrweiler, M.; Balci, M.; Cakmak, O.; Saha-Möller, C.R.
Rearrangement and Valence Isomerization in the Dimethyldioxirane Epoxidation of 2,3,5,6-Tetramethoxybenzobarrelene to Benzonorcaradiene endo-Ester
Tetrahedron Lett., 1995, 36, 1429-1430

534
Adam, W.; Herrmann, W.A.; Saha-Möller, C.R.; Shimizu, M.
Oxidation of Methoxybenzenes to p-Benzoquinones Catalyzed by Methyltrioxorhenium(VII)
J. Mol. Cat., 1995, 97A, 15-20

535
Höft, E.; Hamann, H.-J.; Kunath, A.; Adam, W.; Hoch, U.; Saha-Möller, C.R.; Schreier, P.
Enzyme-Catalyzed Kinetic Resolution of Racemic Secondary Hydroperoxides
Tetrahedron: Asymmetry, 1995, 6, 603-608

536
Adam, W.; Treiber, A.
Oxidation of Acetylated Guanosine by 3,3-Disubstituted 1,2-Dioxetanes through Nucleophilic Attack on the Peroxide Bond: Model Studies on the Oxidative DNA Damage by Reactive Peroxides
J. Am. Chem. Soc., 1995, 117, 2686-2693

537
Prein, M.; Maurer, M.; Peters, E.-M.; Peters, K.; von Schnering H. G.; Adam, W.
Diastereoselective Synthesis of 4-Hydroperoxy-3,5-cyclohexanediones in the Photooxygenation of Hydroxyethyl-Substituted Phenols
Chem. Eur. J., 1995, 1, 89-94

538
Brünker, H.-G.; Adam, W.
Diastereoselective and Regioselective Singlet-Oxygen Ene Oxyfunctionalization (Schenck Reaction): Photooxygenation of Allylic Amines and Their Acyl Derivatives
J. Am. Chem. Soc., 1995, 117, 3976-3982

539
Hoch, U.; Scheller, G.; Schmitt, M.; Schreier, P.; Adam, W.; Saha-Möller, C.R.
Enzymes in Synthetic Organic Chemistry: Selective Oxidoreductions Catalyzed by the Metalloenzymes
In Selective Reactions of Metal-Activated Molecules. J. Sundermeyer; H. Werner, Eds.; Vieweg Verlag: Braunschweig 1995; pp 33-38

540
Adam, W.; Brünker, H.-G.; Golsch, D.; Klug, P.; Lin, J.; Mitchell, C.M.; Prechtl, F.; Prein, M.; Renz, M.; Richter, M.; Saha-Möller, C.R. Schuhmann, R.M.; Shimizu, M.; Smerz, A.; Hoch, U.; Schrei
Selective Oxygen Transfer
In Selective Reactions of Metal-Activated Molecules. J. Sundermeyer; H. Werner, Eds.; Vieweg-Verlag: Braunschweig 1995; pp 39-44

541
Schulz, M.H.; Kluge, R.; Schüßler, M.; Adam, W.; Prechtl, F.
Stereoselective a-Hydroxylation of Ketones via Titanium Enolates by Using Organic Peroxides
In Selective Reactions of Metal-Activated Molecules. J. Sundermeyer; H. Werner, Eds.; Vieweg-Verlag: Braunschweig 1995; pp 45-48

542
Gernert, D.; Kiefer, W.; Kammel, T.; Nau, W.; Adam, W.
Matrix-Isolation Raman Spectroscopy and Semiempirical Calculations of 2,3-Diazabicyclo[2.2.1]hept-2-ene (DBH) and its Photoproduct Bicyclo[2.1.0]pentane (BCP)
J. Mol. Struct., 1995, 348, 333-336

543
Herrmann, W.A.; Galamba Correia, J.D.; Fischer, R.W.; Adam, W.; Lin, J.; Saha-Möller, C.R.; Shimizu, M.
Verfahren zur katalytischen Oxidation von aromatischen Verbindungen
(Hoechst AG), EP-A 95100901.8 1995

544
Adam, W.; Stössel, R.; Treiber, A.
The SN2 Reactivity of 3,3-Disubstituted 1,2-Dioxetanes with Morpholine
J. Org. Chem., 1995, 60, 2879-2884

545
Adam, W.; Jacob, U.; Prein, M.
Importance of Steric Effects in the [4+2] Cycloaddition of 5-Substituted Pentamethylcyclopentadienes
Chem. Commun., 1995, 839-840

546
Adam, W.; Fell, R.T.; Hoch, U.; Saha-Möller, C.R.; Schreier, P.
Kinetic Resolution of Chiral a-Hydroperoxy Esters by Horseradish-Peroxidase-Catalyzed Enantioselective Reduction to a-Hydroxy Esters
Tetrahedron: Asymmetry, 1995, 6, 1047-1050

547
Adam, W.; Jekó, J.; Lévai, A.; Nemes, C.; Patonay, T.; Sebok, P.
Enantioselective Epoxidation of 2,2-Dimethyl-2H-chromenes by Dimethyldioxirane and Jacobsen's Mn(III)salen Catalysts
Tetrahedron Lett., 1995, 36, 3669-3672

548
Nava-Salgado, V.O.; Peters, E.-M.; Peters, K.; von Schnering, H.G.; Adam, W.
The Diastereoselective Synthesis of Ester-Functionalized Alkenes through the Stereocontrolled Conjugate Addition (Michael Reaction) of Prochiral Enolates to Chiral a-Methylene-b-lactones and Thermal Decarboxylation of the Resulting a-Substituted b-Lactones
J. Org. Chem., 1995, 60, 3879-3886

549
Adam, W.; Cilento, G.
From Free Radicals to Electronically Excited Species
Free Rad. Biol. Med., 1995, 19, 103-114

550
Adam, W.; Peters, E.-M.; Peters, K.; Prein, M.; von Schnering, H.G.
Diastereoselective Photooxygenation of Chiral Naphthyl Alcohols: The Hydroxy Group-Directing Effect in the Singlet Oxygen [4+2] Cycloaddition to Arenes
J. Am. Chem. Soc., 1995, 117, 6686-6690

551
Peters, K.; Peters, E.-M.; von Schnering, H.G.; Adam, W.; Rosenthal, J.
Crystal Structure of N-Methyl-anti-7-Carboethoxy-2,3-diazabicyclo[2.2.1]hept-5-ene-2,3-carboximide, C12H15N3O4
Z. Kristallogr., 1995, 210, 545-546

552
Adam, W.; Griesbeck A.G.
Photooxidation of 1,3-Dienes
In CRC Handbook of Organic Chemistry and Photobiology; W.M. Horspool; P.-S. Song, Eds.; CRC Press Inc.: London 1995; pp 311-324

553
Adam, W.; Sahin, C.
Photochemical Decomposition of Cyclic Azoalkanes
In CRC Handbook of Organic Chemistry and Photobiology; W.M. Horspool, P.-S. Song, Eds.; CRC Press Inc.: London 1995; pp 937-953

554
Adam, W.; Prechtl, F.; Richter, M.J.; Smerz, A.K.
Epoxidation versus Allylic Oxidation (CH Insertion) in the Oxyfunctionalization of Vinylsilanes and b-Hydroxy Derivatives by Dimethyldioxirane
Tetrahedron Lett., 1995, 36, 4991-4994

555
Adam, W.; Sauter, M.
Oxyfunctionalization of Benzofurans by Singlet Oxygen, Dioxiranes, and Peracids: Chemical Model Studies for the DNA-Damaging Activity of Benzofuran Dioxetanes (Oxidation) and Epoxides (Alkylation)
Acc. Chem. Res., 1995, 28, 289-298

556
Adam, W.; Jekö, J.; Lévai, A.; Nemes, C.; Patonay, T.
Dimethyldioxirane Epoxidation of Chalcone and Isoflavone Glycoside Acetates
Liebigs Ann. Chem., 1995, 1547-1549

557
Trofimov, A.V.; Vasil'ev, R.F.; Mielke, K.; Adam, W.
Energy-Transfer-Enhanced Chemiluminescence of Adamantanone (n,p*) and Ester (p,p*) Singlet and Triplet Excited States in the Thermolysis of Silyloxyaryl-Substituted Spiroadamantyl Dioxetanes
Photochem. Photobiol., 1995, 62, 35-43

558
Bottle, S.E.; Bott, R.C.; Kennard, C.H.L.; Smith, G.; Adam, W.
Novel Sulfurated Five-, Seven- and Nine-membered Heterocycles: Unusual Products Derived from Potential Bisthionitroxide Precursors
Chem. Commun., 1995, 1449-1450

559
Adam, W.; Saha-Möller, C.R.; Schönberger, A.; Berger, M.; Cadet, J.
Formation of 7,8-Dihydro-8-oxoguanine in the 1,2-Dioxetane-Induced Oxidation of Calf Thymus DNA: Evidence for Photosensitized DNA Damage by Thermally Generated Triplet Ketones in the Dark
Photochem. Photobiol., 1995, 62, 231-238

560
Peters, K.; Peters, E.-M.; von Schnering, H.G.; Adam, W.; Rosenthal, R.J.
Crystal Structure of 6,7-Benzo-3,3-Dichloro-8-diphenylmethylenentricyclo[3.2.1.02.4]oct-4-ene, C25H18Cl2
Z. Kristallogr., 1995, 210, 613-614

561
Kita, F.; Nau, W.M.; Adam, W.; Wirz, J.
Effect of Donor-Acceptor Substitution on Intersystem-Crossing Rates of 1,3-Diaryl-1,3-cyclopentanediyl Triplet Biradicals
J. Am. Chem. Soc., 1995, 117, 8670-8671

562
Adam, W.; Gläser, J.; Peters, K.; Prein, M.
Highly like-Selective [4+2] Cycloadditions of Chiral Dienols: The Importance of 1,3-Allylic Strain in the Hydroxy-Directed Stereocontrol
J. Am. Chem. Soc., 1995, 117, 9190-9193

563
Malisch, W.; Hindahl, K.; Käb, H.; Reising, J.; Adam, W.; Prechtl, F.
Die ersten Hydroxysilandiylverbrückten Zweikernkomplexe: Selektive Oxygenierung der Silicium-Brücke in Silandiyleisen Komplexen mit Dimethyldioxiran
Chem. Ber., 1995, 128, 963-965

564
Adam, W.; Brünker, H.-G.
Diastereoselective Synthesis of Merucathin: The Singlet-Oxygen Ene Reaction (Schenck Reaction) as Key Step Towards an E-Configured b-Amino Allylic Alcohol
Synthesis, 1995, 1066-1067

565
Adam, W.; Heidenfelder, T.; Sahin, C.
Diastereo- and Regioselective Synthesis of Diquinanes and Related Systems from Tricyclo[3.3.0.02,4]octanes by Chemical Electron Transfer (CET)
Synthesis, 1995, 1163-1170

566
Adam, W.; Ballmaier, D.; Epe, B.; Grimm, G.N.; Saha-Möller, C.R.
N-Hydroxypyridinthiones as Photochemical Hydroxyl Radical Sources for Oxidative DNA Damage
Angew. Chem., 1995, 107, 2326-2328; Angew. Chem., Int. Ed. Engl., 1995, 34, 2156-2158

566
Adam, W.; Weinkötz, S.
Triphenylphosphine Reduction of Thiophene Endoperoxides: Nucleophilic Attack on Sulfur versus Biphilic Insertion into the Peroxide Bond
Tetrahedron Lett., 1995, 36, 7431-7432

568
Adam, W.; Ahrweiler, M.; Vlcek, P.
Chemiluminescence of the Labile 1,2-Dioxetanes and Epoxides Produced in the Oxidation of N-Acetylated Dihydro- and Tetrahydropyrazines by Singlet Oxygen, Dimethyldioxirane, and m-Chloroperoxybenzoic Acid
J. Am. Chem. Soc., 1995, 117, 9690-9692

569
Adam, W.; Heidenfelder, T.; Sahin, C.
Generation of Bicyclo[3.2.0]hept-6-ene-2,4-diyl Radical Cations by Chemical Electron Transfer (CET) with Trisarylaminium Salts and Intramolecular Cyclobutene Trapping as an Alternative Entry to the Quadricyclane-Norbornadiene Valence Isomers
J. Am. Chem. Soc., 1995, 117, 9693-9698

570
Adam, W.; Briviba, K.; Duschek, F.; Golsch, D.; Kiefer, W.; Sies, H.
Formation of Singlet Oxygen in the Deoxygenation of Heteroarene N-Oxides by Dimethyldioxirane
Chem. Commun., 1995, 1831-1832

571
Adam, W.; Kumar, A.S.; Saha-Möller, C.R.
Photooxygenation of Vinyl Sulfides: Substituent Effects on the [2+2] Cycloaddition versus Schenck Reaction Modes
Tetrahedron Lett., 1995, 36, 7853-7854

572
Adam, W.; Reinhardt, D.; Reissig, H.-U.; Paulini, K.
Epoxidation of Vinylamides by Dimethyldioxirane: First Spectral Evidence for Enamide Oxides
Tetrahedron, 1995, 51, 12257-12262

573
Adam, W.; Prein, M.
p-Facial Selectivity of the Singlet Oxygen [4+2] Cycloaddition to Chiral Naphthalene Derivatives: The Directing Effect of Carbon-Containing Substituents
Tetrahedron, 1995, 51, 12583-12590

574
Adam, W.; Smerz, A.K.
Solvent Effects in the Dimethyldioxirane Oxidation of Allylic Alcohols: Evidence for Hydrogen Bonding in the Dipolar Transition State of Oxygen Transfer
Tetrahedron, 1995, 51, 13039-13044

575
Möller, M.; Stopper, H.; Häring, M.; Schleger, Y.; Epe, B.; Adam, W.; Saha-Möller, C.R.
Genotoxicity Induced by Furocoumarin Hydroperoxides in Mammalian Cells upon UVA Irradiation
Biochem. Biophys. Res. Commun., 1995, 216, 693-701

576
Malisch, W.; Neumayer, M.; Fey, O.; Adam, W.; Schuhmann, R.M.
Synthese des diastereomerenreinen Ferriosilanols (RS,SR)-Cp (OC) (Ph3P)Fe-Si(Me)(Ph)(OH) und Struktur von (RR,SS)-Cp(OC)(Ph3P)Fe-Si(Me)(Ph)Cl
Chem. Ber., 1995, 128, 1257-1260

577
Malisch, W.; Schmitzer, S.; Lankat, R.; Neumayer, M.; Prechtl, F.; Adam, W.
Metallosilanole vom Typ C5R5(OC)2(Me3P)M-SiPh2OH (M=Cr, Mo, W): Darstellung nach der Dimethyldioxiranmethode und Überführung in funktionalisierte Metallodisiloxane
Chem. Ber., 1995, 128, 1251-1255

578
Adam, W.; Patterson, W.
High-Intensity Laser-Jet Photochemistry: Formation of Benzocyclobutenedione from 1,2,3-Indanetrione via Transient Targeting
J. Org. Chem., 1995, 60, 7769-7773

579
Adam, W.; Hoch, U.; Lazarus, M.; Saha-Möller, C.R.; Schreier, P.
Enzyme-Catalyzed Asymmetric Synthesis: Kinetic Resolution of Racemic Hydroperoxides by Enantioselective Reduction to Alcohols with Horseradish Peroxidase
J. Am. Chem. Soc., 1995, 117, 11898-11901

580
Adam, W.; Fragale, G.; Klapstein, D.; Nau, W.M.; Wirz, J.
Phosphorescence and Transient Absorption of Azoalkane Triplet States
J. Am. Chem. Soc., 1995, 117, 12578-12592

581
Adam, W.; Griesbeck, A.G.
Formation of C-O Bonds by Allylic Oxidation with Singlet Molecular Oxygen
In Methods of Organic Chemistry (Houben Weyl), Stereoselective Synthesis; G. Helmchen, R.W. Hoffmann, J. Mulzer, E. Schauman, 1995; Vol. 21e, pp 4928-4946

582
Adam, W.; Kumar, A.S.; Saha-Möller, C.R.
Synthesis of a-Methylene-b-hydroperoxy Sulfoxides by Regioselective Photooxygenation (Schenck Reaction) of Racemic Vinyl Sulfoxides
Synthesis, 1995, 1525-1528

583
Adam, W.; Ganeshpure, P.A.
Bis(trimethylsilyl) Monoperoxysulfate (CH3)3SiOSO2OOSi(CH3)3
In Encyclopedia of Reagents for Organic Synthesis; L.A. Paquette, Ed.; John Wiley and Sons: Chichester 1995; Vol. 1, pp 599-600

584
Adam, W.; Saha-Möller, C.R.
Interdisciplinary Research as a Key to Chemical Education in the Future
In Chemistry: The Key to the Future, Proceedings of the 13th International Conference on Chemical Education; P.J. Towse, Ed.; 1995; pp 69-77

585
Lévai, A.; Adam, W.; Halász, J.; Nemes, C.; Patonay, T.; Tóth, G.
Dioxirane Oxidation of Benzopyranes, Benzothiopyrans and Related Compounds
Chem. Heterocycl. Comp.(USSR)(Engl.Tr.), 1995, 10, 1345-1349

586
Adam, W.; Fell, R.T.; Hoch, U.; Saha-Moeller, C.R.; Schreier, P.
Kinetic Resolution of Chiral Hydroperoxides with Horseradish Peroxidase
In Book of Abstracts, 210th ACS National Meeting, Chicago; American Chemical Society: Washington, D. C., 1995; Abstract ORGN-057

587
Andler, S.; Adam, W.; Saha-Moeller, C.R.
Inhibition of Photosensitized Oxidative DNA Damage by Ethyl Oleate Hydroperoxide and Alcohol
In Book of Abstracts, 210th ACS National Meeting, Chicago; American Chemical Society: Washington, D. C., 1995; Abstract ORGN-378

1996

588
Adam, W.; Prein, M.; Richter M.J.
Stereochemically Defined Cyclohexanediols through the Regioselective Ring-Opening of Silylated Epoxy Alcohols
Tetrahedron, 1996, 52, 1231-1234

589
Adam, W.; van Barneveld, C.; Golsch, D.
Direct Synthesis of 3-Aryl-1,2,4,5-tetrazine N-1-Oxides by the Oxidation with Methyl(trifluoromethyl)-dioxirane
Tetrahedron, 1996, 52, 2377-2384

590
Adam, W.; Weinkötz, S.
Synthesis of Thiiranes through Direct Sulfur Transfer to Cycloalkanes in the Thermolysis of a Thiophene Endoperoxide
Chem. Commun., 1996, 177-178

591
Adam, W.; Schuhmann, R.M.
Iron Tricarbonyl Complexes in Oxidation Chemistry: Regio- and Stereoselective Oxyfunctionalization of Trienes by Singlet Oxygen and Dimethyldioxirane
J. Org. Chem., 1996, 61, 874-878

592
Prein, M.; Adam, W.
The Schenck Ene Reaction: Diastereoselective Oxyfunctionalization with Singlet Oxygen in Synthetic Applications
Angew. Chem., 1996, 108, 519-538; Angew. Chem., Int. Ed. Engl., 1996, 35, 477-494

593
Adam, W.; Mitchell, C.M.
Methyltrioxorhenium (VII)-Catalyzed Epoxidation of Alkenes with the Urea/Hydrogen Peroxide Adduct
Angew. Chem., 1996, 108, 578-581; Angew. Chem., Int. Ed. Engl., 1996, 35, 533-535

594
Adam, W.; Kammel, T.; Steenken, S.
Generation of a Heterocyclic 1,3-Cyclopentanediyl Radical Cation Derived from the Corresponding Housane by Chemically Induced Electron Transfer Oxidation and Pulse Radiolysis
Angew. Chem., 1996, 108, 582-584; Angew. Chem., Int. Ed. Engl., 1996, 35, 543-545

595
Adam, W.; Brünker, H.-G.; Sampath Kumar, A.; Peters, E.-M.; Peters, K.; Schneider, U.; von Schnering, H.G.
Diastereoselective Singlet-Oxygen Ene Reaction (Schenck Reaction) and Diastereoselective Epoxidation of Heteroatom-Substituted Acyclic Chiral Olefins: A Mechanistic Comparison
J. Am. Chem. Soc., 1996, 118, 1899-1905

596
Adam, W.; Halász, J.; Jámbor, Z.; Lévai, A.; Nemes, C.; Patonay, T.; Tóth, G.
Synthesis and Stereochemistry of the Epoxides of 2-Arylmethylidene-1-tetralones
J. Chem. Soc., Perkin Trans. 1, 1996, 4, 395-400

597
Adam, W.; Golsch, D.; Görth, F.C.
Thianthrene 5-Oxide as a Mechanistic Probe in Oxygen Transfer Reactions: The Case of Carbonyl Oxides versus Dioxiranes Revisited
Chem. Eur. J., 1996, 2, 255-258

598
Malisch, W.; Hindahl, K.; Grün, K.; Adam, W.; Prechtl, F.; Sheldrick, W.S.
Synthese und Reaktivität von Übergangsmetall-substituierten Phosphanen, Arsanen und Stibanen LVII. Oxidation tertiärer und sekundärer Metallphosphane von Eisen und Wolfram mit Dimethyldioxiran
J. Organomet. Chem., 1996, 509, 209-214

599
Ganeshpure, P.A.; Adam, W.
a-Hydroxy Hydroperoxides (Perhydrates) as Oxygen Transfer Agents in Organic Synthesis
Synthesis, 1996, 179-188

600
Adam, W.; Bottle, S.E.; Grice, I.D.; Pfeiler, D.; Wentrup, C.
The Cheletropic Trapping of Nitric Oxide by the bis-Ketene 1,2-Dicarbonylcyclohexa-3,5-diene and the Diene 3,4-Diphenyl-2,5-dimethyl-2,4-hexadiene
Tetrahedron Lett., 1996, 37, 2113-2116

601
Nau, W.M.; Adam, W.; Scaiano, J.C.
Singlet-Oxygen Production from Excited Azoalkanes
J. Am. Chem. Soc., 1996, 118, 2742-2743

602
Adam, W.; Corma, A.; Miranda, M.A.; Sabater-Picot, M.-J.; Sahin, C.
Photochemical (PET) and Chemical (CET) Electron Transfer of Bicyclopentanes (Housanes) in Solution and inside Zeolite Cavities
J. Am. Chem. Soc., 1996, 118, 2380-2386

603
Patonay, T.; Adam, W.; Halász, J.; Lévai, A.; Nemes, C.; Tóth, G.
Oxidations of Benzopyrans, Benzofurans and Related Compounds: One Step Ahead
In Flavonoids and Bioflavonoids. Proceedings of the International Bioflavonoid Symposium, Vienna, Austria; S. Antus, M. Gabor 1996; pp 329-333

604
Lévai, A.; Adam, W.; Jekö, J.; Nemes, C.; Patonay, T.
Dimethyldioxirane Epoxidation of Chalcone and Isoflavone Glycoside Acetates
In Flavonoids and Bioflavonoids. Proceedings of the International Bioflavonoid Symposium, Vienna, Austria; S. Antus, M. Gabor 1996; pp 167-176

605
Adam, W.; Schuhmann, R.M.
Selective Oxyfunctionalization of (Tricarbonylcyclohexadiene)iron-Substituted Furans with Singlet Oxygen and Dimethyldioxirane
Liebigs Ann. Chem., 1996, 635-640

606
Adam, W.; Korb, M.
Diastereoselective Oxidation of Lithium and Chlorotitanocene Enolates Derived from Camphor
Tetrahedron, 1996, 52, 5487-5494

607
Adam, W.; Smerz, A.K.
Nickel-Catalyzed Hydroxylation of 1,3-Dicarbonyl Compounds by Dimethyldioxirane
Tetrahedron, 1996, 52, 5799-5804

608
Adam, W.; Kumar, R.; Reddy, T.I.; Renz, M.
Chemo- and Diastereoselective Epoxidation of Chiral Allylic Alcohols with the Urea/Hydrogen-Peroxide (UHP) Adduct, Catalyzed by Titanium Silicate 1
Angew. Chem., 1996, 108, 944-947; Angew. Chem., Int. Ed. Engl., 1996, 35, 880-882

609
Briviba, K.; Saha-Möller, C.R.; Adam, W.; Sies, H.
Formation of Singlet Oxygen in the Thermal Decomposition of 3-Hydroxymethyl-3,4,4-trimethyl-1,2-dioxetane, A Chemical Source of Triplet-Excited Ketones
Biochem. Mol. Biol. Int., 1996, 38, 647-651

610
Adam, W.; van Barneveld, C.; Bottle, S.E.; Engert, H.; Hanson, G.R.; Harrer, H.M.; Heim, C.; Nau, W.M.; Wang, D.
EPR Characterization of the Quintet State for a Hydrocarbon Tetraradical with Two Localized 1,3-Cyclopentanediyl Biradicals Linked by meta-Phenylene as Ferromagnetic Coupler
J. Am. Chem. Soc., 1996, 118, 3974-3975

611
Trofimov, A.V.; Mielke, K.; Vasil'ev, R.F.; Adam, W.
Chemically Initiated Electron- Exchange Luminescence of Silyloxyaryl-Substituted Spiroadamantyl Dioxetanes. Kinetics and Excited-State Yields
Photochem. Photobiol., 1996, 63, 463-467

612
Adam, W.; Kammel, T.
Generation of 4,5-Diazacyclopentane-1,3-diyl Radical Cations by Chemical Electron-Transfer (CET) Oxidation of Urazole-Bridged Bicyclic Housanes (Bicyclo[2.1.0]pentanes) and their Chemical Transformations
J. Org. Chem., 1996, 61, 3172-3176

613
Epe, B.; Ballmaier, D.; Adam, W.; Grimm, G.N.; Saha-Möller, C.R.
Photolysis of N-Hydroxypyridinethiones a New Source of Hydroxyl Radicals for the Direct Damage of Cell-free and Cellular DNA
Nucleic Acid Res., 1996, 9, 1625-1631

614
Adam, W.; Prein, M.
The p-Facial Diastereoselectivity in the [4+2] Cycloaddition of Singlet Oxygen as Mechanistic Probe
Acc. Chem. Res., 1996, 29, 275-283

615
Adam, W.; Smerz, A.K.
Solvent Effects in the Regio- and Diastereoselective Epoxidations of Acyclic Allylic Alcohols by Dimethyldioxirane: Hydrogen Bonding as Evidence for a Dipolar Transition State
J. Org. Chem., 1996, 61, 3506-3510

616
Adam, W.; Blancafort, L.
Steric and Stereoselective Control of the Mode Selectivity as a Function of Alkene Structure in the Reaction with Dimethyl a-Peroxy Lactone: Cycloadducts and Ene Products versus Epoxides
J. Am. Chem. Soc., 1996, 118, 4778-4787

617
Peters, K.; Peters, E.-M.; Adam, W.; Walter, H.; Sahin, C.
Crystal Structure of the anti-10-Methyl-4-methyl-2,4,6-triazatricyclo[5.2.102,6]dex-8-en-3,5-dione
Z. Kristallogr., 1996, 211, 433-434

618
Adam, W.; Berger, M.; Cadet, J.; Dall'Acqua, F.; Epe, B.; Frank, S.; Ramaiah, D.; Raoul, S.; Saha-Möller, C.R.; Vedaldi, D.
Photochemistry and Photobiology of Furocoumarin Hydroperoxides Derived from Imperatorin: Novel Intercalating Photo-Fenton Reagents for Oxidative DNA Modification by Hydroxyl Radicals
Photochem. Photobiol., 1996, 63, 768-778

619
Nau, W.M.; Adam, W.; Scaiano, J.C.
Fluorescence Quenching of Azoalkanes by Solvent-Assisted Radiationless Deactivation Involving CH Bonds
Chem. Phys. Lett., 1996, 253, 92-96

620
Adam, W.; Walther, B.
Multiple-Photon Chemistry in the Benzophenone Photoreduction during Laser-Jet Photolysis: Effect of Alcohol Solvent on Cross-Coupling versus Hydrogen Abstraction of the Electronically Excited Hydroxydiphenylmethyl Radical
Tetrahedron, 1996, 52, 10399-10404

621
Adam, W.; Halász, J.; Jámbor, Z.; Lévai, A.; Nemes, C.; Patonay, T.; Tóth, G.
Stereoselective Epoxidation of 2-Arylidene-1-indanones and 2-Arylidene-1-benzosuberones
Monatshefte, 1996, 127, 683-690

622
Adam, W.; Andler, S.; Saha-Möller, C.R.; Schönberger, A.
Inhibitory Effect of Ethyl Oleate Hydroperoxide and Alcohol in Photosensitized Oxidative DNA Damage
J. Photochem. Photobiol., 1996, 34B, 51-58

623
Patonay, T.; Lévai, A.; Nemes, C.; Timár, T.; Tóth, G.; Adam, W.
Synthesis and Cyclization of 1-(2-Hydroxyphenyl)-2-propene-1-one Epoxides: 3-Hydroxy-chromanones and -flavones versus 2-(1-Hydroxyalkyl)-3-coumaranones
J. Org. Chem., 1996, 61, 5375-5383

624
Voigt, B.; Porzel, A.; Golsch, D.; Adam, W.; Adam, G.
Regioselective Oxyfunctionalization of Brassinosteroids by Methyl(trifluoromethyl)dioxirane: Synthesis of 25-Hydroxybrassinolide and 25-Hydroxy-24-epibrassinolide by Direct CH Insertion
Tetrahedron Lett., 1996, 52, 10653-10658

625
Adam, W.; Diáz, M.T.; Fell, R.T.; Saha-Möller, C.R.
Kinetic Resolution of Racemic a-Hydroxy Ketones by Lipase-Catalyzed Irreversible Transesterification
Tetrahedron: Asymmetry, 1996, 7, 2207-2210

626
Adam, W.; Lazarus, M.; Saha-Möller, C.R., Schreier, P.
Enantioselective a Hydroxylation of Carboxylic Acids with Molecular Oxygen Catalyzed by the a-Oxidation Enzyme System of Young Pea Leaves (Pisum Sativum): A Substrate Selectivity Study
Tetrahedron: Asymmetry, 1996, 7, 2287-2292

627
Adam, W.; Fell, R.T.; Mock-Knoblauch, C.; Saha-Möller, C.R.
Synthesis of Optically Active a-Hydroxycarbonyl Compounds by (Salen)Mn(III)-Catalyzed Oxidation of Silyl Enol Ethers and Silyl Ketene Acetals
Tetrahedron Lett., 1996, 37, 6531-6534

628
Adam, W.; Jekö, J.; Lévai, A.; Majer, Z.; Nemes, C.; Patonay, T.; Párkányi, L.; Sebök, P.
Determination of the Absolute Configuration of Optically Active 2,2-Dimethyl-3,4-epoxychromans Prepared by the Catalytic Enantioselective Epoxidation with the Dimethyldioxirane/Jacobsen Mn(II)salen System
Tetrahedron: Asymmetry, 1996, 7, 2437-2446

629
Adam, W.; Golsch, D.; Sundermeyer, J.; Wahl, G.
Activation of Bis(trimethylsilyl) Peroxide and tert-Butyl Hydroperoxide with Oxo and Peroxo Complexes of Vanadium, Molybdenum and Tungsten for the Sulfoxidation of Thianthrene 5-Oxide
Chem. Ber., 1996, 129, 1177-1182

630
Adam, W.; Smerz, A.K.
Chemistry of Dioxiranes: Selective Oxidations
Bull. Soc. Chim. Belg., 1996, 105, 581-599

631
Adam, W.; Harrer, H.M.; Kita, F.; Nau, W.M.; Zipf, W.
The D Parameter (EPR Zero-Field Splitting) of Localized 1,3-Cyclopentanediyl Triplet Diradicals as a Measure of Electronic Substituent Effects on the Spin Densities in para-Substituted Benzyl-Type Radicals
J. Org. Chem., 1996, 61, 7056-7065

632
Adam, W.; Harrer, H.M.; Heidenfelder, T.; Kammel, T.; Kita, F.; Nau, W.M.; Sahin, C.
The D Parameter ( Zero-Field Splitting) as a Direct Measure of Structural and Electronic Effects in Localized 1,3-Diradicals
J. Chem. Soc., Perkin Trans. 2, 1996, 2085-2089

633
Adam, W.; Saha-Möller, C.R.; Schönberger, A.
Photooxidation of 8-Oxo-7,8-dihydro-2'-deoxyguanosine by Thermally Generated Triplet-Excited Ketones from 3-(Hydroxymethyl)-3,4,4-trimethyl-1,2-dioxetane and Comparison with Type I and Type II Photosensitizers
J. Am. Chem. Soc., 1996, 118, 9233-9238

634
Adam, W.; Bronstein, I.; Brooks, E.; Engel, T.; Reinhardt, D.; Schneider, F.W.; Trofimov, A.V.; Vasil`ev, R.F.
Electron-Exchange Luminescence of Spiroadamantane-Substituted Dioxetanes Triggered by Alkaline Phosphatase. Kinetics and Elucidation of pH Effects
J. Am. Chem. Soc., 1996, 118, 10400-10407

635
Adam, W.; Corma, A.; Martinez, A.; Renz, M.
The Mechanism of the Double-Bond Cleavage in the Titanium-Zeolite-Catalyzed Oxidation of a-Methylstyrene by Hydrogen Peroxide: The b-Hydroperoxy Alcohol as Intermediate
Chem. Ber., 1996, 129, 1453-1455

636
Adam, W.; Reinhardt, D.; Saha-Möller, C.R.
From the Firefly Bioluminescence to the Dioxetane-Based (AMPPD) Chemiluminescence Immunoassay: A Retroanalysis
Analyst, 1996, 121, 1527-1531

637
Adam, W.; Blancafort, L.
Stereoselective Cycloaddition and Epoxidation of Enol Ethers by a-Peroxy Lactone as a Function of Steric and Stereoelectronic Effects
J. Org. Chem., 1996, 61, 8432-8438

638
Adam, W.; Moorthy, J.N.; Nau, W.M.; Scaiano, J.C.
Photoreduction of Azoalkane Triplet States by Hydrogen Atom and Charge Transfer
J. Org. Chem., 1996, 61, 8722-8723

639
Murphy, S.; Adam, W.
The Elusive 1,4-Dioxy Biradical: Revised Mechanism for the Formation of Diol from 3,3-Dimethyldioxetane in Cyclohexadiene
J. Am. Chem. Soc., 1996, 12916-12921

640
Adam, W.; Putterlik, J.; Schuhmann, R.M.; Sundermeyer, J.
Synthesis of Tris(pyrazolyl)borate-Stabilized Vinyl, Allyl and Homoallyl Tungsten Oxides and Their Selective Oxyfunctionalization by Singlet Oxygen and Dioxirane
Organometallics, 1996, 15, 4586-4596

641
Heindl, D.; Josel, H.-P.; von der Eltz, H.; Herrmann, R.; Höltke, H.-J.; Beckert, R.; Weiss, D.; Adam, W.
Heterocyclische Dioxetan-Substrate, Verfahren zur Herstellung und Verwendung
Patent DE 19538708.2 1996

642
Adam, W.; Hoch, U.; Humpf, H.-U.; Saha-Möller, C.R., Schreier, P.
Horseradish- Peroxidase(HRP)-Catalyzed Enantioselective Reduction of Racemic Hydroperoxy Homoallylic Alcohols: A Novel Enzymatic Method for the Preparation of Optically Active, Unsaturated Diols and Hydroperoxy Alcohols
Chem. Commun., 1996, 2701-2702

643
Saha-Möller, C.R.; Adam, W.
Four-Membered Rings with Two Oxygen Atoms: Dioxetanes
In Comprehensive Heterocyclic Chemistry, 2nd Ed. (CHEC-2), A. R. Katritzky, C. W. Rees, E. F. V. Scriven, Eds. in Chief; 3- a 1996; Chap. 1.33, pp 1041-1082

644
Reddy, T.I.; Adam, W.; Renz, M.
Diastereoselective Epoxidation of Allylic Alcohols with Hydrogen Peroxide Catalyzed by Titanium Silicate (TS-1 or Ti-beta)
In Book of Abstracts, 211th ACS National Meeting, New Orleans; American Chemical Society: Washington, D. C., 1996; Abstract ORGN-160

1997

645
Adam, W.; Andler, S.; Ballmeier, D.; Emmert, S.; Epe, B.; Grimm, G.N.; Mielke, K.; Möller, M.; Rünger, T.M.; Saha-Möller, C R.; Schönberger, A.
Oxidative DNA Damage Induced by Dioxetanes, Photosensitizing Ketones, and Photo-Fenton Reagents
In Recent Results in Cancer Research; H.K. Müller-Hermelink, H.G. Neumann, W. Dekant, Eds.; Springer Verlag: Berlin, Heidelbe 1997; Vol. 143, pp 21-34

646
Adam, W.; Curci, R.; D'Accolti, L.; Dinoi, A.; Fusco, C.; Gasparrini, F.; Kluge, R.; Paredes, R.; Schulz, M.; Smerz, A.K.; Veloza, L.A.; Weinkötz, S.; Winde, R.
Epoxidation and Oxygen Insertion into Alkane CH Bonds by Dioxirane Do Not Involve Detectable Radical Pathways
Chem. Eur. J., 1997, 3, 105-109

647
Adam, W.; Golsch, D.
Probing for Electronic and Steric Effects in the Peracid Oxidation of Thianthrene 5-Oxide
J. Org. Chem., 1997, 62, 115-119

648
Schulz, M.; Liebsch, S.; Kluge, R.; Adam, W.
Organo Sulfonic Peracids, 41: The Reaction of Arenesulfonylimidazoles with H2O2 in the Presence of Ketones - A New Entry to Dioxetanes
J. Org. Chem., 1997, 62, 188-193

649
Ouchi, A.; Koga, Y.; Adam, W.
Two-Photon Laser-Induced Reaction of 1,8-Bis(halomethyl)naphthalenes from Different Excited States and Transient Targeting of Its Intermediate by Time-Delayed, Two-Color Photolysis and Argon Ion Laser-Jet Technique
J. Am. Chem. Soc., 1997, 119, 592-599

650
Adam, W.; Saha-Möller, C.R.; Schönberger, A.
Type I and Type II Photosensitized Oxidative Modification of 2'-Deoxyguanosine (dGuo) by Triplet-Excited Ketones Generated Thermally from the 1,2-Dioxetane HTMD
J. Am. Chem. Soc., 1997, 119, 719-723

651
Adam, W.; Harrer, H.M.; Kita, F.; Nau, W.M.
Localized Triplet Diradicals as Probe for Electronic Substituent Effects in Benzyl-Type Radicals: The D Scale
Pure & Appl. Chem., 1997, 69, 91-96

652
Adam, W.; Schneider, K.
Multiple-Photon Chemistry in the Laser-Jet: Photochemistry of the 4-Biphenylmethyl Radical
J. Chem. Soc., Perkin Trans. 2, 1997, 2, 441-444

653
Adam, W.; Harrer, H.M.; Kita, F.; Korth, H.-G.; Nau, W.M.
Electronic Effects of para and meta Substituents on the EPR D Parameter in 1,3-Arylcylopentane-1,3-diyl Triplet Diradicals. A New Spectroscopic Measure of a Spin Densities and Radical Stabilization Energies in Benzyl-Type Monoradicals
J. Org. Chem., 1997, 62, 1419-11426

654
Kyagova, A.A.; Zhuravel, N.N.; Malakhov, M.V.; Lysenko, E.P.; Adam, W.; Saha-Möller, C.R.; Potapenko, A.Y.
Suppression of Delayed Type Hypersensitivity and Hemolysis Induced by Previously Photooxidized Psoralen: Effect of Fluence Rate and Psoralen Concentration
Photochem. Photobiol., 1997, 65, 694-700

655
Adam, W.; Paredes, R.; Smerz, A.K.; Veloza, L.A.
Probing for Steric and Electronic Effects in Diastereoselective Dioxirane Epoxidations Compared to the Oxygen Transfer by Peroxy Acids
Liebigs Ann. Chem., 1997, 547-551

656
Adam, W.; Lévai, A.; Mérour, J.-Y.; Nemes, C.; Patonay, T.
Dioxirane Oxidation of 2-Arylidene-2,3-dihydro-1H-indol-3-ones. Diastereoselective Formation of Spiroepoxides
Synthesis, 1997, 268-270

657
Adam, W.; Smerz, A.K.; Zhao, C.-G.
Dioxiranes - Highly Reactive Oxidants for Stereoselective Oxyfunctionalizations
J. Prakt. Chem., 1997, 339, 298-300

658
Adam, W.; Blancafort, L.
Reaction of a-Peroxy Lactones with C, N, P and S Nucleophiles: Adduct Formation and Nucleophilic Oxidation by Nucleophilic Attack and Biphilic Insertion into the Peroxide Bond
J. Org. Chem., 1997, 62, 1623-1629

659
Adam, W.; Groer, P.; Saha-Möller, C.R.
Enzymatic Preparation of Optically Active a-Methylene b-Lactones by Lipase-Catalyzed Kinetic Resolution Through Asymmetric Transesterification
Tetrahedron: Asymmetry, 1997, 8, 833-836

660
Adam, W.; Emmert, O.; Harrer, H.M.
Photochemically Generated Cyclopentane-1,3-diyl Triplet Diradicals as Model Systems for the Assessment of Spin Delocalization in Heteroaryl-Substituted Benzyl-Type Monoradicals through the EPR-Spectral D Parameter
J. Chem. Soc., Perkin Trans. 2, 1997, 687-694

661
Hoch, U.; Adam, W.; Fell, R.T.; Saha-Möller, C.R.; Schreier, P.
Horseradish Peroxidase - A Biocatalyst for the One-Pot Synthesis of Enantiomerically Pure Hydroperoxides and Alcohols
J. Mol. Cat., 1997, 117A, 321-328

662
Adam, W.; Corma, A.; Martinez, A.; Mitchell, C.M.; Reddy, I.; Renz, M.; Smerz, A.K.
Diastereoselective Epoxidation of Allylic Alcohols with Hydrogen Peroxide Catalyzed by Titanium-Containing Zeolites or Methyltrioxorhenium versus Stoichiometric Oxidation with Dimethyldioxirane: Clues on the Active Species of the Zeolite Lattice
J. Mol. Cat., 1997, 117A, 357-366

663
Adam, W.; Schneider, K.; Stapper, M.; Steenken, S.
Multiple-Photon Chemistry of 9-(Phenoxymethyl)- and 9,10-Bis(phenoxymethyl)anthracenes in the Laser Jet: Generation, Photochemistry and Time-Resolved Laser-Flash Spectroscopy of Anthracenylmethyl Radicals and Pulse Radiolysis of 9-(Bromomethyl)anthracene
J. Am. Chem. Soc., 1997, 119, 3280-3287

664
Adam, W.; Korb, M.
The Titanium-Catalyzed, Asymmetric Epoxidation of Allylic Alcohols with Optically Active Hydroperoxides in the Presence of Achiral Diol Ligands
Tetrahedron: Asymmetry, 1997, 8, 1131-1142

665
Hoch, U.; Humpf, H.-U.; Schreier, P.; Saha-Möller, C.R.; Adam, W.
Configurational Assignment of Optically Active Hydroperoxy Homoallylic Alcohols and the Corresponding Diols by Circular Dichroism and Multidimensial Gas Chromatography
Chirality, 1997, 69-74

666
Adam, W.; Mock-Knoblauch, C.; Saha-Möller, C.R.
Kinetic Resolution of Hydroxy Vinylsilanes by Lipase-Catalyzed Enantioselective Acetylation
Tetrahedron: Asymmetry, 1997, 8, 1441-1444

667
Adam, W.; Peters, K.; Renz, M.
Titanium-Catalyzed Diastereoselective Epoxidations of Ene Diols and Allylic Alcohols with b-Hydroperoxy Alcohols as Novel Oxygen Donors
J. Org. Chem., 1997, 62, 3183-3189

668
Adam, W.; Corma, A.; Reddy, T.I.; Renz, M.
The Diastereoselective Catalytic Epoxidation of Chiral Allylic Alcohols by the TS-1 and Ti-beta Zeolites: Evidence for a Hydrogen-Bonded, Peroxy-Type Loaded Complex as Oxidizing Species
J. Org. Chem., 1997, 62, 3631-3637

669
Adam, W.; Schneider, K.; Steenken, S.
Multiple-Photon Chemistry in the Laser Jet: Photochemistry and Time-Resolved Laser-Flash Spectroscopy of the 1-Naphthylmethyl Radical
J. Org. Chem., 1997, 62, 3727-3733

670
Schenk, W.A.; Frisch, J.; Dürr, M.; Burzlaff, N.; Stalke, D.; Fleischner, R.; Adam, W.; Prechtl, F.; Smerz, A.
Oxidation of Thioether Ligands in Pseudotetrahedral Cyclopentadienylruthenium Complexes: Toward a New Stereoselective Synthesis of Chiral Sulfoxides
Inorg. Chem., 1997, 36, 2372-2378

671
Adam, W.; van Barneveld, C.; Emmert, O.; Harrer, H.M.; Kita, F.; Sampath Kumar, A.; Maas, W.; Nau, W.M.; Reddy, S.H.K.; Wirz, J.
About Monoradicals, Triplet Diradicals and Higher Spin States: Understanding Electronic Substituent Effects through EPR and Time-Resolved UV Spectroscopy
Pure & Appl. Chem., 1997, 69, 735-742

672
Adam, W.; Moorthy, J. M.; Nau, W.; Scaiano, J.C.
Solvent Effect on the Product Distribution in the Photochemical Pathways of a-CN versus b-CC Cleavage of n,p*-Triplet-Excited Azoalkanes
J. Am. Chem. Soc., 1997, 119, 5550-5555

673
Adam, W.; Reinhardt, D.
Fluoride- and Base-Induced Chemiluminescence (CIEEL) of a Bifunctional Spiroacridane-Substituted Dioxetane
Liebigs Ann. Chem., 1997, 1359-1364

674
Adam, W.; Mitchell, C.M.; Paredes, R.; Smerz, A.K.; Veloza, L.A.
1-Methylgeraniol as Novel Regio- and Diasteeoselective Probe for Hydrogen Bonding in Hydroxy-Assisted Oxygen-Transfer Reactions
Liebigs Ann. Chem., 1997, 1365-1369

675
Adam, W.; Mock-Knoblauch, C.; Saha-Möller, C.R.
Biocatalytic Kinetic Resolution of Hydroperoxy Vinylsilanes by Horseradish Peroxidase (HRP) and Lipases, a Comparative Study
Tetrahedron: Asymmetry, 1997, 12, 1947-1950

676
Adam, W; Moorthy, J.N.; Nau, W.M.; Scaiano, J.C.
Charge-Transfer-Induced Photoreduction of Azoalkanes by Amines
J. Am. Chem. Soc., 1997, 119, 6749-6756

677
Nau, W.M.; Adam, W.; Klapstein; D.; Sahin, C.; Walter, H.
Correlation of Oxidation and Ionization Potentials for Azoalkanes
J. Org. Chem., 1997, 62, 5128-5132

678
Adam, W.; Groer, P.; Mielke, K.; Saha-Möller, C.R.; Kiefer, W.; Nagel, V.; Schneider, F.W.; Ballmaier, D.; Schleger, Y.; Epe, B.
Photochemical and Photobiological Studies with Acridine and Phenanthridine Hydroperoxides in Cell-Free DNA
Photochem. Photobiol., 1997, 66, 26-33

679
Adam, W.; Mielke, K.; Saha-Möller, C.R.; Möller, M.; Stopper, H.; Hutterer, R.; Schneider F.W.; Ballmaier, D.; Epe, B.; Gasparro, F.F.; Chen, X.; Kagan, J.
Photochemical Studies of a Furonaphthopyranone as Benzo-Spaced Psoralen Analog in Cell-Free and Cellular DNA
Photochem. Photobiol., 1997, 66, 46-54

680
Adam, W.; Reinhardt, D.
Chemical Triggering of Dioxetanes Derived from 9-Adamantylideneacridanes: Fluoride- and Base-Induced Chemiluminescence (CIEEL) of Siloxy- and Acetoxy-Substituted Dioxetanes
J. Chem. Soc., Perkin Trans. 2, 1997, 1453-1463

681
Adam, W.; Deeg, O.; Weinkötz, S.
Direct Thioepoxidation of Strained Cyclic Alkenes by the Photolytic Sulfur-Atom Transfer from Thiocarbonyl S-Oxides (Sulfines)
J. Org. Chem., 1997, 62, 7084-7085

682
Adam, W.; Harrer, H.M.; Maas, W.
Additivity of the Electronic meta-Substituent Effect in 3,5-Disubstituted Cumyl Radicals Assessed by the EPR D Parameter of 1,3-Arylcyclopentane-1,3-diyl Triplet Radicals
J. Org. Chem., 1997, 62, 7263-7266

683
Adam, W.; Blancafort, L.; Saha-Möller, C.R.
Kinetic Resolution of Racemic Halohydrins, Precursors of Optically Active Di- and Trialkyl-Substituted Epoxides, with Lipase from Pseudomonas sp.
Tetrahedron: Asymmetry, 1997, 8, 3189-3192

684
Adam, W.; Kammel, T.; Toubartz, M.; Steenken, S.
Detection of Phenyl-Substituted Radical Cations Derived from Cyclopentyl- and Urazole-Type Azoalkanes by Pulse Radiolysis: Influence of Heteroatom Substitution on the Radical-Cation Reactivities
J. Am. Chem. Soc., 1997, 119, 10673-10676

685
Adam, W.; Wirth, T.
Electronic, Steric and Stereoelectronic Effects in the Diastereoselective Photooxygenation (Schenck Ene Reaction) of Acyclic Chiral Alkenes
In Actas de la 26a Reunion Bienal de la Real Sociedad Espanola de Quimica, C. M. Gordillo, Ed.; Servicio de Publicaciones de 1997; pp 191-198

686
Adam, W.; Lazarus, M.; Boss, B.; Saha-Möller, C.R.; Humpf, H.-U.; Schreier, P.
Enzymatic Resolution of Chiral 2-Hydroxy Carboxylic Acids by Enantioselective Oxidation with Molecular Oxygen Catalyzed by the Glycolate Oxidase from Spinach (Spinacia oleracea)
J. Org. Chem., 1997, 62, 7841-7843

687
Adam, W.; Moorthy, J.N.; Nau, W.M.; Scaiano, J.C.
Photoreduction of Azoalkanes by Direct Hydrogen Abstraction from 1,4-Cylohexadiene, Alcohols, Stannanes, and Silanes
J. Org. Chem., 1997, 62, 8082-8090

688
Adam, W.; Humpf, H.-U.; Korb, M.; Schreier, P.
The Configurational Assignment of the Optically Active 5-[(1-Hydroperoxy)ethyl]3-ethoxycarbonyl-2-methylfuran and its Alcohol by Exciton-Coupled Dichroism (ECCD)
Tetrahedron: Asymmetry, 1997, 8, 3555-3558

689
Schenk, W.A.; Steinmetz, B.; Hagel, M.; Adam, W.; Saha-Möller, C.R.
Oxyfunctionalization of Allyl-Thioether-Ruthenium Complexes with Dimethyldioxirane
Z. Naturforsch., 1997, 1359-1371

690
Adam, W.; Zhao, C.-G.
Synthesis of Optically Active C2-Symmetric Ketones for the Asymmetric Epoxidation of Prochiral Olefins by Dioxiranes Generated in situ with CaroateTM as Peroxide Source
Tetrahedron: Asymmetry, 1997, 8, 3995-3998

691
Adam, W.; Harrer, H.M.
Electronic Substituent Effects in Radical Chemistry: The DD Scale for Benzyl-Type Radicals
Anales de Quimica, 1997, 93, 271-276

1998

692
Adam, W.; Andler, S.; Saha-Möller, C.R.
DNA Cleavage Induced by Oxyl Radicals Generated in the Photosensitized Decomposition of Fatty Ester Hydroperoxides Derived from Oleic and Linoleic Acid
Arch. Biochem. Biophys., 1998, 349, 261-266

693
Adam, W.; Grimm, G.N.; Saha-Möller, C.R.
DNA Cleavage Induced by Alkoxyl Radicals Generated in the Photolysis of N-Alkoxypyridinethiones
Free Rad. Biol. Med., 1998, 24, 234-238

694
Adam, W.; Paredes, R.; Smerz, A.K.; Veloza, L.A.
Regio-, Diastereo- and Chemoselectivities in the Dioxirane Oxidation of Acyclic and Cyclic Allylic Alcohols by Methyl(trifluoromethyl)dioxirane (TFD): A Comparison with Dimethyldioxirane
Eur. J. Org. Chem., 1998, 349-354

695
Adam, W.; Renze, J.; Wirth, T.
Stereoelectronic Control of the Diastereoselectivity in the Photooxygenation (Schenck Ene Reaction) of an Electron-Poor Allylic Alcohol and its Ethers
J. Org. Chem., 1998, 63, 226-227

696
Adam, W.; Borden, W.T.; Burda, C.; Foster, H.; Heidenfelder, T.; Heubes, M.; Hrovat, D.A.; Kita, F.; Lewis, S.B.; Scheutzow, D.; Wirz, J.
Transient Spectroscopy of a Derivative of 2,2-Difluoro-1,3-diphenylcylopentane-1,3-diyl - A Persistent Localized Singlet 1,3-Diradical
J. Am. Chem. Soc., 1998, 120, 593-594

697
Adam, W.; Fell, R.T.; Stegmann, V.R.; Saha-Möller, C.R.
Synthesis of Optically Active a-Hydroxy Carbonyl Compounds by the Catalytic, Enantioselective Oxidation of Silyl Enol Ethers and Ketene Acetals with (Salen)manganese(III) Complexes
J. Am. Chem. Soc., 1998, 120, 708-714

698
Adam, W.; Handmann, V.-I.; Kita, F.; Heidenfelder, T.
Divergent Pathways in the Rearrangement of Tricyclo[3.3.0.02,4]octanes (Housanes) on Chemical Electron Transfer (CET) versus Acid Catalysis: A Comparison of Radical Cations and Carbocations
J. Am. Chem. Soc., 1998, 120, 831-832

699
Adam, W.; Fell, R.T.; Saha-Möller, C.R.; Zhao, C.-G.
Synthesis of Optically Active a-Hydroxy Ketones by Enantioselective Oxidation of Silyl Enol Ethers with a Fructose-Derived Dioxirane
Tetrahedron: Asymmetry, 1998, 397-401

700
Adam, W.; Lazarus, M.; Saha-Möller, C.R., Schreier, P.
Quantitative Transformation of Racemic 2-Hydroxy Acids into (R)-2-Hydroxy Acids by Enantioselective Oxidation with Glycolate Oxidase and Subsequent Reduction of 2-Keto Acids with D-Lactate Dehydrogenase
Tetrahedron: Asymmetry, 1998, 351-355

701
Adam, W.; Wirth, T.; Pastor, A.; Peters, K.
Dramatic Diastereoselectivity in the Asymmetric Ene Reactions of Triazolinediones and Singlet Oxygen with Chiral 2,2-Dimethyloxazolidine Derivatives of Tiglic Acid
Eur. J. Org. Chem., 1998, 501-506

702
Peters, K.; Peters, E.-M.; Adam, W.; Ahrweiler, M.; Vlcek, P.
Crystal Structure of N,N'-diacetyl-N,N'-dibenzoyl-1,2-ethylendiamine, (CH3CO)2(C6H5CO)2C2H4N2
Z. Kristallogr., 1998, 301-302

703
Peters, K.; Peters, E.-M.; Adam, W.; Qian, X.; Saha-Möller, C.R.
Crystal Structure of 2,2',3,3'-tetramethylbisfuro[3,2-b]naphthalene, (CH3)4C14H4O2
Z. Kristallogr., 1998, 303-304

704
Peters, K.; Peters, E.-M.; Adam, W.; Nestler, B.
Crystal Structure of 2-Benzoyl-4-methyl-1-[1-(methylethenyl)-2-benzoyloxypropyl]-1,2,4-triazolidine-3,3-dione, C23H23N3O5
Z. Kristallogr., 1998, 305-306

705
Peters,K.; Peters, E.-M.; Adam, W.; Jacob, U.; Prein, M.
Crystal Structure of anti-1,4,7,8,9,10-hexamethyl-10-methylthio-2,4,6-triazatricyclo[5.2.1.02,6]dec-8-ene-3,5-dione, (CH3)7C7N3O2S
Z. Kristallogr., 1998, 307-308

706
Peters, K.; Peters, E.-M.; Adam, W.; Jacob, U.; Prein, M.
Crystal Structure of anti-10-Formyl-1,4,7,8,9,10-hexamethyl-2,4,6-triazatricyclo[5.2.1.02,6]dec-8-ene-3,5-dione, (CH3)6(CHO)C7N3O2
Z. Kristallogr., 1998, 309-310

707
Peters, K.; Peters, E.-M.; Adam, W.; Ahrweiler; M.; Reinhardt, D.
Crystal Structure of 13-Acetyl-4,13-dimethyl-12-oxacylopropane-12-spiro[2,4,6]triazatricyclo-[5.2.2.02.6]undec-10-ene-3,5,9-trione, C13H13N3O5
Z. Kristallogr., 1998, 311-312

708
Adam, W.; Diaz, M.T.; Saha-Möller, C.R.
Lipase-Catalyzed Kinetic Resolution of threo-Configured 1,2-Diols: A Comparative Study of Transesterification versus Hydrolysis
Tetrahedron: Asymmetry, 1998, 589-598

709
Adam, W.; Diaz, M.T.; Saha-Möller, C.R.
Lipase-Catalyzed Kinetic Resolution of a,b-Unsaturated a'-Acetoxy Ketones
Tetrahedron: Asymmetry, 1998, 791-796

710
Adam, W.; Nestler, B.; Pastor, A.; Wirth, T.
Hydroxy-Directed Diastereoselective Ene Reaction of Triazolinediones with Chiral Allylic Alcohols
Tetrahedron Lett., 1998, 2625

711
Schüler, E.; Häring, D.; Boss, B.; Herderich, M.; Schreier, P.; Adam, W.; Mock-Knoblauch, C.; Renz, M.; Saha-Möller, C.R.; Weichold, O.
The Potential of Selenium-Containing Peroxidases in Asymmetric Catalysis: Glutathion Peroxidase and Seleno-Subtilisin
In Selective Reactions of Metal-Activated Molecules; H.Werner; P. Schreier, Eds.; Vieweg Verlag: Braunschweig 1998; pp 35-38

712
Adam, W.; Diaz, M.T.; Fell, R.T.; Groer, P.; Mock-Knoblauch, C.; Saha-Möller, C.R.; Weichold, O.;Boss, B.; Hoch, U.; Humpf, H.-U.; Lazarus, M.; Lukacs, Z.; Schreier, P.
Biocatalytic Synthesis of Optically Active Oxyfunctionalized Compounds
In Selective Reactions of Metal-Activated Molecules; H.Werner; P. Schreier, Eds.; Vieweg Verlag: Braunschweig 1998; pp 39-42

713
Adam, W.; Fell, R.T.; Korb, M.N.; Mitchell, C.M., Saha-Möller, C.R.
Selective Metal-Catalyzed Oxygen Transfer
In Selective Reactions of Metal-Activated Molecules; H.Werner; P. Schreier, Eds.; Vieweg Verlag: Braunschweig 1998; pp 43-45

714
Adam, W.; Corma, A.; Renz, M.
Chemo- and Diastereoselective Epoxidations Catalyzed by Titanium-Containing Zeolites: Evidence for a Hydrogen-Bonded, Peroxy-Type Loaded Complex as Oxidizing Species
In Selective Reactions of Metal-Activated Molecules; H.Werner; P. Schreier, Eds.; Vieweg Verlag: Braunschweig 1998; pp 47-50

715
Schenk, W.A.; Dürr, M.; Steinmetz, B.; Adam, W.; Saha-Möller, C.R.
Enantioselective Oxidation of Thioethers Using Ruthenium Complexes as Chiral Auxiliary
In Selective Reactions of Metal-Activated Molecules; H.Werner; P. Schreier Eds.; Vieweg Verlag: Braunschweig 1998; pp 245-249

716
Elias, H.; Stock, F.; Adam, W.; Mitchell, C.M.; Neuburger, M.
Salen-Type Oxo Vanadium Complexes as Catalysts for Sulfoxidation and Epoxidation Reactions with Hydroperoxides
In Selective Reactions of Metal-Activated Molecules; H.Werner; P. Schreier Eds.; Vieweg Verlag: Braunschweig 1998; pp 251-255

717
Aubry, J.M.; Nardello, V.; Bouttemy, S.; Wirth, T.; Linker, T.; Adam, W.
The Luminous and the Dark Side of Singlet Oxygen: Comparison Between Photochemical and Chemical Sources of Singlet Oxygen (1O2, 1Dg) in Organic Synthesis
In Selective Reactions of Metal-Activated Molecules; H.Werner; P. Schreier Eds.; Vieweg Verlag: Braunschweig 1998; pp 277-281

718
Adam, W.; Korb, M.N.; Saha-Möller, C.R.
Optically Active Epoxy Diols by Titanium-Catalyzed Oxidation of Enantiomerically Enriched Hydroperoxy and Hydroxy Homoallylic Alcohols
Eur. J. Org. Chem., 1998, 907-912

719
Adam, W.; Fell, R.T.; Lévai, A.; Patonay, T., Peters, K.; Simon, A.; Tóth, G.
Enantioselective Epoxidation of Isoflavones by Jacobsen's Mn(III)salen Catalysts and Dimethyldioxirane Oxygen-Atom Source
Tetrahedron: Asymmetry, 1998, 9, 1121-1124

720
Nagel, V.; Duschek, F.; Kiefer, W.; Görth, F.; Golsch, D.; Adam,W.; Ferrer, M.; Messeguer, A.
Detection of Singlet Oxygen During Several Organic Reactions by Chemiluminescence Spectroscopy
Asian J. Spectrosc., 1998, 35-43

721
Abe, M.; Adam, W.
Electronic Substituent Effects on the EPR-Spectral D Parameter of Trimethylenemethane (TMM) Triplet Diradicals Compared with Localized Cyclopentane-1,3-Diyls
J. Chem. Soc., Perkin Trans. 2, 1998, 1063-1068

722
Adam, W.; Andler, S.; Nau, W.M.; Saha-Möller, C.R.
Oxidative DNA Damage by Radicals Generated in the Thermolysis of Hydroxymethyl-Substituted 1,2-Dioxetanes through the a-Cleavage of Chemiexcited Ketones
J. Am. Chem. Soc., 1998, 120, 3549-3559

723
Adam, W.; Güthlein, M.; Peters, E.-M.; Peters, K.; Wirth, T.
Chiral-Auxiliary-Induced Diastereoselectivity in the [4+2] Cycloaddition of Optically Active 2,2-Dimethyloxazolidine Derivatives of Sorbic Acid: A Model Study with Singlet Oxygen as the Smallest Dienophile
J. Am. Chem. Soc., 1998, 120, 4091-4093

724
Adam, W.; Korb, M.N.; Roschmann, K.J.; Saha-Möller, C.R.
Titanium-Catalyzed, Asymmetric Sulfoxidation of Alkyl Aryl Sulfides with Optically Active Hydroperoxides
J. Org. Chem., 1998, 63, 3423-3428

725
Adam, W.; Weinkötz, S.
1,3-Dipolar Cycloaddition of Fluorenethione S-Oxide and trans-Cyclooctene: Isolation of a Sultene and Its Novel Acid-Catalyzed Diastereoselective Sulfur-Atom Transfer to Cyclic Olefins
J. Am. Chem. Soc., 1998, 120, 4861-4862

726
Adam, W.; Argüello, J.E.; Peñéñory, A.B.
Photochemical Electron-Transfer Reactions between Sulfides and Tetranitromethane. Oxidation vs Fragmentation of the Sulfide Radical-Cation Intermediate
J. Org. Chem., 1998, 63, 3905-3910

727
Adam, W.; Makosza, M.; Stalinski, K.; Zhao, C.-G.
DMD Oxidation of in-situ-Generated H Adducts Derived from Nitroarenes and the Carbanion of 2-Phenylpropionitrile to Phenols: The First Direct Substitution of a Nitro by a Hydroxy Group
J. Org. Chem., 1998, 63, 4390-4391

728
Adam, W.; Bronstein, I.; Trofimov, A.V.
Solvatochromic Effects on the Electron Exchabnge Chemiluminescence (CIEEL) of Spiroadamantyl-Substituted Dioxetanes and the Fluorescence of Relevant Oxyanions
J. Phys. Chem., 1998, 102A, 5406-5414

729
Adam, W.; Harrer, H.M.; Kita, F.; Nau, W.M.
The EPR-Spectroscopic D Parameter of Localized Triplet Diradicals as Probe for Electronic Effects in Benzyl-Type Monoradicals
Adv. Photochem., 1998, 24, 205-254

730
Adam, W.; Lazarus, M.; Schmerder, A.; Humpf, H.-U.; Saha-Möller, C.R.; Schreier, P.
Synthesis of Optically Active a-Hydroxy Acids by Kinetic Resolution Through Lipase-Catalyzed Enantioselective Acetylation
Eur. J. Org. Chem., 1998, 2013-2018

731
Adam, W.; Fröhling, B.; Peters, K.; Weinkötz, S.
Diastereoselective Episulfidation of Strained Cyclic Alkenes by a Thiophene Endoperoxide versus Epoxidation by Dimethyldioxirane (DMD)
J. Am. Chem. Soc., 1998, 120, 8914-8919

732
Adam, W.; Grimm, G.N.; Saha-Möller, C.R.; Dall'Acqua, F.; Miolo, G.; Vedaldi, D.
DNA Damage by tert-Butoxyl Radicals Generated in the Photolysis of a Water-Soluble, DNA-Binding Peroxyester as Radical Source
Chem. Res. Toxicol., 1998, 11, 1089-1097

733
Adam, W.; Lazarus, M.; Hoch, U.; Korb, M.N.; Saha-Möller, C.R.; Schreier, P.
Horseradish-Peroxidase-Catalyzed Enantioselective Reduction of Racemic Hydroperoxy Homoallylic Alcohols: A Novel Enzymatic Method for the Preparation of Optically Active, Unsaturated Diols and Hydroperoxy Alcohols
J. Org. Chem., 1998, 63, 6123-6127

734
Adam, W.; Nikolaus, A.
Fluorescence Quenching of Ester-Substituted DBO-Type Azoalkanes by Olefins and Arenes: Electronic and Steric Effects, Exciplex Formation and Hydrogen Abstraction
Eur. J. Org. Chem., 1998, 2177-2179

735
Lévai, A.; Adam, W.; Fell, R.T.; Gessner, R.; Patonay, T.; Simon, A.; Tóth, G.
Enantioselective Synthesis and Chiroptical Properties of Optically Active Isoflavone Epoxides
Tetrahedron, 1998, 54, 13105-13114

736
Adam, W.; Häfner, A.; Nikolaus, A.; Sauer, J.; Schneider, F.W.
Structural Effects on the Photopersistence of Ester- and Phenyl-Substituted DBO-Type Polycyclic Azoalkanes with Cyclopropyl and Norbornyl Annelation
J. Inf. Rec., 1998, 24, 185-190

737
Adam, W.; Arnold, M.A.; Grimm, G.N.; Saha-Möller, C.R.; Dall'Acqua, F.D.; Miolo, G.; Vedaldi, D.
4-tert-Butylperoxymethyl-9-methoxypsoralen as Intercalating Photochemical Alkoxyl-Radical Source for Oxidative DNA Damage
Photochem. Photobiol., 1998, 68, 511-518

738
Gernet, D.; Adam, W.; Kiefer, W.
Matrix-isolation Raman spectroscopy, semiempirical calculations and normal coordinate analysis of strained systems Part II: Bicyclo[2.1.0]pentane
Vibr. Spectrosc., 1998, 17, 31

739
Ferrer, M.; Sánchez-Baeza, F.; Messeguer, A., Adam, W.; Golsch, D.; Goerth, F.; Kiefer, W.; Nagel, W.
The Release of Singlet Oxygen in the Reaction of Dioxiranes with Amine N-Oxides
Eur. J. Org. Chem., 1998, 2527-2532

740
Adam, W.; Boland, W.; Hartmann-Schreier, J., Humpf, H.-U.; Lazarus, M.; Saha-Möller, C.R.; Saffert, A.; Schreier, P.
a Hydroxylation of Carboxylic Acids with Molecular Oxygen Catalyzed by the a Oxidase of Peas (Pisum sativum): A Novel Biocatalytic Synthesis of Enantiomerically Pure (R)-2-Hydroxy Acids
J. Am. Chem. Soc., 1998, 120, 11044-11048

741
Adam, W.; Boss, B.; Harmsen, D.; Lukacs, Z.; Saha-Möller, C.R.; Schreier, P.
The Kinetic Resolution of Chiral Hydroperoxides: Hydrogen-Peroxide-Mediated Screening of Peroxidase-Active Soil Bacteria
J. Org. Chem., 1998, 63, 7598-7599

742
Abe, M.; Adam, W.; Nau, W.M.
Photochemical Generation and Methanol Trapping of Localized 1,3 and 1,4 Singlet Diradicals Derived from a Spiroepoxy-Substituted Cyclopentane-1,3-diyl
J. Am. Chem. Soc., 1998, 120, 11304-11310

743
Malisch, W.; Jehle, H.; Möller, S.; Saha-Möller, C.R.; Adam, W.
Regioselective Hydroxylation of Metallo Disilanes of the Iron Group - An Impressive Example of the Transition Metal Effect
Eur. J. Inorg. Chem., 1998, 1585-1587

744
Malisch, W.; Jehle, H.; Mitchell, C.M.; Adam, W.
A Catalytic Pathway for the Conversion of Tungsten Silanes into Tungsten Silanols
J. Organomet. Chem., 1998, 566, 259-262

745
Adam, W.; Balci, M.; Kiliç, H.
Oxyfunctionalization of Biphenylene by Singlet Oxygen, Hydrogen Peroxide/Methyltrioxorhenium, and Dimethyldioxirane
J. Org. Chem., 1998, 63, 8544-8546

746
Alam, M.M.; Ito, O.; Grimm, G.N.; Adam, W.
Characterization and Reactivities of Transient Species Generated by Laser-Flash Photolysis of N-Hydroxypyridine-4-thione
J. Chem. Soc., Perkin Trans. 2, 1998, 2471-2476

747
Adam, W.; Heidenfelder, T.
Electronic Substituent Effects for the Fine-Tuning of the Regioselectivity in the Diastereoselective Rearrangement of 1,3-Cyclopentanediyl Radical Cations Generated from Tricyclo[3.3.0.02,4]octanes (Housanes) by Chemical Electron Transfer (CET)
J. Am. Chem. Soc., 1998, 120, 11858-11863

748
Adam, W.; Garcia, H.; Mitchell, C.M.; Saha-Möller, C.R.; Weichold, O.
The Selective Catalytic Oxidation of Silanes to Silanols with H2O2 Activated by the Ti-beta Zeolite
Chem. Commun., 1998, 2609-2610

749
Adam, W.; Makosza, M.; Saha-Möller, C.R.; Zhao, C.-G.
A Mild and Efficient Nef Reaction for the Conversion of Nitro to Carbonyl Group by Dimethyldioxirane (DMD) Oxidation of Nitronate Anions
Synlett, 1998, 1335-1336

750
Adam, W.; Saha-Möller, C.R.; Zhao, C.-G.
Enantioselective Oxidation of vic-Diols to Optically Active a-Hydroxy Ketones by a Fructose-Derived Dioxirane
Tetrahedron: Asymmetry, 1998, 9, 4117-4122

751
Adam, W.; Fröhling, B.; Weinkötz, S.
Thermal and Photochemical 1,3-Dipolar Cycloaddition of Fluorenethione S-oxide (Sulfine) to the Strained Triple Bond of Cyclooctyne
J. Org. Chem., 1998, 63, 9154-9155

752
Patonay, T.; Adam, W.; Levai, A.
Dimethyldioxirane Oxidations of Some Heterocycles Containing Oxygen or Sulfur: Chemo- and Stereoselectivity
In Proceedings of the Blue Danube Symposium on Heterocyclic Chemistry; Kotschy, A., Hajos, G., Eds.; Merlin Multimedia Ltd.: 1998; Paper 11/1-Paper 11/6

753
Adam, W.; Lazarus, M.; Saha-Möller, C.R.; Weichold, O.; Hoch, U.; Häring, D.; Schreier, P.
Biotransformations with Peroxidases.
In Advances in Biochemical Engineering/Biotechnology; Faber, K., Ed.; Springer Verlag: Heidelberg, 1998; Vol. 63, pp 73-108

1999

754
Peters, K.; Peters, E.-M.; Adam, W.; Pastor, A.; Wirth, T.
Crystal structure of [S-(R*, R*)]-1-[3-(2,2-dimethyl-4-phenyloxazolidine-3-yl]-1-methyl-2-[methylidene-3-oxopropyl]-4-phenyl-1,2,4-triazolidine-3,5-dione, C11H14NO[C5H6O)C8H6N3 O2
Z. Kristallogr., 1999, 87-88

755
Häring, D.; Schüler, E.; Adam, W.; Saha-Möller, C.R.; Schreier, P.
Semisynthetic Enzymes in Asymmetric Synthesis: Enantioselective Reduction of Racemic Hydroperoxides
J. Org. Chem., 1999, 64, 832-835

756
Rodriguez, G.; Castedo, L., Dominguez, D.; Saá, C.; Adam, W.; Saha-Möller, C.R.
Dioxirane Epoxidation of 10-Membered-Ring Stilbene Lactams as Synthetic Precursors to Protoberberines
J. Org. Chem., 1999, 64, 877-883

757
Adam, W.; Bronstein, I.; Trofimov, A.V.; Vasil'ev, R.F.
Solvent-Cage Effect (Viscosity Dependence) as a Diagnostic Probe for the Mechanism of the Intramolecular Chemically Initiated Electron-Exchange Luminescence (CIEEL) Triggered from a Spiroadamantyl-Substituted Dioxetane
J. Am. Chem. Soc., 1999, 121, 958-961

758
Adam, W.; Grimm, G.N.; Marquardt, S.; Saha-Möller, C.R.
Are Pyridinethiones Reliable Photochemical Oxyl-Radical Sources for Photobiological Studies? The Importance of Secondary Photolysis Products in the Guanine Oxidation of 2'-Deoxyguanosine and Cell-Free DNA
J. Am. Chem. Soc., 1999, 121, 1179-1185

759
Adam, W.; Degen, H.-G.; Saha-Möller, C.R.
Regio- and Diastereoselective Catalytic Epoxidation of Chiral Allylic Alcohols with Hexafluoroacetone Perhydrate. Hydroxy-Group Directivity through Hydrogen Bonding
J. Org. Chem., 1999, 64, 1274-1277

760
Adam, W.; Saha-Möller, C.R.; Schmid, K.S.
Lipase-Catalyzed Kinetic Resolution of Z-Configured Homoallylic Alcohols
Tetrahedron: Asymmetry, 1999, 10, 315-322

761
Adam, W.; Stegmann, V.R.; Saha-Möller, C.R.
Regio- and Diastereoselective Epoxidation of Chiral Allylic Alcohols Catalyzed by Manganese(salen) and Iron(porphine) Complexes
J. Am. Chem. Soc., 1999, 121, 1879-1882

762
Adam, W.; Saha-Möller, C.R.; Schambony, S.B.
A Highly Diastereoselective Dioxetane Formation by the Hydroxy-Directed [2+2] Cycloaddition of Singlet Oxygen to a Chiral Allylic Alcohol
J. Am. Chem. Soc., 1999, 121, 1834-1838

763
Adam, W.; Mitchell, C.M.; Saha-Möller, C.R.; Weichold, O.
Host-Guest Chemistry in a Urea Matrix: Catalytic and Selective Oxidation of Triorganosilanes to the Corresponding Silanols by Methyltrioxorhenium and the Urea/Hydrogen Peroxide Aduct
J. Am. Chem. Soc., 1999, 121, 2097-2103

764
Adam, W.; Kurz, A.; Saha-Möller, C.R.
DNA and 2'-Deoxyguanosine Damage in the Horseradish-Peroxidase-Catalyzed Autoxidation of Aldehydes: The Search for the Oxidizing Species
Free Rad. Biol. Med., 1999, 26, 566-579

765
Adam, W.; Mitchell, C.M.; Saha-Möller, C.R.
Steric and Electronic Effects in the Diastereoselective Catalytic Epoxidation of Cyclic Allylic Alcohols with Methyltrioxorhenium (MTO)
Eur. J. Org. Chem., 1999, 785-790

766
Peters, K.; Peters, E.-M.; Fröhling, B.; Weinkötz, S.; Adam, W.
Crystal Structure of trans-9-Thiabicyclo[6.1.0]nonan-3-ol, C8H13(S)OH
Z. Kristallogr., 1999, 275-276

767
Potapenko, A.-Y.; Kyagova, A.A.; Andina, E.S.; Zhuravel, N.N.; Lysenko, E.P.; Möller, M.; Stopper, H.; Adam, W.; Saha-Möller, C.R.
Photohemolysis Sensitized by the Furocoumarin Imperatorin and its Oxyfunctionalized Derivatives
Photochem. Photobiol., 1999, 69, 410-420

768
Patonay, T.; Adam, W.; Jeko, J.; Kövér, K.E.; Lévai, A.; Németh, M.; Peters, K.
Oxazepines and Thiazepines 36. Diastereoselective Sulfoxidation of 2,3-Dihydro-1,5-Benzothiazepin-4(5H)-ones by Dimethyldioxirane
Heterocycles, 1999, 51, 85-94

769
White, R.C.; Adam, W.; Ihmels, H.; Selvam, T.
Photolysis of N-Phenyl-hydoxylamine: A Novel Photochemical Disproportionation Reaction in the N-O Bond Cleavage Assisted by Hydrogen Bonding
J. Photochem. Photobiol., 1999, 122A, 7-10

770
Adam, W.; Lukacs, Z.; Saha-Möller, C.R.; Schreier, P.
Biotransformation of (1-Phenyl)ethyl Hydroperoxide with Aspergillus Niger: A Model Study on Enzyme Selectivity and on the Induction of Peroxidase Activity
Biochim. Biophys. Acta, 1999, 1427, 236-244

771
Alam, M.M.; Ito, O.; Adam, W.; Grimm, G.; Saha-Möller, C.R.
Photochemical Reactions of Triplet State of N-Hydroxyacridine-9-thione Studied by Laser-Flash Photolysis
Phys. Chem. Chem. Phys., 1999, 1, 1851-1857

772
Adam, W.; Bronstein, I.; Trofimov, A.V.
Unusual Hydrogen-Bonding Effect on the Fluorescence versus Chemiluminescence (CIEEL) of the Meta-Oxybenzoate Ion
In Bioluminescence and Chemiluminescence: Perspectives for the 21st Century, Proceedings of the 10th International Symposium 1999; pp 33-36

773
Adam, W.; Emmert, O.; Heidenfelder, T.
The EPR-Spectral D Parameter of Photochemically Generated Cyclopentane-1,3-diyl Triplet Diradicals as a Quantitative Measure of Spin Delocalization in Vinyl-, Phenyl- and Carbonyl-Substituted Radicals
J. Org. Chem., 1999, 64, 3417-3421

774
Adam, W.; Nikolaus, A.; Sauer, J.
Influence of Bridgehead Substitution and Ring Annelation on the Photophysical Properties of Polycyclic DBO-Type Azoalkanes
J. Org. Chem., 1999, 64, 3695-3698

775
Adam, W.; Mitchell, C.M.; Saha-Möller, C.R.
Regio- and Diastereoselective Catalytic Epoxidation of Acyclic Allylic Alcohols with Methyltrioxorhenium: A Mechanistic Comparison with Metal (Peroxy and Peroxo Complexes) and Nonmetal (Peracids and Dioxirane) Oxidants
J. Org. Chem., 1999, 64, 3699-3707

776
Adam, W.; Bottke, N.; Krebs, O.; Saha-Möller, C.R.
Allylic Amidation of Olefins by Ene Reaction of Acylnitroso Compounds Generated in situ by Oxidation of Hydroxamic Acids
Eur. J. Org. Chem., 1999, 1963-1965

777
Wilsey, S.; Bernardi, F.; Olivucci, M.; Robb, M.A.; Murphy, S.; Adam, W.
The Thermal Decomposition of 1,2-Dioxetane Revisited
J. Phys. Chem., 1999, 103, 1669-1677

778
Adam, W.; Wirth, T.
Hydroxy-Group Directivity in the Epoxidation of Chiral Allylic Alcohols: Control of Diastereoselectivity through Allylic Strain and Hydrogen Bonding
Acc. Chem. Res., 1999, 32, 703-710

779
Rodriguez, G.; Castedo, L.; Dominguez, D.; Sáa, C., Adam, W.
Regioselective Synthesis of Isoquino[1,2-b][3]benzazepines (Homoprotoberberines) through 11-Membered-Ring Stilbene Lactams Obtained by Radical Macrocyclization
J. Org. Chem., 1999, 64, 4830-4833

780
Adam, W.; Mock-Knoblauch, C.; Saha-Möller, C.R.
Asymmetric Synthesis with the Enzyme Coprinus Peroxidase: Kinetic Resolution of Chiral Hydroperoxides and Enantioselective Sulfoxidation
J. Org. Chem., 1999, 64, 4834-4839

781
Adam, W.; Saha-Möller, C.R.; Zhao, C.-G.
Asymmetric Epoxidation of Olefins by Chiral Dioxiranes Generated in situ From Ketones of D-(-)-Quinic Acid
Tetrahedron: Asymmetry, 1999, 10, 2749-2755

782
Adam, W.; Marquardt, S.; Saha-Möller, C.R.
Oxidative DNA Damage in the Photolysis of N-Hydroxy-2-Pyridone, a Specific Hydroxyl-Radical Source
Photochem. Photobiol., 1999, 70, 287-291

783
Kita, F.; Adam, W.; Jordan, P.; Nau, W.M.; Wirz, J.
1,3-Cyclopentanediyl Diradicals: Substituent and Temperature Dependence of Triplet-Singlet Intersystem Crossing
J. Am. Chem. Soc., 1999, 121, 9265-9275

784
Adam, W.; Garcia, H.; Marti, V.; Moorthy, J.N.
Homolytic Substitution (SH2) versus Triplet Diradical (ISC) in the Photochemical Denitrogenation of a DBH Azoalkane: Temperature-Dependent syn/anti Diastereoselectivity as a Mechanistic Probe for the Doubly-Inverted Housane
J. Am. Chem. Soc., 1999, 121, 9475-9476

785
Adam, W.; Saha-Möller, C.R.; Zhao, C.-G.
Asymmetric C-H Oxidation of vic Diols to a-Hydroxy Ketones by a Fructose-Derived Dioxirane: Electronic Effects on the Enantioselectivity of Oxygen Transfer
J. Org. Chem., 1999, 64, 7492-7497

786
Adam, W.; Saha-Möller, C.R.; Schambony, S.; Schmid, K.S.; Wirth, T.
Stereocontrolled Photooxygenations - A Valuable Synthetic Tool
Photochem. Photobiol., 1999, 70, 476-483

787
Adam, W.; Lazarus, M.; Saha-Möller, C.R.; Schreier, P.
Biocatalytic Synthesis of Optically Active a-Oxyfunctionalized Carbonyl Compounds
Acc. Chem. Res., 1999, 32, 837-845

788
Adam, W.; Heidenfelder, T.
Regio- and Diastereoselective Rearrangement of Cyclopentane-1,3-diyl Radical Cations Generated by Electron Transfer
Chem. Soc. Rev., 1999, 28, 359-366

789
Adam, W.; Barneveld van, C.; Gerke, J.-S.; Klärner, F.-G.
The EPR D-Parameter of 1,3-Cyclopentanediyl Triplet Diradicals as a Probe for Steric Substituent Effects in Benzyl-Type Radicals
J. Chem. Soc., Perkin Trans. 2, 1999, 2723-2728

790
Blancafort, L.; Adam, W.; González, D.; Olivucci, M.; Vreven, T.; Robb, M.A.
Theoretical Study of the 1,2 Rearrangement of Housane Radical Cations: Key Role of a Transient Cyclopentane-1,3-diyl Intermediate
J. Am. Chem. Soc., 1999, 121, 10583-10590

791
Adam, W.; Barneveld van, C.
The Importance of Spin Polarization in Electronic Substituent Effects of the Zero-Field EPR D Parameter in 1,3-Diarylcyclopentane-1,3-diyl Triplet Diradicals
J. Am. Chem. Soc., 1999, 121, 10820-10827

792
Andina, E.S.; Kyagova, A. A.; Yurikova, N.N.; Neklyukova, M.B.; Potapenko, A.Y.; Adam, W.; Saha-Moeller, C.R.
Immunosuppression Induced by the Photooxidation Products of Furocoumarins (Psoralens)
In Proceedings of the Symposium on Biologic Effects of Light; Holick, M.F., Jung, E.G. , Eds.;. Kluwer Academic Publishers: H 1999; pp 213-216

2000

793
Adam, W.; Lukacs, Z.; Viebach, K.; Humpf, H.-U.; Saha-Möller, C.R.; Schreier, P.
Microscale Determination of the Absolute Configuration of a-Aryl-Substituted Alcohols by the CD Exciton Chirality Method
J. Org. Chem., 2000, 65, 186-190

794
Adam, W.; Lukacs, Z.; Harmsen, D.; Saha-Möller, C.R.; Schreier, P.
Biocatalytic Asymmetric Hydroxylation of Hydrocarbons with the Topsoil-Microorganism Bacillus megaterium
J. Org. Chem., 2000, 65, 878-882

795
Adam, W.; Roschmann, K.J.; Saha-Möller, C.R.
Catalytic Asymmetric Aziridination of Enol Derivatives in the Presence of Chiral Copper Complexes to give Optically Active a-Amino Ketones
Eur. J. Org. Chem., 2000, 557-561

796
Adam, W.; Nikolaus, A.
Photoreduction of Polycyclic DBO-Type Azoalkane with Amines to Hydrazine Products
J. Am. Chem. Soc., 2000, 122, 884-888

797
Adam, W.; Saha-Möller, C.R.; Schmid, K.S.
Preparation of Optically Active Allylic Hydroperoxy Alcohols and 1,3 Diols by Enzyme-Catalyzed Kinetic Resolution and Photooxygenation of Chiral Homoallylic Alcohols
J. Org. Chem., 2000, 65, 1431-1433

798
Adam, W.; Makosza, M.; Zhao, C.-G.; Surowiec, M.
On the Mechanism of the Dimethyldioxirane Oxidation of H Adducts (Meisenheimer Complexes) Generated from Nitroarenes and Carbanions
J. Org. Chem., 2000, 65, 1099-1101

799
Abe, M.; Adam, W.; Heidenfelder, T.; Nau, W.M.; Zhang, X.
Intramolecular and Intermolecular Reactivity of Localized Singlet Diradicals: The Exceedingly Long-Lived 2,2-Diethoxy-1,3-diphenylcyclopentane-1,3-diyl
J. Am. Chem. Soc., 2000, 122, 2019-2026

800
Adam, W.; Gadissa Gelalcha, F.; Saha-Möller, C.R., Stegmann, V.R.
Chemoselective C-H Oxidation of Alcohols to Carbonyl Compounds with Iodosobenzene Catalyzed by (Salen)chromium Complex
J. Org. Chem., 2000, 65, 1915-1918

801
Adam, W.; Barneveld van, C.; Emmert, O.
The EPR D Parameter as a Measure of Spin Delocalization in 1,3-Cyclopentanediyl Triplet Diradicals with Extendedly Conjugated p-Type Substituents
J. Chem. Soc., Perkin Trans. 2, 2000, 4, 637-641

802
Peters, K.; Peters, E.-M.; Adam, W.; Köver, P.; Lévai, A.; Patonay, T.
Crystal Structure of [1S*, 2S*]-trans-6-chloro-2-methyl-1-thiochroman-4-one 1-oxide, C9H6SO2(CH3)Cl
Z. Kristallogr., 2000, 215, 219-220

803
Peters, K.; Peters, E.-M.; Adam,W.; Marti, V.
Crystal Structure of (c-4a,c-8a)-1,4,4a5,8,8a-hexahydro-1,4,10,10-tetramethyl-r-1,c-4:t-5,t-8-dimethanophthalazine, [C7H8N2][C3N2(CH)4]
Z. Kristallogr., 2000, 215, 210

804
Peters, K.; Peters, E.-M.; Adam,W.; Pastor, A.; Wirth, T.
Crystal Structure of [(S-(R*,2R*,3S*)]-2,2-Dimethyl-3-[(2,3-dimethyloxiranyl)carbonyl]4-phenyloxazolidine, [(C3H3NO)(CH3)2(C6H5)]CO[C2HO(CH3) 2]
Z. Kristallogr., 2000, 215, 211-212

805
Peters, K.; Peters, E.-M.; Adam, W.; Köver, P.; Lévai, A.; Patonay, T.
Crystal Structure of [1S, 2S]-cis-6-Chloro-2-methyl-1-thiochroman-4-one 1-oxide, C9H6SO2(CH3)Cl
Z. Kristallogr., 2000, 215, 217-218

806
Peters, K.; Peters, E.-M.; Schambony, S.B.; Adam, W.
Crystal Structure of [2S-[2a(S*),4a]]-2-(1-hydroxy-2-methyl-2-propenyl-N,4-diphenyl-3-oxazolidinecarboxamide, C3H4NO(C4H7O)(C6H5)(CONHC 6H5)
Z. Kristallogr., 2000, 215, 213-214

807
Peters, K.; Peters, E.-M.; Stegmann, V.R.; Adam,W.
Crystal Structure of (S*,S*-1-(3,3-Dimethyl-4,4-diphenyl-2-oxetanyl)ethyl 4-Nitrobenzoate, (C6H5)2(CH3)2C3HO[CHOCO(CH3)(C6H4NO2)]
Z. Kristallogr., 2000, 215, 215-216

808
Li, W.; Lei, X-G.; Lem, G.; McDermott, A.E.; Turro, N.J.; Bottke, N.; Adam, W.
Oxygen and Structural Effects on Silicalite 29Si Spin-Lattice Relaxation Studied by High-Resolution 29Si Solid-State NMR Spectroscopy
Chem. Mat., 2000, 12, 731-737

809
Adam, W.; Matsumoto, M.; Trofimov, A.V.
Hydrogen-Bonding Effects on the Fluorescence versus Electron-Transfer-Initiated Chemiluminescence Spectra of the m-Oxybenzoate Ion Derived from a Bicyclic Dioxetane
J. Org. Chem., 2000, 65, 2078-2082

810
Adam, W.; Peters, K. Peters, E.-M.; Stegmann, V.R.
Hydroxy-Directed Regio- and Diastereoselective [2+2] Photocycloaddition (Paterno-Büchi Reaction) of Benzophenone to Chiral Allylic Alcohols
J. Am. Chem. Soc., 2000, 122, 2958-2959

811
Adam, W.; Garcia, H.; Marti, V.; Moorthy, J.N.; Peters, K.; Peters, E.-M.
Photochemical Denitrogenation of Norbornene-Annelated 2,3-Diazabicyclo[2.1.1]hept-2-ene-Type Azoalkanes: Crystal-Lattice versus Zeolite-Interior Effects
J. Am. Chem. Soc., 2000, 122, 3536-3537

812
Adam, W.; Pastor, A.; Peters, K.; Peters, E.-M.
Opposite p-Face Selectivity for the DMD and m-CPBA Epoxidations of Chiral 2,2-Dimethyloxazolidine Derivatives of Tiglic Amides: Control by Steric Interactions versus Hydrogen Bonding
Org. Lett., 2000, 2, 1019-1022

813
Adam, W.; Pastor, A.; Wirth, T.
Direct Amination of Olefins through Sequential Triazolinedione Ene Reaction and Carbanion-Assisted Cleavage of the N-N Urazole Bond
Org. Lett., 2000, 2, 1295-1297

814
Adam, W.; Mitchell, C.M.; Saha-Möller, C.R.; Selvam, T.
Titanium-Catalysed Oxidation of Thianthrene 5-Oxide in Heterogeneous (Zeolites) versus Homogeneous Media: Electrophilic versus Template-Mediated Oxygen Transfer
J. Mol. Cat., 2000, 154A, 251-255

815
Peters, K.; Peters, E.-M.; Güthlein, M.; Wirth, T.; Adam, W.
Crystal Structure of [4S-[3(2R*, 3Z, 5R*), 4R]]-3-[2,5-bis(acetyloxy)-1-oxo-3-hexenyl]-2,2-dimethyl-4-phenyl-oxazolidine,[C6H7O(OCOCH3)2][C3H3NO(CH3) 2C6H5]
Z. Kristallogr., 2000, 215, 383-384

816
Akita, M.; Miyaji, T.; Muroga, N.; Mock-Knoblauch, C.; Adam, W.; Hikichi, S.; Moro-oka, Y.
Synthesis and Dehydrative Condensation of Square-Planar Mono- and Dinuclear Hydroxopalladium Complexes with the Hydrotris(3,5-diisopropylpyrazolyl)borato Ligand (TpiPr2), TpiPr2(Py)Pd-OH, and (µ-OH)2{PdTp iPr2(H2O)}2
Inorg. Chem., 2000, 39, 2096-2102

817
Adam, W.; Mitchell, C.M.; Saha-Möller, C.R.; Weichold, O.
Structure, Reactivity, and Selectivity of Metal-Peroxo Complexes versus Dioxiranes
In Metal-Oxo and Metal-Peroxo Species in Catalytic Oxidations for Structure and Bonding; Meunier, B., Ed.; Springer-Verlag: B 2000; pp 237-285

818
Adam, W.; Saha-Möller, C.R. , Weichold, O.
NaY Zeolite as Host for the Selective Heterogeneous Oxidation of Silanes and Olefins with Hydrogen Peroxide Catalyzed by Methyltrioxorhenium (MTO)
J. Org. Chem., 2000, 65, 2897-2899

819
Adam, W.; Marti, V.; Sahin, C.; Trofimov, A.V.
Viscosity-Controlled Stereoselective Inversion in the Photochemical Denitrogenation of a Stereolabeled Diazabicyclo[2.2.1]heptene (DBH)-Type Azoalkane
J. Am. Chem. Soc., 2000, 122, 5002-5003

820
Adam, W.; Lukacs, Z.; Saha-Möller, C.R.; Schreier, P.
Biocatalytic Kinetic Resolution of Racemic Hydroperoxides through the Enantioselective Reduction with Free and Immobilized Microorganisms
J. Am. Chem. Soc., 2000, 122, 4887-4892

821
Adam, W.; Bheema Rao, P.; Degen, H.-G., Saha-Möller, C.R.
Metal-Template Effect in the Asymmetric Weitz-Scheffer Epoxidation of a,ß Enones by an Optically Active Hydroperoxide
J. Am. Chem. Soc., 2000, 122, 5654-5655

822
Adam, W.; Saha-Möller, C.R.; Weichold, O.
Synthesis of Optically Active a-Methyl ß-Hydroperoxy Esters by Diastereoselective Singlet-Oxygen Ene Reaction and Horseradish-Peroxidase Catalyzed Kinetic Resolution
Chem. Monthly, 2000, 131, 697-705

823
Abe, M.; Adam, W.; Ino, Y.; Nojima, M.
Stereochemical Deuterium Labeling as Mechanistic Probe for Differentiating the Singlet- and Triplet-Diradical Spin States in the Rearrangement of the 2-Spiroepoxy-1,3-cyclopentanediyl to Oxetanes
J. Am. Chem. Soc., 2000, 122, 6508-6509

824
Adam, W.; Baumgarten, M.; Maas, W.
A Hydrocarbon Hexaradical with Three Localized 1,3-Cyclopentanediyl Triplet Diradicals Linked by 1,3,5-Trimethylenebenzene as Ferromagnetic Coupler: Synthesis of the Azoalkane Precursor, Photochemical Generation of the Polyradical and EPR Characterization of its Septet-Spin Ground State
J. Am. Chem. Soc., 2000, 122, 6735-6738

825
Adam, W.; Bottke, N.; Krebs, O.
The New skew and the Established cis and gem Regioselectivities in the Ene Reaction of Trisubstituted Olefins: Comparison of the Singlet Oxygen, Triazolinedione, and Nitrosoarene Enophiles
J. Am. Chem. Soc., 2000, 122, 6791-6792

826
Adam, W.; Groer, P.; Saha-Möller, C.R.
Synthesis of Optically Active a-Methylene g-Lactones Through Lipase-Catalyzed Kinetic Resolution
Tetrahedron: Asymmetry, 2000, 11, 2239-2243

827
Adam, W.; Casades, I.; Fornés, V.; Garcia, H.; Weichold, O.
UV-Vis and IR Spectral Characterization of Persistent Carbenium Ions, Generated upon Incorporation of Cinnamyl Alcohols in the Acid Zeolites HZSM-5 and HMor
J. Org. Chem., 2000, 65, 3947-3951

828
Adam, W.; Emmert, O.
The D Parameter of Vinyl-Substituted 1,3-Cyclopentanediyl Triplet Diradicals as a Sensititve Tool to Determine Electronic Substituent Effects in Allylic Radicals
J. Org. Chem., 2000, 65, 4127-4130

829
Adam, W.; Peters, K.; Peters, E.-M., Schambony, S.B.
Diastereoselective and Regioselective Singlet-Oxygen Ene Reaction of Oxazolidine-Substituted Alkenes: Control through Hydrogen Bonding Mediated by the Urea Functionality of Chiral Auxiliaries
J. Am. Chem. Soc., 2000, 122, 7610-7611

830
Nava Salgado, V.; Adam, W.
The Unexpected Reorganizations of a ß-Lactone Aldolate to 1,3-Dioxan-4-ones in the Reaction of 4-(1-Methylethyl)-3-[(phenylthio)methyl]-1-oxetan-2-one Lithium Enolate with Acetaldehyde
Eur. J. Org. Chem., 2000, 2529-2533

831
Adam, W. Groer, P.; Humpf, H.-U.; Saha-Möller, C.R.
Synthesis of Optically Active a-Methylene ß-Lactams through Lipase-Catalyzed Kinetic Resolution
J. Org. Chem., 2000, 65, 4919-4922

832
Adam, W.; Saha-Möller, C.R.; Weichold, O.
Epoxidation of trans-Cyclooctene by Methyltrioxorhenium (MTO)/H2O2: Reaction of trans Epoxide with the Monoperoxo Complex
J. Org. Chem., 2000, 65, 5001-5004

833
Adam, W.; Fröhling, B.
An a,a'-Dioxothione in the Reaction of Ninhydrin with Potassium Thiotosylate and its [4+2] Cycloaddition with trans-Cyclooctene
Org. Lett., 2000, 2, 2519-2522

834
Adam, W.; Lukacs, Z.; Saha-Möller, C.R.; Weckerle, B.; Schreier, P.
Microbial Asymmetric CH Oxidations of Simple Hydrocarbons: A Novel Monooxygenase Activity of the Topsoil Microorganism Bacillus megaterium
Eur. J. Org. Chem., 2000, 2923-2926

835
Adam, W.; Matsumoto, M.; Trofimov, A.V.
Viscosity Dependence of the Chemically Induced Electron-Exchange Chemiluminescence Triggered from a Bicyclic Dioxetane
J. Am. Chem. Soc., 2000, 122, 8631-8634

836
Adam, W.; Emmert, O.
Steric Influence of E- or Z-Monosubstituted and Terminally Disubstituted Vinyl Groups in Matrix-Isolated Cyclopentane-1,3-diyl Triplet Diradicals as Probed by the Zero-Field EPR D Parameter
J. Org. Chem., 2000, 65, 5664-5667

837
Adam, W.; Hajra, S.; Herderich, M.; Saha-Möller, C.R.
A Highly Chemoselective Oxidation of Alcohols to Carbonyl Products with Iodosobenzene Diacetate Mediated by Chromium(III)(salen) Complexes: Synthetic and Mechanistic Aspects
Org. Lett., 2000, 2, 2773-2776

838
Adam, W.; Balci, M.; Kiliç, H.
2,3-Dioxabicyclo[2.2.2]oct-7-en-5-one: Synthesis and Reactions of the Keto Endoperoxide of Phenol
J. Org. Chem., 2000, 65, 5926-5931

839
Adam, W.; Mock-Knoblauch, C.; Saha-Möller, C.R.; Herderich, M.
Are Mn(IV) Species Involved in Mn(Salen)-Catalyzed Jacobsen-Katsuki Epoxidations? A Mechanistic Elucidation of Their Formation and Reaction Modes by EPR Spectroscopy, Mass-Spectral Analysis, and Product Studies: Chlorination versus Oxygen Transfer
J. Am. Chem. Soc., 2000, 122, 9685-9691

840
Adam, W. ; Bottke, N.
Hydroxy-Group Directivity in the Nitroso Ene Reaction: Diastereo- and Regioselective Amination of Chiral Allylic Alcohols
J. Am. Chem. Soc., 2000, 122, 9846-9847

841
Adam, W.; Trofimov, A.V.
The Effect of meta versus para Substitution on the Efficiency of Chemiexcitation in the Chemically Triggered Electron-Transfer-Initiated Decomposition of Spiroadamantyl Dioxetanes
J. Org. Chem., 2000, 65, 6474-6478

842
Adam, W.; Bach, R.D.; Dmitrenko, O.; Saha-Möller, C.R.
A Computational Study of the Hydroxy-Group Directivity in the Peroxyformic Acid Epoxidation of the Chiral Allylic Alcohol (Z)-3-Methyl-3-penten-2-ol: Control of threo Diastereoselectivity through Allylic Strain and Hydrogen Bonding
J. Org. Chem., 2000, 65, 6715-6728

843
Adam, W., Bottke, N., Krebs, O.
Steric and Conformational Control of the Regioselectivities in the Ene Reaction with Trisubstituted Cycloalkenes - Comparison of the Enophiles Singlet Oxygen, Triazolinedione and Nitrosoarene
Org. Lett., 2000, 21, 3293-3296

844
Adam, W.; Maas, W.
EPR-Spectral Determination of Electronic Substituent Effects on the D Values of Hydrocarbon Polyradicals (Quintet and Septet Spin States) Composed of Localized 1,3-Cyclopentanediyl Spin-Carrying Units Linked by 1,3-Di- and 1,3,5-Trimethylenebenzene Ferromagnetic Couplers
J. Org. Chem., 2000, 65, 7650-7655

845
Adam, W.; Roschmann, K.J.; Saha-Möller, C.R.
A Novel Counterion Effect on the Diastereoselectivity in the MnIII-Catalyzed Epoxidation of Phenyl-Substituted cis Alkenes
Eur. J. Org. Chem., 2000, 3519-3521

846
Uppili, S.; Marti, V.; Nikolaus, A.; Jockusch, S.; Adam, W.; Engel, P.S.; Turro, N.J.; Ramamurthy, V.
Heavy-Cation-Induced Phosphorescence of Alkanones and Azoalkanes in Zeolites as Hosts: Induced S1 (np*) to T1 (np*) Intersystem Crossing and S0 to T1 (np*) Absorption
J. Am. Chem. Soc., 2000, 122, 11025-11026

847
Adam, W.; Degen, H.-G.; Pastor, A.; Saha-Möller, C.R.; Schambony, S.B.; Zhao, C.-G.
Preparative Use of Peroxidic Oxidants for Oxygen-Transfer Reactions
In DFG Research Report on Peroxide Chemistry: Mechanistic and Preparative Aspects of Oxygen Transfer; Adam, W., Ed; Wiley-VCH 2000; pp 78-112

848
Adam, W.; Hartung, J.; Okamoto, H.; Saha-Möller, C.R.; Spehar, K.
N-Hydroxy-4-(4-chlorophenyl)thiazole-2(3H)-thione as a Photochemical Hydroxyl-Radical Source: Photochemistry and Oxidative Damage of DNA (Strand Breaks) and 2'-Deoxyguanosine (8-oxodG Formation)
Photochem. Photobiol., 2000, 72, 619-624

849
Adam, W.; Maas, W.; Nau, W.M.
Wavelength-Selective Photodenitrogenation of Azoalkanes to High-Spin Polyradicals with Cyclopentane-1,3-diyl Spin-Carrying Units and their Photobleaching: EPR/UV Spectroscopy and Product Studies of the Matrix-Isolated Species
J. Org. Chem., 2000, 65, 8790-8796

850
Adam, W.; Corma, A.; Garcia, H.; Weichold, O.
Titanium-Catalyzed Heterogeneous Oxidations of Silanes, Chiral Allylic Alcohols, 3-Alkylcyclohexanes, and Thianthrene 5-Oxides: A Comparison of the Reactivities and Selectivities for the Large-Pore Zeolite Ti-ß, the Mesoporous Ti-MCM-41, and the Layered Alumosilicate Ti-ITQ-2
J. Catal., 2000, 196, 339-344

851
Adam, W.; Diedering, M.
The Generation, Detection and Chemical Fate of 1,3-Cyclopentanediyl Radical Cations
In Atualidades de Fisico-Quimica Organica, 1999; Humeres, E., Ed.; Univ. Fed. St. Catarina: Florianopolis, Brazil 2000; Vol. 12, pp 15-34

852
Lévai, A.; Patonay, T.; Székely, A.; Vass, E.B.; Adam, W.; Jekö, J.
A Comparative Study of the Epoxidation of 2-Substituted Isoflavones by Dimethyldioxirane, Sodium Hypochlorite, and Alkaline Hoydrogen Peroxide (Weitz-Scheffer-Reaction)
J. Heterocycl. Chem., 2000, 37, 1065-1069

853
Adam, W.; Kurz, A.; Saha-Möller, C.R.
Peroxidase-Catalyzed Oxidative Damage of DNA and 2'-Deoxyguanosine by Model Compounds of Lipid Hydroperoxides: Involvement of Peroxyl Radicals
Chem. Res. Toxicol., 2000, 13, 1199-1207

854
Adam, W. (Editor)
Peroxide Chemistry: Mechanistic and Preparative Aspects of Oxygen Transfer
In DFG Research Report on Peroxide Chemistry, Wiley-VCH: Weinheim, 2000

2001

855
Adam, W.; Schambony, S.B.
Diastereoselective Epoxidation of Oxazolidine-Substituted Alkenes by Dimethyldioxirane and m-Chlorobenzoic Acid: p-Facial Control through Hydrogen Bonding by the Urea Functionality
Org. Lett., 2001, 3, 79-82

856
Mahler, H-C.; Schulz, I.; Adam, W.; Grimm, G.N.; Saha-Möller, C.R., Epe, B.
tert-Butoxyl Radicals Generate Mainly 7,8-Dihydro-8-Oxoguanine in DNA
Mut. Res., 2001, 461, 289-299

857
Peters, E.-M.; Peters, K; Librera C.P.; Adam, W.
Crystal Structure of (3aa,8aa,13aß)-3a,4,8a,9,13a,14-hexamethyl-1,2,3,3a,6,7,8,8a,1,12,12,13a-tris(cyclopenta[4,5:4',5':4'',5'']pyrazolo)[1,5-a:1',5'-c:1'',5''-e]triazine, C24H 36N6
Z. Kristallogr., 2001, 216, 123-125

858
Adam, W.; Arnold, M.A.; Saha-Möller, C.R.
Photooxidative Damage of Guanine in DG and DNA by the Radicals derived from the a Cleavage of the Electronically Excited Carbonyl Products Generated in the Thermolysis of Alkoxymethyl-Substituted Dioxetanes and the Photolysis of Alkoxyacetones
J. Org. Chem., 2001, 66, 597-604

859
Adam, W., Bheema Rao, P.; Degen, H.-G.; Saha-Möller, C.R.
Asymmetric Weitz-Scheffer Epoxidation of Conformationally Flexible and Fixed Enones with Sterically Demanding Hydroperoxides Mediated by Optically Active Phase-Transfer Catalysts
Tetrahedron: Asymmetry, 2001, 12, 121-125

860
Adam, W.; Lukacs, Z.; Kahle, C.; Saha-Möller, C.R., Schreier, P.
Biocatalytic Asymmetric Hydroxylation by Free and Immobilized Bacillus megaterium Cells
J. Mol. Cat., 2001, 377-385

861
Adam, W.; Stegmann, V.R.; Weinkötz, S.
Unusual Temperature-Dependent Diastereoselectivity in the [2+2] Photocycloaddition (Paterno-Büchi Reaction) of Benzophenone to cis- and trans-Cyclooctene through Conformational Control
J. Am. Chem. Soc., 2001, 123, 2452-2453

862
Patonay, T.; Adam, W.; Lévai, A.; Köver, P.; Németh, M.; Peters, E.-M.; Peters, K.
Chemo- and Diastereoselectivity in the Dimethyldioxirane Oxidation of 2,3-Dihydro-4H-1-benzothiopyran-4-ones and 4H-1-Benzothiopyran-4-ones. Unusual Reactivity of 4H-1-Benzothiopyran-4-one-1-Oxides
J. Org. Chem., 2001, 66, 2275-2280

863
Adam, W., Bargon, R.M.
Episulfidation of Strained Cycloalkenes in the Thermolysis of 5-Aryloxy-1,2,3,4-thiatriazoles
Eur. J. Org. Chem., 2001, 1959-1962

864
Adam, W.; Marti, V.; Sahin, C.; Trofimov, A.V.
Stereoselective Formation of Inverted Housane in the Denitrogenation of the Diazenyl Diradical Photolytically Derived from a Stereolabeled Diazabicyclo[2.2.1]hept-2-ene with Bridgehead Substituents as a Function of Solvent- and Temperature-Varied Viscosity
Chem. Phys. Lett., 2001, 26-32

865
Adam, W.; Bottke, N.; Engels, B.; Krebs, O.
An Experimental and Computational Study on the Reactivity and Regioselectivity for the Nitrosoarene Ene Reaction; Comparison with Triazolinedione and Singlet Oxygen
J. Am. Chem. Soc., 2001, 123, 5542-5548

866
Adam, W.; Stegmann, V.R.
Hydroxy-Group Directivity in the Regioselective and Diastereoselective [2+2] Photocycloaddition (Paternò-Büchi Reaction) of Aromatic Carbonyl Compounds to Chiral and Achiral Allylic Substrates: The Preparation of Oxetanes with up to Three Stereogenic Centers as Synthetic Building Blocks
Synthesis, 2001, 8, 1203-1214

867
Adam, W.; Trofimov, A.V.
Does the Electron Jump or is Charge Transferred in the Triggered CIEEL Mechanism of Dioxetanes?
In Chemiluminescence at the Turn of the Millenium. An Indispensible Tool in Modern Chemistry, Biochemistry and Medicine; Alb 2001; pp 7-10

868
Adam, W.; Trofimov, A.V.; Vasil'ev, R.R.
Elucidation of Thermally and Electron-Transfer Induced Chemiluminescence by the Semiempirical PM3 Method
In Chemiluminescence at the Turn of the Millenium. An Indispensible Tool in Modern Chemistry, Biochemistry and Medicine; Alb 2001; pp 11-14

869
Adam, W.; Peters, K.; Peters, E.-M.; Schambony, S.B.
Efficient Control of the Diastereoselectivity and Regioselectivity in the Singlet-Oxygen Ene Reaction of Chiral Oxazolidine-Substituted Alkenes by a Remote Urea NH Functionality. Comparison with Dimethyldioxirane and m-Chorobenzoic Acid Epoxidations
J. Am. Chem. Soc., 2001, 123, 7228-7232

870
Adam, W.; Grüne, M.; Diedering, M.; Trofimov, A.V.
Temperature and Viscosity Dependence in the Stereoselective Formation of Inverted Housane for the Photochemical Nitrogen Loss from the Deuterium-Stereolabeled Parent Diazabicyclo[2.2.1]hept-2-ene
J. Am. Chem. Soc., 2001, 123, 7109-7112

871
Adam, W.; Humpf, H.-U.; Roschmann, K.J.; Saha-Möller, C.R.
Enantioselective Epoxidation with Chiral MnIII(salen) Catalysts: Kinetic Resolution of Aryl-Substituted Allylic Alcohols
J. Org. Chem., 2001, 66, 5796-5800

872
Makosza, M.; Adam, W.; Zhao, C.-G.; Surowiec, M.
Oxidation of Nitrobenzylic Carbanions with Dimethyldioxirane. New Synthesis of Quinomethanes and Nitrobenzylic Carbinols. First Examples of Methylation of Carbanions with Dimethyldioxirane
J. Org. Chem., 2001, 66, 55022

873
Adam, W.; Bargon, R.M.
Molybdenum-Catalyzed Episulfidation of (E)-Cycloalkenes with Elemental Sulfur
Chem. Commun., 2001, 1910-1911

874
Adam, W.; Saha-Möller, C.R.; Schmid, K.S.
The Synthesis of 4,6-Dideoxyfuranoses through the Regioselective and Diastereoselective Oxyfunctionalization of a Dimethylphenylsilyl-Substituted Chiral Homoallylic Alcohol
J. Org. Chem., 2001, 66, 7365-7371

875
Adam, W.; Saha-Möller, C.R.; Ganeshpure, P.A.
Synthetic Applications of Nonmetal Catalysts for Homogeneous Oxidation
Chem. Rev., 2001, 101, 3499-3548

876
Bolm, C.; Beckmann, O.; Kühn, T.; Palazzi, C.; Adam, W.; Bheema Rao, P.; Saha-Möller, C.R.
Influence of Hydroperoxides on the Enantioselectivity of the Metal-Catalyzed Asymmetric Baeyer-Villiger Oxidation and Epoxidation with Chiral Ligands
Tetrahedron: Asymmetry, 2001, 12, 2441-2446

877
Adam, W.; Prikhodovski, S.; Roschmann, K.J., Saha-Möller, C.R.
Oxidation of Aryl-Substituted Allylic Alcohols by an Optically Active FeIII(Porph*) Catalyst: Enantioselectivity, Diasteroselectivity and Chemoselectivity in the Epoxide versus Enone Formation
Tetrahedron: Asymmetry, 2001, 12, 2677-2681

878
Adam, W.; Diedering, M.; Trofimov, A.V.
Pressure Dependence of the Stereoselectivity in the Photodenitrogenation of Diazabicyclo[2.2.1]hept-2-ene in Supercritical Fluids: Evidence for the Diazenyl Diradical
Chem. Phys. Lett., 2001, 350, 453-458

879
Adam, W.; Arnold, M.A.; Nau, W.M.; Pischel, U.; Saha-Möller, C.R.
Structure-Dependent Reactivity of Oxyfunctionalized Acetophenones in the Photooxidation of DNA: Base Oxidation and Strand Breaks through Photolytic Radical Formation (Spin Trapping, EPR Spectroscopy, Transient Kinetics) versus Photosensitization (Electron Transfer, Hydrogen-Atom Abstraction)
Nucleic Acid Res., 2001, 29, 4955-4962

2002

880
Adam, W.; Bheema Rao, P.; Degen, H.-G.; Lévai, A.; Patonay, T.; Saha-Möller, C.R.
Asymmetric Weitz-Schefffer Epoxidation of Isoflavones with Hydroperoxides, Mediated by Optically Active Phase-Transfer Catalysts
J. Org. Chem., 2002, 67, 259-264

881
Adam, W.; Librera, C.P.
The Rearrangement of Annelated Housanes to Triquinane-Like Hydrocarbons by Electron Transfer (1,3-Cyclopentanediyl Radical Cations) and Acid Catalysis (Cyclopentyl Carbenium Ions)
J. Org. Chem., 2002, 67, 576-581

882
Adam, W.; Bheema, Rao; P.; Degen, H.-G.; Saha-Möller, C.R.
Asymmetric Weitz-Scheffer Epoxidation of a,b-Enones by Optically Active Hydroperoxides: Control of Enantioselectivity through Metal-Coordinated or Hydrogen-Bonded Templates
Eur. J. Org. Chem., 2002, 630-639

883
Adam, W.; Herold, M.; Hill, C.L.; Saha-Möller, C.R.
Allylic CH Oxidation versus Epoxidation of 2-Cyclohexenols, Catalyzed by Chromium- and Manganese-Substituted Polyoxometalates and Salen Complexes
Eur. J. Org. Chem., 2002, 941-946

884
Adam, W ; Marquardt, S.; Kemmer, D.; Saha-Möller, C.R.; Schreier, P.
2'-Deoxyguanosine (dG) Oxidation and Strand-Break Formation in DNA by the Radicals Released in the Photolysis of N-tert-Butoxy-2-pyridone. Are tert-Butoxyl or Methyl Radicals Responsible for the Photooxidative Damage in Aqueous Media?
Org. Lett., 2002, 4, 225-228

885
Adam, W.; Diedering, M.; Trofimov, A.
Solvent Effects in the Photodenitrogenation of the Azoalkane Diazabicyclo[2.2.1]hept-2-ene: Viscosity- and Polarity-Controlled Stereoselectivity in the Housane Formation from the Diazenyl Diradical
Phys. Chem. Chem. Phys., 2002, 4, 1036-1039

886
Adam, W.; Arnold, M.A.; Grüne, M.; Nau, W.N.; Pischel, U.; Saha-Möller, C.R.
Spiroiminodihydantoin is a Major Product in the Photooxidation of 2'-Deoxyguanosine by the Triplet States and Oxyl Radicals Generated from Hydroxyacetophenone Photolysis and Dioxetane Thermolysis
Org. Lett., 2002, 4, 537-540

887
Adam, W.; Fröhling, B.
Lewis-Acid-Catalyzed Sulfur Transfer from a Sultene to Strained Alkenes
Org. Lett., 2002, 4, 599-602

888
Voigt, B.; Porzel, A.; Adam, G.; Golsch, D.; Adam, W.; Wagner, C.; Merzweiler, K.
Synthesis of 2,24-Diepicastasterone and 3,24-Diepicastasterone as Potential Brassinosteroid Metabolites of the Cockroach Periplaneta Americana
Collect. Czech. Chem. Commun., 2002, 67, 91-102

889
Cui, M.; Adam, W.; Shen, J.H.; Luo, X.M.; Tan, X.J.; Chen, K.X; Ji, R.Y.; Jiang, H.L.
A Density-Functional Study of the Mechanism for the Diastereoselective Epoxidation of Chiral Allylic Alcohols by the Titanium Peroxy Complexes
J. Org. Chem., 2002, 67, 1427-1435

890
Adam, W.; Cakmak, O.; Saha-Möller, C.R.; Tutar, A.
Highly Brominated Norbornanes by Photobromination as Precursors for the Convenient Synthesis of 2,3,5,6-Tetrabromo- and 2,3,5,6-Tetramethoxy-Substituted Norbornadienes
Synlett, 2002, 49-52

891
Adam, W.; Kiliç, H.; Saha-Möller, C.R.
An Efficient Regioselective and Diastereoselective Synthesis of the Epoxy-Quinol Functionality as Building Block for the Manumycin Antibiotics by the Sequence of Photooxygenation, Reduction and Weitz-Scheffer Epoxidation
Synlett, 2002, 510-512

892
Adam, W.; Stegmann, V.R.
Unusual Temperature Dependence in the cis/trans-Oxetane Formation Discloses Competitive syn versus anti Attack for the Paterno-Büchi Reaction of Triplet-Excited Ketones with cis and trans Cylooctenes. Conformational Control of Diastereoselectivity in the Cyclization and Cleavage of Preoxet
J. Am. Chem. Soc., 2002, 124, 3600-3607

893
Adam, W.; Arnold, M.A.; Nau, W.; Pischel, U.; Saha-Möller, C.R.
A Comparative Photomechanistic Study (Spin Trapping, EPR Spectroscopy, Transient Kinetics, Photoproducts) of Nucleoside Oxidation (dG and 8-oxodG) by Triplet-Excited Acetophenones and by the Radicals Generated from a-Oxy-Substituted Derivatives through Norrish-Type I Cleavage
J. Am. Chem. Soc., 2002, 124, 3893-3904

894
Adam, W.; Roschmann, K.; Saha-Möller, C.R.; Seebach, D
cis-Stilbene and (1a,2a,3a)-(2-Ethenyl-3-methoxycyclopropyl)benzene as Mechanistic Probes in the MnIII(salen)-Catalyzed Epoxidation: Influence of the Oxygen Source and the Counterion on the Diastereoselectivity of the Competitive Concerted and Radical-Type Oxygen Transfer
J. Am. Chem. Soc., 2002, 124, 5068-5073

895
Adam, W.; Diedering, M; Trofimov, A. V.
Photochemical versus Thermal Skeletal Inversion: Viscosity-Controlled Photodenitrogenation of a Bridgehead-Substituted DBH-Type Azoalkane and Thermal syn-to-anti Housane Isomerisation
J. Am. Chem. Soc., 2002, 124, 5427-5430

896
Lévai, A.; Kocevar, M.; Tóth, G.; Simon, A.; Vranicar, L.; Adam, W.
Synthesis and Dimethyldioxirane Oxidation of Tetrahydrobenzofurans
Eur. J. Org. Chem., 2002, 1830-1833

897
Abe, M.; Adam, W.; Hara, M.; Hattori, M.; Majima, T.; Nojima, M.; Tachibana, K.; Tojo, S.
On the Electronic Character of Localized Singlet 2,2-Dimethoxycyclopentane-1,3-diyl Diradicals: Substituent Effects on the Lifetime
J. Am. Chem. Soc., 2002, 124, 6540-6541

898
Marquez, F.; Marti, V.; Palomares, E.; Garcia, H.; Adam, W.
Observation of Azo-Chromophore Fluorescence and Phosphorescence Emissions from DBH by Applying Exclusively the Orbital Confinement Effect in Siliceous Zeolites Devoid of Charge-Balancing Cations
J. Am. Chem. Soc., 2002, 124, 7264-7265

899
Adam, W.; Ortega Schulte, C.M.
Spin Delocalization in 1-Heteroallyl Monoradicals as a Measure of Radical Stabilization by Heterovinyl Substituents, Assessed through the EPR-Spectral Zero-Field D Parameter of 1,3-Cyclopentanediyl Triplet Diradicals
J. Org. Chem., 2002, 67, 4569-4573

900
Adam, W.; Bosio, S.G.; Fröhling, B.; Stalke, D.
Unusual Sulfur Chemistry in the Thermal Reaction of Sultene and Thiophene-Endoperoxide Sulfur Donors with Cyclic Alkynes: Reversible Formation of a Persistent Thiirenium Ion and Trapping of a Thiirene by [4+2] Cycloaddition
J. Am. Chem. Soc., 2002, 124, 8316-8320

901
Adam, W.; Marquardt, S.; Kemmer, D.; Saha-Möller, C.R.; Schreier, P.
Photobiological Model Studies on Perester and Pyridone tert-Butoxyl-Radical Sources (Photo-Fenton Reagents): 2 -Deoxyguanosine Modification by Methyl Radicals Generated through Competitive b Cleavage in Aqueous Media
Photochem. Photobiol. Sci., 2002, 1, 609-612

902
Adam, W.; Bosio, S.G.; Turro, N.J.
Highly Diastereoselective Dioxetane Formation in the Photooxygenation of Enecarbamates with an Oxazolidinone Chiral Auxiliary: Steric Control in the [2+2] Cycloaddition of Singlet Oxygen through Conformational Alignment
J. Am. Chem. Soc., 2002, 124, 8814-8815

903
Adam, W.; Bosio, S.G.; Gogonas, E.P.; Hadjiarapoglou; L.P.
A Stereoselective and Regioselective Synthesis of trans,trans-Configured 1, 2, 3-Trisubstituted Indanes: Cycloaddition of Alkenes with Iodonium Ylides of beta-Disulfones
Synthesis, 2002, 14, 2084-2090

904
Lazarus, M., Adam, W., Saha-Möller, C.R., Schreier, P.
Biotransformations with Oxidases and Peroxidases for the Synthesis of Optically Active Building Blocks
In 3rd International Conference on Oxygen and Life, Kyoto, Japan; Ishimura, Y., Ed.; Elsevier Science: Amsterdam Internationa 2002; pp 45-49

905
Kazakov, D.V.; Maistrenko, G.Y.; Polyakova, N.P.; Latypova, R.R.; Kazakov, V.P.; Adam, W.; Trofimov, A.V.; Zhao, C.-G.; Kiefer, W.; Schlücker, S.
On the Chemiluminescence in the Oxidation of the Tetravalent Uranium to the Uranyl Ion by Dimethyldioxirane
Luminescence, 2002, 293-298

906
Adam, W.; Hartung, J.; Okamoto, H.; Marquardt, S.; Nau, W.M.; Pischel, U.; Saha-Möller, C.R.; Pehar, K.
Photochemistry of N-Isopropoxy-Substituted 2(1H)-Pyridone and 4-p-Tolylthiazole-2(3H)-thione: Alkoxyl-Radical Release (Spin-Trapping, EPR and Transient Spectroscopy) and its Significance in the Photooxidative Induction of DNA Strand Breaks
J. Org. Chem., 2002, 67, 6041-6049

907
Adam, W.; Librera, C.P.; Trofimov, A.V.
Viscosity-Controlled, Product-Selective Rearrangement of the Cyclopentane-1,3-diyl Radical Cation Derived from an Annelated Housane by Electron Transfer: A Case of Curtin-Hammett Behavior
J. Am. Chem. Soc., 2002, 124, 11936-11939

908
Adam, W.; Bargon, R.M.; Bosio, S.G.; Schenk, W.A.; Stalke, D.
The Direct Synthesis of Isothiocyanates from Isonitriles by Molybdenum-Catalyzed Sulfur Transfer with Elemental Sulfur
J. Org. Chem., 2002, 67, 7037-7041

909
Adam, W.; Garcia, H.; Diedering, M.; Marti, V.; Olivucci, M.; Palomares, E.
Stereochemical Memory in the Temperature-Dependent Photodenitrogenation of Bridgehead-Substituted DBH-Type Azoalkanes: Inhibition of Inverted-Housane Formation in the Diazenyl Diradical through the Mass Effect (Inertia) and Steric Hindrance
J. Am. Chem. Soc., 2002, 124, 12192-12199

910
Adam, W.; Trofimov, A.V.
Electron-Transfer-Induced Dioxetane Chemiluminescence.
In Elektronenübertragung in Chemie und Biologie; Russow, J., Schäfer, H.-J., Eds; GDCh: Frankfurt am Main, GDCh-Monograph.;ÿ 2002; Vol. 23, pp 55-62

911
Adam, W.; Degen, H.-G.; Krebs, O.; Saha-Möller, C.R.
Efficient p-Facial Control in the Ene Reaction of Nitrosoarene, Triazolinedione and Singlet Oxygen with Tiglic Amides of the Bornane-Derived Sultam as Chiral Auxiliary: An Economical Synthesis of Enantiomerically Pure Nitrogen- and Oxygen-Functionalized Acrylic Acid Derivatives
J. Am. Chem. Soc., 2002, 124, 12938-12939

912
Adam, W.; Bosio, S.G.; Degen, H.-G.; Krebs, O.; Schumacher, D.; Stalke, D.
A Comparative Study on the Diastereofacial Control in the [4+2] Cycloaddition of Sorbates and the Ene Reaction of Tiglates with Singlet Oxygen and PTAD by a Variety of Chiral Auxiliaries
Eur. J. Org. Chem., 2002, 3944-3953

913
Adam, W.; Malisch, W.; Roschmann, K.J.; Saha-Möller, C.R.; Schenk, W.A.
Catalytic Oxidations by Peroxy, Peroxo and Oxo Metal Complexes: An Interdisciplinary Account with a Personal View
J. Organomet. Chem., 2002, 661, 3-16

914
Adam, W.; Heckel, F.; Saha-Möller, C.R.; Schreier, P.
Biocatalytic Synthesis of Optically Active Oxyfunctionalized Building Blocks with Enzymes, Chemoenzymes and Microorganisms
J. Organomet. Chem., 2002, 661, 17-29

915
Möller, M.; Adam, W.; Saha-Möller, C.R.; Stopper, H.
Studies on Cytotoxic and Genotoxic Effects of N-Hydroxypyridine-2-thione (Omadine) in L5178Y Mouse Lymphoma Cells
Toxicol. Lett., 2002, 136, 77-84

916
Adam, W.; Corley, D.A.; Trofimov, A.V.; White, R.C.
Viscosity Dependence of the Denitrogenation Quantum Yield in Azoalkane Photolysis: Experimental Evidence for Reversible Formation of the Diazenyl Diradical
Org. Lett., 2002, 4, 4277-4280

917
Adam, W.; Krebs, O.; Orfanopoulos, M.; Stratakis, M.
Control of Regioselectivity by the Lone Substituent through Steric and Electronic Effects in the Nitrosoarene Ene Reaction of Deuterium-Labeled Trisubstituted Alkenes
J. Org. Chem., 2002, 67, 8395-8399

918
Adam, W.; Bottke, N.; Krebs, O.; Lykakis, I.; Orfanopoulos, M.; Stratakis, M.
Ene Reaction of Singlet Oxygen, Triazolinedione and Nitrosoarene with Chiral Deuterium-Labelled Allylic Alcohols: The Interdependence of Diastereoselectivity and Regioselectivity Discloses Mechanistic Insights into the Hydroxy-Group Directivity
J. Am. Chem. Soc., 2002, 124, 14403-14409

919
Adam, W.; Alsters, P.L.; Neumann, R.; Saha-Möller, C.R.; Sloboda-Rozner, D.; Zhang, R.
A New Highly Selective Method for the Catalytic Epoxidation of Chiral Allylic Alcohols by Sandwich-Type Polyoxometalates with Hydrogen Peroxide
Synlett, 2002, 2011-2014

920
Adam, W.; Bosio, S.G.; Turro, N.J.
Control of the Mode Selectivity (Ene Reaction versus [2+2] Cycloaddition) in the Photooxygenation of Ene Carbamates: Directing Effect of an Alkenylic Nitrogen Functionality
J. Am. Chem. Soc., 2002, 124, 14004-14005

921
Stratakis, M.; Nencka, R.; Rabalakos, C.; Adam, W.; Krebs, O.
Thionin-Sensitized Intrazeolite Photooxygenation of Trisubstituted Alkenes: Substituent Effects on the Regioselectivity As Probed Through Isotopic Labelling
J. Org. Chem., 2002, 67, 8758-8763

922
Adam, W., van Barneveld, C.; Emmert, O.; Maas, W.
Carbon-Centered High-Spin Polyradicals
In Landolt-Börnstein Numerical Data and Functional Relationship in Science and Technology: Magnetic Properties of Free Radica 2002; Vol. II/26B, Chap. 7, pp 373-418

923
Adam, W., van Barneveld, C.; Emmert, O.; Maas, W.
High-Spin Mono- and Polycarbenes
In Landolt-Börnstein Numerical Data and Functional Relationship in Science and Technology: Magnetic Properties of Free Radica 2002; Vol. II/26B, Chap. 8, pp 419-459

924
Adam, W.; Kiefer, W.; Schlücker, S.; Saha-Möller, C.R.; Kazakov, D.V.; Kazakov, V.P.; Latypova, R.R.
Formation of Singlet Oxygen During the Decomposition of Dimethyldioxirane, Catalyzed by Anionic Nucleophiles
In Bioluminescence and Chemiluminescence: Progress and Current Applications, Proceedings of the 12th International Symposium 2002; pp 129-132

925
Adam, W.; Zhao, C.-G.; Saha-Möller, C.R.
Dioxirane Epoxidation of Olefins
Org. React., 2002, 61, 219-516

2003

926
Adam, W.; Diedering, M.; Marti, V.
Preferred Formation of anti Housane (Retention) in the Sensitized Photodenitrogenation of Cyclopentane-Annellated DBH-Type Azoalkanes through Long-Range Steric Effects in the Cyclization of the Triplet Cyclopentane-1,3-diyl Diradicals
Eur. J. Org. Chem., 2003, 592-596

927
Adam, W.; Librera, C.P.; Klärner, F.-G.; Wurche, F.
Stereochemical Memory in the Regioselective and Diastereoselective Rearrangement of Tricyclo[3.3.0.02,4]octanes (Housanes) by Electron Transfer (1,3-Cyclopentanediyl Radical Cations) and Acid (Cyclopentyl Carbenium Ions) and Silver(I)-Ion Catalysis
J. Am. Chem. Soc., 2003, 125, 995-1001

928
Adam, W.; Zhang, A.
Highly p-Facial Stereoselective Aldol Reaction of (S)-Proline-Derived Amide Enolate with Benzaldehydes
Eur. J. Org. Chem., 2003, 587-591

929
Adam, W.; Diedering M.; Sajimon, M.C.; Trofimov, A.V.
Structural Dependence on the Stereoselective Formation of Inverted Housane in the Viscosity-Controlled Photodenitrogenation of DBH-Type Azoalkanes
Phys. Chem. Chem. Phys., 2003, 5, 329-332

930
Bach, R.D.; Dmitrenko, O.; Adam, W.; Schambony, S.B.
Relative Reactivity of Peracids versus Dioxiranes (DMDO and TFDO) in the Epoxidation of Alkenes. A Combined Experimental and Theoretical Analysis
J. Am. Chem. Soc., 2003, 125, 924-934

931
Adam, W.; Ortega Schulte, C.M.
An Effective Synthesis of Cyanoenamines by Peterson Olefination
Synlett, 2003, 414-416

932
Adam, W.; Ortega Schulte, C.M.
Spin Delocalization by Triple Bonds, Assessed from the EPR-Spectral D Parameter of 1,3-Cyclopentanediyl Triplet Diradicals
J. Org. Chem., 2003, 68, 1007-1011

933
Adam, W.; Alsters, P.; Neumann, R.; Saha-Möller, C.R.; Sloboda-Rozner, D.; Zhang, R.
A Highly Chemoselective, Diastereoselective and Regioselective Epoxidation of Chiral Allylic Alcohols with Hydrogen Peroxide, Catalyzed by Sandwich-Type Polyoxometalates: Enhancement of Reactivity and Control of Selectivity by the Hydroxy Group through Metal-Alcoholate Bonding
J. Org. Chem., 2003, 68, 1721-1728

934
Abe, M.; Adam, W.; Minamoto, T.; Ino, Y.; Nojima, M.
Mechanism of an Alcohol-Trapping Reaction in the Direct and Benzophenone-Sensitized Photodenitrogenation of a Spiroepoxy-Substituted Azoalkane: Solvent Effects and Stereochemical Deuterium Labeling
J. Org. Chem., 2003, 68, 1796-1803

935
Adam, W.; Krebs, O.; Orfanopoulos, M.; Stratakis, M.; Vougioukalakis, G.C.
Intramolecular and Intermolecular Kinetic Isotope Effects (KIE) in the Nitrosoarene Ene Reaction: Experimental Evidence for Reversible Intermediate Formation
J. Org. Chem., 2003, 68, 2420-2425

936
Adam, W.; Bargon, R.M.; Schenk, W.A.
Direct Episulfidation of Alkenes and Allenes with Elemental Sulfur and Thiiranes as Sulfur Sources, Catalyzed by Molybdenum Oxo Complexes
J. Am. Chem. Soc., 2003, 125, 3871-3876

937
Adam, W.; Alsters, P.L.; Neumann, R.; Saha-Möller, C.R.; Seebach, D.; Zhang. R.
Highly Efficient Catalytic Asymmetric Epoxidation of Allylic Alcohols by an Oxovanadium-Substituted Polyoxometalate with a Regenerative TADDOL-Derived Hydroperoxide
Org. Lett., 2003, 5, 725-728

938
Adam, W.; Bosio, S.G.; Wolff, B.T.
Chiral-Auxiliary-Controlled Diastereoselectivity in the Epoxidation of Enecarbamates with DMD and m-CPBA
Org. Lett., 2003, 5, 819-822

939
Adam, W.; Diedering, M.
Enhanced Formation of Inverted Housane through Steric Effects by Rotationally Unsymmetric Bridgehead Substituents in the Ring Closure of Triplet Cyclopentane-1,3-diyl Diradicals, Generated Photolytically from 2,3-Diazabicyclo[2.2.1]heptene(DHB)-Type azoalkanes
Photochem. Photobiol. Sci., 2003, 2, 393-397

940
Adam, W.; Beck, A.K.; Pichota, A.; Saha-Möller, C.R.; Seebach, D.; Vogl, N.; Zhang, R.
Control of Enantioselectivity Through a Hydrogen-Bonded Template in the Vanadium(V)-Catalyzed Epoxidation of Allylic Alcohols by Optically Active Hydroperoxides
Tetrahedron: Asymmetry, 2003, 14, 1355-1361

941
Adam, W.; Gogonas, E.P.; Hadjiarapoglou, L.
A Remarkable Cycloaddition of Bis(arylsulfonyl)iodonium Ylide with Norbornene Derivatives for the Direct Synthesis of Functionalized Indanes
Synlett, 2003, 1165-1169

942
Adam, W.; Gogonas, E.P.; Hadjiarapoglou L.
Bis(sulfonyl)methyl Insertion into Alkenyl versus Phenyl Carbon-Hydrogen Bonds in the Reaction of Bis(sulfonyl)iodonium Ylides with Highly Phenylated Ethylenes
Eur. J. Org. Chem., 2003, 1064-1068

943
Adam, W.; Sajimon, M.C.; Trofimov, A.V.
Viscosity-Dependent Diastereoselectivity and Product Selectivity in the Photodenitrogenation of a Spirocyclopropyl-Substituted DBH-Type Azoalkane
Photochem. Photobiol. Sci., 2003, 2, 677-680

944
Griesbeck, A.G.; Adam, W.; Bartoschek, A.; El-Idreesy, T.T.
Photooxygenation of Allylic Alcohols: Kinetic Comparison of Unfunctionalized Alkenes with Prenol-Type Allylic Alcohols, Ethers and Acetates
Photochem. Photobiol. Sci., 2003, 2, 877-881

945
Adam, W.; Trofimov, A.V.
Viscosity as a Valuable Experimental Tool to Study the Mechanism of Stereoselective and Product-Selective Chemical Transformation through Frictional Impositions
Acc. Chem. Res., 2003, 36, 571-579

946
Adam, W.: Librera, C.; Trofimov, A.V.
Stereochemical Memory versus Curtin-Hammett Behavior in the Rearrrangement of
J. Am. Chem. Soc., 2003, 125, 5741-5744

947
Poon, T.; Turro, N.J.; Chapman, J.; Lakshminarasimhan,P.; Lei, X.; Adam, W.; Bosio, S.G.
A Supramolecular 'Ship in Bottle' Strategy for Enantiomeric Selectivity in Geminate Radical Pair Recombination
Org. Lett., 2003, 5, 2025-2028

948
Adam, W.; Gogonas, E.P.; Hadjiarapoglou, L.
Alkenyl CH Insertion of a b-Disulfone Iodonium Ylide into Flavones
Tetrahedron, 2003, 59, 7929-7934

949
Sinicropi, A.; Page, C.S.; Adam, W.; Olivucci, M.
A Computational Study on the Origin of the Stereoselectivity for the Photochemical Denitrogenation of Diazabicycloheptene
J. Am. Chem. Soc., 2003, 125, 10947- 10959

950
Adam, W.; Bargon, R.M.; Mloston, G.
Episulfidation of trans-Cyclooctene by 1,2,4-Oxadithiolanes
Eur. J. Org. Chem., 2003, 4012-4015

951
Adam, W.; Alsters, P.L.; Beck, A.; Neumann, R.; Saha-Möller, C.R.; Seebach, D.; Zhang, R.
Chiral Hydroperoxides as Oxygen Source in the Catalytic Asymmetric Epoxidation of Allylic Alcohols by Sandwich-Type Polyoxometalates: Control of Stereoselectivity through a Metal-Coordinated Template
J. Org. Chem., 2003, 68, 8222-8231

952
Adam, W.; Krebs, O.
Progress in the Regioselective and Stereoselective Allylic Nitrogen Functionalization by the Nitroso Ene Reaction
Chem. Rev., 2003, 103, 4131-4146

953
Adam, W.; Gogonas, E.P.; Hadjiarapoglou, L.P.
A Facile Diastereoselctive Synthesis of Functionalized 1,2,3-Trisubstituted Benzocyclopentenes through the Cycloaddition of Bis(phenylsulfonyl)iodonium Ylides to Cyclic Alkenes
J. Org. Chem., 2003, 68, 9155-9159

954
Griesbeck, A.G.; El-Idressy, T.T.; Adam, W.; Krebs, O.
Ene Reactions with Singlet Oxygen
In Handbook of Organic Photochemistry and Photobiology, 2nd ed.; Horspool, W. M.; Lenci, F.(Eds.); CRC Press, Inc.: London 2003; Chap. 8, pp 1-20

955
Griesbeck, A.G.; Bartoschek, A.; Adam, W.; Bosio, S.G.
Photooxygenation of 1,3-Dienes
In Handbook of Organic Photochemistry and Photobiology, 2nd ed.; Horspool, W. M., Lenci, F. (Eds.); CRC Press, Inc.: London 2003; Chap. 25, pp 1-19

956
Adam, W.; Trofimov, A.V.
Photomechanistic Aspects of Bicyclic Azoalkanes: Triplet States, Photoreduction and Double Inversion
In Handbook of Organic Photochemistry and Photobiology, 2nd ed.; Horspool, W. M.; Lenci, F. (Eds.); CRC Press, Inc.: London 2003; Chap. 93, pp 1-16

957
Simon, A,; Tóth, G.; Librera, C.P.; Adam, W.
1H, 13C and 15N NMR Investigation of a New , Condensed Hexahydro-1,3,5-triazine
Magn. Reson. Chem., 2003, 41, 541-544

958
Poon, T.; Turro, N.J.; Chapman, J.; Lakshminarasimhan, P.; Lei, X.; Jockush, S.; Franz, R.; Adam, W.; Bosio, S.G.
Stereochemical Features of the Physical and Chemical Interactions of Singlet Oxygen with Enecarbamates
Org. Lett., 2003, 5, 4951-4953

959
Chapman, J.R.; Turro, N.J.; Poon, T.; Lakshminarasimhan, P.; Bosio, S.; Adam, W.; Jockusch, S.; Lei, X.; Liu, Z.; Ramamurthy, V.
An Investigation of the Induction Capabilities of Oxazolidinones in the Enantioselective Formation of Methyldeoxybenzoin
In Abstracts of Papers, 225th ACS National Meeting, New Orleans; American Chemical Society: Washington, D. C., 2003; Abstract CHED-394

2004

960
Adam, W.; Zhang, A.
High p-Facial Selectivity through Magnesium Chelation in the DMD Epoxidation of a,b-Unsaturated Amides with Chiral Pyrroliginone Auxiliaries
Eur. J. Org. Chem., 2004, 147-152

961
Adam, W.; Bargon, R.M.
The Synthesis of Thiiranes by Direct Sulfur Transfer: The Challenge of Developing Effective Sulfur Donors and Metal Catalysts
Chem. Rev., 2004, 104, 251-261

962
Abe, M.; Adam, W.; Borden, W.T.; Hattori, M.; Hrovat, D.A.; Nojima, M.; Nozaki,K.; Wirz, J.
Effects of Spiroconjugation on the Calculated Singlet-Triplet Energy Gap in 2,2-Dialkoxycyclopentane-1,3-diyls and on the Experimental Electronic Absorption Spectra of Singlet 1,3-Diphenyl Derivatives. Assignment of the Lowest-Energy Electronic Transition of Singlet Cyclopentane-1,3-diyls
J. Am. Chem. Soc., 2004, 126, 574-582

963
Adam, W.; Ganeshpure, P.A.; Saha-Möller, C.R.
A Convenient Synthesis of Nickel(II) and Cobalt(II) Complexes with Unsymmetrical Salen-Type Ligands and their Application as Catalysts for the Oxidation of 2,6-Dimethylphenol and 1,5-Dihydroxynaphthalene by Molecular Oxygen
Ind. J. Chem., 2004, 43A, 56-62

964
Adam, W.; Saha-Möller, C.R.; Kazakov, D.V.; Kazakov, V.P.; Kiefer, W.; Latypova, R.R.; Schlueker, S.
Singlet-Oxygen Generation in the Reaction of Dioxiranes with Nucleophilic Anions
Photochem. Photobiol. Sci., 2004, 3, 182-188

965
Adam, W.; Bosio, S.G.; Turro, N.J.; Wolff, B.T.
Enecarbamates as Selective Substrates in Oxidations: Chiral-Auxiliary-Controlled Mode Selectivity and Diastereoselectivity in the [2+2] Cycloaddition and Ene Reaction of Singlet Oxygen and in the Epoxidation by DMD and mCPBA
J. Org. Chem., 2004, 69, 1704-1715

966
Adam, W.; Ortega Schulte, C.M.
Captodative Stabilization in Geminally Substituted Allylic Radicals Assessed by Means of the EPR-Spectral D Parameter of 1,3-Cyclopentanediyl Triplet Diradicals
Eur. J. Org. Chem., 2004, 1482-1491

967
Adam, W.; Heckel, F.; Saha-Möller, C.R.; Taupp, M.; Schreier, P.
A Highly Enantioselective Biocatalytic Sulfoxidation by the Topsoil Bacterium Pseudomonas Frederiksbergensis
Tetrahedron: Asymmetry, 2004, 15, 983-985

968
Adam, W.; Diedering, M., Trofimov, A.V
The Intriguing Double-Inversion Stereochemistry in the Denitrogenation of 2,3-Diazabicyclo[2.2.1]heptene-Type Azoalkanes (DBH): A Model Mechanistic Study in Physical Organic Chemistry
J. Physorg. Chem., 2004, 17, 643-655

969
Poon, T.; Sivaguru, J.; Franz, R.; Jockusch, S.; Martinez, C.; Washington, I.; Adam, W. ; Inoue, Y.; Turro, N.J.
Temperature and Solvent Control of the Stereoselectivity in the Reactions of Singlet Oxygen with Oxazolidinone-Substituted Enecarbamates
J. Am. Chem. Soc., 2004, 126, 10498-10499

970
Nardello, V.; Caron, L. ; Aubry, J.-M.; Bouttemy, S.; Wirth, T.; Saha-Möller, C.R. ; Adam, W.
Reactivity, Chemoselectivity and Diastereoselectivity of the Oxyfunctionalization of Chiral Allylic Alcohols and Derivatives in Microemulsions : Comparison of the Chemical Oxidation by the Hydrogen Peroxide/Sodium Molybdate System with the Photooxygenation
J. Am. Chem. Soc., 2004, 126, 10692-10700

971
Sivaguru, J.; Poon, T.; Franz, R.; Jockusch, S.; Adam, W.; Turro, N.J.
Stereocontrol Within Confined Spaces: Enantioselective Photooxidation of Enecarbamates Inside Zeolite Supercages
J. Am. Chem. Soc., 2004, 126, 10816-10817

2005

972
Adam, W.; Heckel, F.; Saha-Möller, C.R.; Taupp, M.; Meyer, J.-M.; Schreier, P.
Opposite Enantioselection by Phenotypically and Genotypically Identical Strains in the Bacterial Whole-Cell Sulfoxidation by Pseudonomas frederiksbergensis
Appl. Environ. Microbiol., 2005, 71, 2199-2202

973
Adam, W.; Zhang, A.
Chiral-Auxiliary-Controlled Stereoselective Epoxidation of CC Double Bonds
Synlett, 2005, 1047-1073

974
Adam, W.; Kazakov, V.P.; Kazakov, D.V.; Latypova, R.R.; Maistrenko, G.Y.; Mal'zev, D.V.; Safarov, F.E.
On the Role of Singlet-Oxygen Dimol Chemiluminescence in Oxirane Reactions.
In Proceedings of the 13th International Symposium on Bioluminescence and Chemiluminescence; Tsuji, A., Maeda, M., Matsumoto, 2005; pp 135-138

975
Adam, W.; Trofimov, A.V.
On the CIEEL Mechanism of Triggerable Dioxetanes: Does the Electron Jump or is it Charge Transfer?
In Proceedings of the 13th International Symposium on Bioluminescence and Chemiluminescence; Tsuji, A., Maeda, M., Matsumoto, 2005; pp 197-200

976
Sivaguru, J.; Saito, H.; Poon, T.; Omonuwa, T.; Franz, R.; Jockusch, S.; Inoue, Y.; Adam, W.; Turro, N.J.
Stereoselective Photooxidation of Enecarbamates: Reactivity of Ozone versus Singlet Oxygen
Org. Lett., 2005, 7, 2089-2092

977
Saito, H.; Sivaguru,, J.; Jockusch, S.; Inoue, Y.; Adam, W.; Turro, N.J.
Stereoselective E/Z Photoisomerization of Oxazolidinone-Functionalized Enecarbamates: Direct and Triplet-Sensitized Irradiation
Chem. Commun., 2005, 3424-3426

978
Pastor, A.; Adam, W.; Wirth, T.; Tóth, G.
Diastereoselective Reactions of the Tiglic-Acid Functionality Mediated by the Oxazolidine Chiral Auxiliary: A Mechanistic Comparison of the DMD and m-CPBA Epoxidations versus the Singlet-Oxygen and PTAD Ene Reactions
Eur. J. Org. Chem., 2005, 3075-3084

979
Möller, M.; Stopper, H.; Adam, W.; Grimm, G.N.; Saha-Möller, C.R.
Cytotoxicity and Genotoxicity of N-tert-Butoxypyridine-2-thione upon UVA Irradiation and in the Dark
Free Radical Biology & Medicine, 2005, 39, 473-482

980
Adam, W.; Kazakov, D.V.; Kazakov, V.P.
Singlet-Oxygen Chemiluminescence in Peroxide Reactions
Chem. Rev., 2005, 105, 3371-3387

981
Heckel, F.; Adam, W.; Saha-Möller, C.R.; Schreier, P.
Pseudomonas freferiksbergensis - Enantiodifferenzierung in der bakteriellen, whole-cell Sulfoxidation
Lebensmittelchem., 2005, 59, 92

982
Adam, W.; Zhao, C.-G.
Oxidation of Unactivated Alkanes by Dioxiranes
In Wiley-VCH Handbook of CH Transformations, Dyker, G., Ed.; Wiley-VCH Verlag GmbH: Weinheim, 2005; Chapter IV2.1.2, pp 507-516

983
Hooper, C.; Poon, T.; Franz, R.; Sivaguru, J.; Jockusch, S.; Turro, N.J.; Adam, W.
Mechanistic Insight on the Stereoselective Photooxidation of Enecarbamates Using PTAD, a Singlet Oxygen Analog
In Abstracts of Papers, 229th ACS National Meeting, San Diego; American Chemical Society: Washington, D. C., 2005; Abstract CHED-439

984
Franz, R.; Poon, T.; Sivaguru, J.; Jockusch, S.; Turro, N.J.; Adam, W.
Mechanistic Insights into the Diastereoselective Photooxidation of Enecarbamates
In Abstracts of Papers, 229th ACS National Meeting, San Diego; American Chemical Society, Washington, D. C., 2005; Abstract ORGN-464

2006

985
Sivaguru, J.; Saito, H.; Solomon, M.R.; Kaanamalle, L.; Poon, T.; Jockusch, S.; Ramamurthy, V.; Inoue, Y.; Adam, W.; Turro, N.J.
The Control of Chirality by Cations in Confined Spaces: Photooxidation of Encarbamates Inside Zeolite Supercages
Photochem. Photobiol., 2006, 82, 123-131

986
Adam, W.; Zhao, C.-G.
Contemporary Dioxirane Chemistry: Epoxidations, Heteroatom Oxidations and CH Insertions.
In The Chemistry of Peroxides , Rappoport, Z., Maeak, I., Eds.; John Wiley & Sons: New York 2006; pp 1129-1169

987
Adam, W.; Trofimov, A.V.
Contemporary Trends in Dioxetane Chemistry.
In The Chemistry of Functional Groups, Peroxides , Rappoport, Z., Marek, I., Eds.; John Wiley & Sons: New York 2006; pp 1171-1209

988
Nardello, V.; Aubry, J.-M., De Vos, D.E.; Neumann, R.; Adam,W. ;Zhang, R.; ten Elshof,J.E.; Witte, P.T.; Alsters, P.L.
Inorganic compounds and materials as catalysts for oxidations with aqueous hydrogen peroxide
J. Mol. Cat., 2006, 251, 185-193

989
Sivaguru, J.; Solomon, M.R.; Saito, H.; Poon, T.; Jockusch, S.; Adam, W.; Inoue, Y.; Turro, N.J.
Conformationally controlled (entropy effects), stereoselective vibrational quenching of singlet oxygen in the oxidative cleavage of oxazolidinone-functionalized enecarbamates through solvent and temperature variations
Tetrahedron, 2006, 62, 6707-6717

990
Sivaguru, J.; Poon, T.; Hooper, C.; Saito, H.; Solomon, M.; Jockusch, S.; Adam, W.; Inoue, Y.; Turro, N.J
A Comparative Mechanistic Analysis of the Stereoselectivity Trends Observed in the Oxidation of Chiral Oxazolidinone-Functionalized Enecarbamates by Singlet Oxygen, Ozone and Triazolinedione
Tetrahedron, 2006, 62, 10647-10659

991
Aubry, J.-M.; Adam, W.; Alsters, P.L.; Borde, C.; Queste, S.; Marko, J.; Nardello, V
Dark Singlet Oxygenation of Organic Substrates in Single-Phase and Multiphase Microemulsion Systems
Tetrahedron, 2006, 62, 10753-10761

992
Moscatelli, A.; Ottaviani, M.F.; Adam, W.; Buchachenko, A.; Jockusch, S.; Turro, N.J.
Interactions between Molecular Oxygen and Nitroxide Radicals: A Search for a Reversible Complex.
Helv. Chim. Acta, 2006, 89, 2441-2449

2007

993
Saito, H.; Sivaguru, J.; Jockush, S.; Dyer, J.; Inoue, Y.; Adam, W.; Turro, N.J.
Controlled Diastereoselectivity at the Alkene Geometry Through Selective Encapsulation: E-Z Photoisomerization of Oxazolidinone-Functionalized Enecarbamates within Hydrophobic NaNo Cavities
Chem. Comm., 2007, 819-821

994
Sajimon, M.C.; Ramaiah, D.; Suresh, C.H.; Adam, W.; Lewis, F.D.; George, M.V.
Photochromic Dibenzobarrelenes: Long-Lived Triplet Biradical Intermediates
J. Am. Chem. Soc., 2007, 129, 9439-9445

995
Adam, W. ; Gogonas, E.P.; Nyxas, I.A.; Hadjiarapoglou, L.P.
[3+2] Cycloaddition of Phenyliodonium Bis(arylsulfonyl)methylides with a,b Enones
Synthesis, 2007, 3211-3218

996
Adam, W.; Zhao, C.-G.; Jakka, K.
Dioxirane Oxidations of Allenes, Alkynes and Arenes, Heteroatom Substrates, Alkanes and Silanes, and Organometallic Compounds
Org. React., 2007, 69, 1-346

2008

997
Sivaguru, J.; Solomon, M.; Poon, T.; Jockusch, S.; Bosio, S.G.; Adam, W.; Turro, N.J.
The Reaction of Singlet Oxygen with Chiral Enecarbamates: A Mechanistic Playground for Investigating Chemoselectivity, Stereoselectivity and Selective Vibratioselectivity of Photooxidations
Acc. Chem. Res., 2008, 41, 387- 400

998
Solomon, M.R.; Sivaguru, J.; Jockusch, S.; Adam, W.; Turro, N.J.
Vibrational Deactivation of Singlet Oxygen: Does it Play a Role in Stereselectivity during Photooxygenation?
Photochem. Photobiol. Sci., 2008, 7, 531 - 533

999
Alsters, P.L.;Witte, P.T.; Neumann, R.; Rozner, D.S.; Adam, W.; Zhang, R.; Reedijk, J.; Gamez, P.; ten Elshof, J.T.; Chowdhury, S.R.
Fine-Tuning and Recycling of Homogeneous Tungstate and Polytungstate Epoxydation Catalysts
in Mechanisms in Homogeneous and Heterogeneous Epoxydation Catalysis, Oyama S. T.,Ed.; Elsevier B.V.: Amsterdam 2008; Chap. 16, pp. 415-428

2009

1000
Adam, W.; Zhao, C.-G.; Saha-Möller, C.R.; Jakka, K.
Oxidation of Organic Compounds by Dioxiranes
Denmark, S. E., Ed.; John Wiley & Sons, Inc.: Hoboken, New Jersey 2009

1001
Kilic, H.; Adam, W.; Alsters, P.L.
Effect of Additives on Chemoselectivity and Diastereoselectivity in the Catalytic Epoxiation of Chiral Allylic Alcohols with Hydrogen Peroxide and Binuclear Manganese Complexes
J. Org. Chem., 2009, 74, 1135-1140

1002
Solomon, M-R.; Sivaguru, J.; Jokusch, S.; Adam, W.; Turro, N.J.
Physical ans Chemical Quenching Rates and their Influence on the Stereoselective Photooxygenation of Oxazolidinone-Functionalized Enecarbamates
Photochem. Photobiol. Sci, 2009, 8, 912-915

1003
Solomon, M. R.; Saito , H.; Sivaguru, J.; Jokusch, S.; Inoue, Y.; Adam, W.; Turro,N.J.
Isolation and syn Elimination of a Peterson Adduct to Obtain Optically Pure Product in the Diastereoselective Synthesis of Oxazolidinone-Functionalized Enecarbamates
Lett. Org. Chem., 2009, 6, 362-366

1004
Valentín, E. M.; Montes, I.; Adam, W.
Counterion Effects in the Nucleophilic Substitution Reaction of the Acetate Ion with Alkyl Bromides in the Synthesis of Esters
J. Chem. Educ., 2009, 86, 1315-1318

2010

1005
Ovchinnikov, M. Y.; Khursan, S. L.; Kazakov, D. V.; Adam, W.
The Theoretical Trajectory for the Chloride-Ion-Induced Generation of Singlet Oxygen in the Decomposition of Dimethyldioxirane
J. Photochem. Photobiol. A: Chem., 2010, 210, 100-107

1006
Solomon, M. R.; Sivaguru, J.; Jockusch, S.; Adam, W.; Turro, N.
Decoding Stereocontrol During the Photooxygenation of Oxazolodinone-Functionalized Enecarbamates
Org. Lett., 2010, 12, 2142-2145

2011

 

2012

1007
Kazakov, D.V.; Timerbaev, A.R.; Safarov, F.E.; Nazirov, T.I.; Kazakova, O.B.; Ishmuratov, G.Y.; Terent'ev, A.O.; Borisov,D.A.; Tolstikov, A.G. and Adam, W.
Chemiluminescence from the Biomimetic Reaction of 1,2,4-Trioxolanes and 1,2,4,5-Tetroxanes with Ferrous Ions
RSC Advances, 2012, 2, 107-110

 

2013

 

2014

1008
Kagova, A.; Potapenko, A.; Möller, M.; Stopper, H.; Adam, W.
Photohemolysis Sensitized by the Furocoumarin Derivate Alloimperatorin and its Hydoperoxyde Photooxidation Product
Photochem. Photobiol., 2014, 90, 162-170

 

2015

1009
Terent'ev, A.O.; Vil, V.A.; Nikishin, G.I.; Adam, W.
Lanthanide-Catalized Oxidative C-O Coupling of 1,3-Dicarbonyl Compounds with Diacyl Peroxides
Synlett, 2015, 26, 802-806

2016

1010
Ye, J.; Hatano, S.; Abe, M.; Kishi, R.; Murata, Y.; Nakano, M.; Adam, W.
A Puckered Singlet Cyclopentane-1,3-diyl: Detection of the Third Isomer in Homolysis
Chem. Eur. J., 2016, 22, 2299-2306

1011
Terent’ev, A. O.; Vil, V. A.; Gorlov, E. S.; Nikishin, G.I.; Pivnitsky, K. K.; Adam, W.
Lanthanide-Catalyzed Oxyfunctionalization of 1,3-Diketones, Acetoacetic Esters, and Malonates by Oxidative C−O Coupling with Malonyl Peroxides
J. Org. Chem., 2016, 81, 810-823.

2017

1012
Terent’ev, A. O.; Vil, V.; A.; Gorlov, E. S.; Rusina, O. N.; Korlyukov, A.A.; Gennady, A.A.; Nikishin, G. I.; Adam, W.
Selective Oxidative Coupling of 3H-Pyrazol-3-ones, Isoxazol-5(2H)-ones, Pyrazolidine-3,5-diones, Barbituric Acids with Malonyl Peroxides: An Effective C-O Functionalization ChemistrySelect, 2017, 2, 3334-3341

2018

1013
De Lucchi, O.; Fabbro, C.; Adam, W.
The environmental culprits water, oxygen, heat, and light in the fateful destiny of the organic chemicals contained in art work of cultural heritage
Rev. Press. 2018, 2, 19-40

2019

1014
Jirau-Colón, H.; González-Parrilla, L.; Martinez-Jiménez, J.; Adam, W.; Jiménez-Velez, B.
Rethinking the Dental Amalgam Dilemma: An Integrated Toxicological Approach
Int. J. Environ. Res. Public Health 2019, 16, 1036-1048

 

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